Literature DB >> 23659279

Asymmetric cross-dimerization between methyl methacrylate and substituted alkene by Ru(0)-bicyclononadiene complex.

Yuki Hiroi1, Nobuyuki Komine, Sanshiro Komiya, Masafumi Hirano.   

Abstract

New Ru(0)-naphthalene complexes containing a bicyclononadiene ligand catalyze the linear cross-dimerization between methyl methacrylate and substituted alkenes by an oxidative coupling mechanism. The chiral (S,S)-2-methylbicyclo[3.3.1]nona-2,6-diene complex (S,S)-1b catalyzes asymmetric linear cross-dimerization between methyl methacrylate and 2,5-dihydrofuran to give the cross-dimer in 74% yield in 80% ee.

Entities:  

Year:  2013        PMID: 23659279     DOI: 10.1021/ol400963d

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

1.  Cobalt-Catalysed Asymmetric Hydrovinylation of 1,3-Dienes.

Authors:  Yam N Timsina; Rakesh K Sharma; T V RajanBabu
Journal:  Chem Sci       Date:  2015-04-23       Impact factor: 9.825

2.  Diastereoselective carbocyclization of 1,6-heptadienes triggered by rhodium-catalyzed activation of an olefinic C-H bond.

Authors:  Christophe Aïssa; Kelvin Y T Ho; Daniel J Tetlow; María Pin-Nó
Journal:  Angew Chem Int Ed Engl       Date:  2014-03-14       Impact factor: 15.336

  2 in total

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