Literature DB >> 23712417

Calcium-based Lewis acid catalysts.

Jeanne-Marie Begouin1, Meike Niggemann.   

Abstract

Recently, Lewis acidic calcium salts bearing weakly coordinating anions such as Ca(NTf₂)₂, Ca(OTf)₂, CaF₂ and Ca[OCH(CF₃)₂]₂ have been discovered as catalysts for the transformation of alcohols, olefins and carbonyl compounds. High stability towards air and moisture, selectivity and high reactivity under mild reaction conditions render these catalysts a sustainable and mild alternative to transition metals, rare-earth metals or strong Brønsted acids.
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Year:  2013        PMID: 23712417     DOI: 10.1002/chem.201203496

Source DB:  PubMed          Journal:  Chemistry        ISSN: 0947-6539            Impact factor:   5.236


  8 in total

1.  Calcium Bistriflimide-Mediated Sulfur(VI)-Fluoride Exchange (SuFEx): Mechanistic Insights toward Instigating Catalysis.

Authors:  Brian Han; Samuel R Khasnavis; Matthew Nwerem; Michael Bertagna; Nicholas D Ball; O Maduka Ogba
Journal:  Inorg Chem       Date:  2022-06-14       Impact factor: 5.436

2.  Sulfonamide Synthesis via Calcium Triflimide Activation of Sulfonyl Fluorides.

Authors:  Paramita Mukherjee; Cristian P Woroch; Leah Cleary; Mark Rusznak; Ryan W Franzese; Matthew R Reese; Joseph W Tucker; John M Humphrey; Sarah M Etuk; Sabrina C Kwan; Christopher W Am Ende; Nicholas D Ball
Journal:  Org Lett       Date:  2018-06-11       Impact factor: 6.072

3.  Calcium(ii)-catalyzed enantioselective conjugate additions of amines.

Authors:  Brice E Uno; Rachel D Dicken; Louis R Redfern; Charlotte M Stern; Greg G Krzywicki; Karl A Scheidt
Journal:  Chem Sci       Date:  2018-01-10       Impact factor: 9.825

4.  Transesterification of Lactic Acid Oligomers with Ethanol, a Way to Anhydrous Ethyl Lactate: A Kinetic Study.

Authors:  Silvestr Figalla; Jaroslav Petrůj; Tereza Švestková
Journal:  Molecules       Date:  2018-08-15       Impact factor: 4.411

5.  Sustainable Access to 5-Amino-Oxazoles and Thiazoles via Calcium-Catalyzed Elimination-Cyclization with Isocyanides.

Authors:  Ashley J Basson; Mark G McLaughlin
Journal:  ChemSusChem       Date:  2021-03-03       Impact factor: 8.928

6.  Chemo- and Stereoselective Synthesis of Substituted Thiazoles from tert-Alcohols Bearing Alkene and Alkyne Groups with Alkaline Earth Catalysts.

Authors:  Srinivasarao Yaragorla; Dandugula Sneha Latha
Journal:  ACS Omega       Date:  2022-09-15

7.  Unified Approach to Diverse Fused Fragments via Catalytic Dehydrative Cyclization.

Authors:  Ashley J Basson; Nathan R Halcovitch; Mark G McLaughlin
Journal:  Chemistry       Date:  2022-07-04       Impact factor: 5.020

8.  Atomically confined calcium in nitrogen-doped graphene as an efficient heterogeneous catalyst for hydrogen evolution.

Authors:  Jie Sun; Suchun Li; Qi Zhao; Cunping Huang; Qiang Wu; Wei Chen; Qunjie Xu; Weifeng Yao
Journal:  iScience       Date:  2021-06-15
  8 in total

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