Literature DB >> 23677241

Efficient epoxidation of olefins by H2O2 catalyzed by iron "helmet" phthalocyanines.

Igor Y Skobelev1, Evgeny V Kudrik, Olga V Zalomaeva, Florian Albrieux, Pavel Afanasiev, Oxana A Kholdeeva, Alexander B Sorokin.   

Abstract

High yields of epoxides were obtained in the oxidation of a large range of olefins using 1.2-2 equiv. of H2O2 in the presence of iron helmet phthalocyanines. The involvement of high-valent iron oxo species was evidenced using cryospray mass spectrometry.

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Year:  2013        PMID: 23677241     DOI: 10.1039/c3cc42301h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  5 in total

1.  Re(CO)3-Templated Synthesis of α-Amidinoazadi(benzopyrro)methenes.

Authors:  Allen J Osinski; Daniel L Morris; Richard S Herrick; Christopher J Ziegler
Journal:  Inorg Chem       Date:  2017-11-27       Impact factor: 5.165

2.  A Biomimetic, One-Step Transformation of Simple Indolic Compounds to Malassezia-Related Alkaloids with High AhR Potency and Efficacy.

Authors:  Nikitia Mexia; Stamatis Koutrakis; Guochun He; Alexios-Leandros Skaltsounis; Michael S Denison; Prokopios Magiatis
Journal:  Chem Res Toxicol       Date:  2019-11-07       Impact factor: 3.739

3.  Mechanistic Studies on the Hexadecafluorophthalocyanine-Iron-Catalyzed Wacker-Type Oxidation of Olefins to Ketones*.

Authors:  Florian Puls; Felix Seewald; Vadim Grinenko; Hans-Henning Klauß; Hans-Joachim Knölker
Journal:  Chemistry       Date:  2021-10-27       Impact factor: 5.020

4.  A Bottom Up Approach Towards Artificial Oxygenases by Combining Iron Coordination Complexes and Peptides.

Authors:  Olaf Cusso; Michael W Giuliano; Xavi Ribas; Scott J Miller; Miquel Costas
Journal:  Chem Sci       Date:  2017-03-03       Impact factor: 9.825

5.  Helmet Phthalocyaninato Iron Complex as a Primary Drier for Alkyd Paints.

Authors:  Jan Honzíček; Eliška Matušková; Štěpán Voneš; Jaromír Vinklárek
Journal:  Materials (Basel)       Date:  2021-03-05       Impact factor: 3.623

  5 in total

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