Literature DB >> 23712509

Carbonylation of the simplest persistent diaminocarbene.

Tim Schulz1, Christian Färber, Michael Leibold, Clemens Bruhn, Wolfgang Baumann, Detlef Selent, Timo Porsch, Max C Holthausen, Ulrich Siemeling.   

Abstract

The reactions of the acyclic diaminocarbenes (Me2N)2C and (Ph2N)(iPr2N)C with CO proceed in a 2 : 1 stoichiometric ratio, affording unprecedented betainic oxyallyl species of type [(R2N)2C]2CO.

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Year:  2013        PMID： 23712509     DOI： 10.1039/c3cc42888e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Generation of 1,2-azaboretidines via reduction of ADC borane adducts.

Authors:  H Braunschweig; A Gackstatter; T Kupfer; T Scheller; F Hupp; A Damme; N Arnold; W C Ewing
Journal:  Chem Sci       Date:  2015-04-16       Impact factor: 9.825

2.  Metal free oxidation of vinamidine derivatives: a simple synthesis of α-keto-β-diimine ligands.

Authors:  Monika Tripathi; Vianney Regnier; Zakaria Ziani; Marc Devillard; Christian Philouze; David Martin
Journal:  RSC Adv       Date:  2018-11-14       Impact factor: 3.361

3.  The curious case of a sterically crowded Stenhouse salt.

Authors:  Valentin Théry; Florian Molton; Selim Sirach; Neven Tillet; Jacques Pécaut; Eder Tomás-Mendivil; David Martin
Journal:  Chem Sci       Date:  2022-07-27       Impact factor: 9.969
  3 in total

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