| Literature DB >> 23679016 |
Daisuke Uraguchi1, Ryosuke Tsutsumi, Takashi Ooi.
Abstract
An efficient and highly enantioselective Payne-type oxidation of N-sulfonyl imines is developed. The reaction exhibits broad substrate generality and unique chemoselectivity based on the combined use of hydrogen peroxide and trichloroacetonitrile under the catalysis of P-spiro chiral triaminoiminophosphorane.Entities:
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Year: 2013 PMID： 23679016 DOI： 10.1021/ja403491j
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419