Literature DB >> 23683086

Palladium-catalyzed C-H arylation using phosphoramidate as a directing group at room temperature.

Bathoju Chandra Chary1, Sunggak Kim, Youngchul Park, Jinsik Kim, Phil Ho Lee.   

Abstract

This communication describes the first phosphoramidate directing group for synthetically useful arylation. Remarkably, the nature of a new directing group drives selective C-H bond activation to afford diverse N-aryl phosphoramidates in good to excellent yields at room temperature.

Entities:  

Year:  2013        PMID： 23683086     DOI： 10.1021/ol4009987

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  6 in total

Review 1.  A comprehensive overview of directing groups applied in metal-catalysed C-H functionalisation chemistry.

Authors:  Carlo Sambiagio; David Schönbauer; Remi Blieck; Toan Dao-Huy; Gerit Pototschnig; Patricia Schaaf; Thomas Wiesinger; Muhammad Farooq Zia; Joanna Wencel-Delord; Tatiana Besset; Bert U W Maes; Michael Schnürch
Journal:  Chem Soc Rev       Date:  2018-08-28       Impact factor: 54.564

Review 2.  Opening up the Toolbox: Synthesis and Mechanisms of Phosphoramidates.

Authors:  Emeka J Itumoh; Shailja Data; Erin M Leitao
Journal:  Molecules       Date:  2020-08-13       Impact factor: 4.411

3.  Synthesis of ethoxy dibenzooxaphosphorin oxides through palladium-catalyzed C(sp(2))-H activation/C-O formation.

Authors:  Seohyun Shin; Dongjin Kang; Woo Hyung Jeon; Phil Ho Lee
Journal:  Beilstein J Org Chem       Date:  2014-05-23       Impact factor: 2.883

4.  P(O)R2-directed Pd-catalyzed C-H functionalization of biaryl derivatives to synthesize chiral phosphorous ligands.

Authors:  Rong-Bin Hu; Hong-Li Wang; Hong-Yu Zhang; Heng Zhang; Yan-Na Ma; Shang-Dong Yang
Journal:  Beilstein J Org Chem       Date:  2014-09-02       Impact factor: 2.883

5.  Cationic Pd(II)-catalyzed C-H activation/cross-coupling reactions at room temperature: synthetic and mechanistic studies.

Authors:  Takashi Nishikata; Alexander R Abela; Shenlin Huang; Bruce H Lipshutz
Journal:  Beilstein J Org Chem       Date:  2016-05-20       Impact factor: 2.883

6.  Branch-Selective Alkene Hydroarylation by Cooperative Destabilization: Iridium-Catalyzed ortho-Alkylation of Acetanilides.

Authors:  Giacomo E M Crisenza; Olga O Sokolova; John F Bower
Journal:  Angew Chem Int Ed Engl       Date:  2015-10-22       Impact factor: 15.336
  6 in total

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