| Literature DB >> 23675583 |
Natalie A Dixon1, Ashley B McQuarters, Jodi S Kraus, Jonathan B Soffer, Nicolai Lehnert, Reinhard Schweitzer-Stenner, Elizabeth T Papish.
Abstract
Complexes with bulky hydrotris(triazolyl)borate (Ttz) ligands, TtzCuCO, were used to probe how acids change the donor properties of Ttz ligands. (Ttz(tBu,Me))CuCO shows four distinct protonation states and a gradual increase in the CO stretch. The increased electrophilic nature of the Cu center upon protonation leads to enhanced C-H activation catalysis.Entities:
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Year: 2013 PMID： 23675583 DOI： 10.1039/c3cc00036b
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222