Literature DB >> 23675918

Cleavage of carbon-carbon triple bond: direct transformation of alkynes to nitriles.

Noriko Okamoto1, Minoru Ishikura, Reiko Yanada.   

Abstract

A new cleavage reaction of carbon-carbon triple bonds proceeds efficiently with NIS and TMSN3, giving the corresponding nitriles in moderate to good yields.

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Year:  2013        PMID： 23675918     DOI： 10.1021/ol401311h

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  4 in total

1.  Silver-Catalyzed Stereoselective Aminosulfonylation of Alkynes.

Authors:  Yongquan Ning; Qinghe Ji; Peiqiu Liao; Edward A Anderson; Xihe Bi
Journal:  Angew Chem Int Ed Engl       Date:  2017-07-07       Impact factor: 15.336

2.  Visible light-mediated photocatalytic oxidative cleavage of activated alkynes via hydroamination: a direct approach to oxamates.

Authors:  Narenderreddy Katta; Mamata Ojha; Arumugavel Murugan; Sagar Arepally; Duddu S Sharada
Journal:  RSC Adv       Date:  2020-03-27       Impact factor: 3.361

3.  Gold-catalyzed synthesis of tetrazoles from alkynes by C-C bond cleavage.

Authors:  Morgane Gaydou; Antonio M Echavarren
Journal:  Angew Chem Int Ed Engl       Date:  2013-11-13       Impact factor: 15.336

4.  Facile scission of isonitrile carbon-nitrogen triple bond using a diborane(4) reagent.

Authors:  Hiroki Asakawa; Ka-Ho Lee; Zhenyang Lin; Makoto Yamashita
Journal:  Nat Commun       Date:  2014-06-26       Impact factor: 14.919
  4 in total

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