Literature DB >> 23695544

Thermal induced intramolecular [2 + 2] cycloaddition of allene-ACPs.

Kai Chen1, Run Sun, Qin Xu, Yin Wei, Min Shi.   

Abstract

A facile synthetic method for preparation of bicyclo[4.2.0] nitrogen heterocycles has been developed via a thermal induced intramolecular [2 + 2] cycloaddition reaction of allene-ACPs. The DFT calculations indicate that this intramolecular cycloaddition proceeds in a concerted manner and a strained small ring is essential.

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Year:  2013        PMID: 23695544     DOI: 10.1039/c3ob40911b

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN: 1477-0520            Impact factor:   3.876


  2 in total

1.  Click chemistry: Straining to react.

Authors:  John A Milligan; Peter Wipf
Journal:  Nat Chem       Date:  2016-04       Impact factor: 24.427

2.  A visible-light mediated ring opening reaction of alkylidenecyclopropanes for the generation of homopropargyl radicals.

Authors:  Xiao-Yu Zhang; Chao Ning; Ben Mao; Yin Wei; Min Shi
Journal:  Chem Sci       Date:  2021-05-28       Impact factor: 9.825

  2 in total

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