Literature DB >> 23657204

Spectroscopic properties and reactivity of a mononuclear oxomanganese(IV) complex.

Domenick F Leto1, Rena Ingram, Victor W Day, Timothy A Jackson.   

Abstract

A non-porphyrinic, mononuclear oxomanganese(IV) complex was generated at room temperature and characterized by spectroscopic methods. The Mn(IV)=O adduct is capable of activating C-H bonds by a H-atom transfer mechanism and is more reactive in this regard than most Mn(IV)=O species.

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Year:  2013        PMID： 23657204     DOI： 10.1039/c3cc00244f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  18 in total

1.  Steric control of dioxygen activation pathways for MnII complexes supported by pentadentate, amide-containing ligands.

Authors:  Joshua D Parham; Gayan B Wijeratne; Jaycee R Mayfield; Timothy A Jackson
Journal:  Dalton Trans       Date:  2019-08-13       Impact factor: 4.390

2.  Preparation and Properties of an MnIV-Hydroxide Complex: Proton and Electron Transfer at a Mononuclear Manganese Site and its Relationship to the Oxygen Evolving Complex within Photosystem II.

Authors:  Taketo Taguchi; Kari L Stone; Rupal Gupta; Benedikt Kaiser-Lassalle; Junko Yano; Michael P Hendrich; A S Borovik
Journal:  Chem Sci       Date:  2014-08-01       Impact factor: 9.825

3.  Thermodynamics of Proton and Electron Transfer in Tetranuclear Clusters with Mn-OH2/OH Motifs Relevant to H2O Activation by the Oxygen Evolving Complex in Photosystem II.

Authors:  Christopher J Reed; Theodor Agapie
Journal:  J Am Chem Soc       Date:  2018-08-16       Impact factor: 15.419

4.  Structural Characterization of a Series of N5-Ligated MnIV -Oxo Species.

Authors:  Allyssa A Massie; Melissa C Denler; Reena Singh; Arup Sinha; Ebbe Nordlander; Timothy A Jackson
Journal:  Chemistry       Date:  2019-12-20       Impact factor: 5.236

5.  Equatorial Ligand Perturbations Influence the Reactivity of Manganese(IV)-Oxo Complexes.

Authors:  Allyssa A Massie; Melissa C Denler; Luísa Thiara Cardoso; Ashlie N Walker; M Kamal Hossain; Victor W Day; Ebbe Nordlander; Timothy A Jackson
Journal:  Angew Chem Int Ed Engl       Date:  2017-03-16       Impact factor: 15.336

6.  A Reactive Manganese(IV)-Hydroxide Complex: A Missing Intermediate in Hydrogen Atom Transfer by High-Valent Metal-Oxo Porphyrinoid Compounds.

Authors:  Jan Paulo T Zaragoza; Maxime A Siegler; David P Goldberg
Journal:  J Am Chem Soc       Date:  2018-03-15       Impact factor: 15.419

7.  Reaction landscape of a pentadentate N5-ligated Mn(II) complex with O2˙- and H2O2 includes conversion of a peroxomanganese(III) adduct to a bis(μ-oxo)dimanganese(III,IV) species.

Authors:  Domenick F Leto; Swarup Chattopadhyay; Victor W Day; Timothy A Jackson
Journal:  Dalton Trans       Date:  2013-07-19       Impact factor: 4.390

8.  High-Valent Manganese-Oxo Valence Tautomers and the Influence of Lewis/Brönsted Acids on C-H Bond Cleavage.

Authors:  Regina A Baglia; Courtney M Krest; Tzuhsiung Yang; Pannee Leeladee; David P Goldberg
Journal:  Inorg Chem       Date:  2016-09-30       Impact factor: 5.165

9.  Mn K-edge X-ray absorption studies of mononuclear Mn(III)-hydroxo complexes.

Authors:  Derek B Rice; Gayan B Wijeratne; Timothy A Jackson
Journal:  J Biol Inorg Chem       Date:  2017-10-20       Impact factor: 3.358

10.  MnIII-Peroxo adduct supported by a new tetradentate ligand shows acid-sensitive aldehyde deformylation reactivity.

Authors:  Melissa C Denler; Gayan B Wijeratne; Derek B Rice; Hannah E Colmer; Victor W Day; Timothy A Jackson
Journal:  Dalton Trans       Date:  2018-10-02       Impact factor: 4.390
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