Literature DB >> 23656521

Ready synthetic access to enantiopure allylic α(F)-branched fluoroalkenes.

Florent Larnaud1, Julien Malassis, Emmanuel Pfund, Bruno Linclau, Thierry Lequeux.   

Abstract

Convenient access to homochiral fluoroalkenes is described via a Julia-Kocienski olefination reaction. The required homochiral fluorosulfone is synthesized by a Mitsunobu reaction from readily available enantiopure secondary alcohols.

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Year:  2013        PMID: 23656521     DOI: 10.1021/ol400917j

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  3 in total

1.  E- or Z-Selective synthesis of 4-fluorovinyl-1,2,3-triazoles with fluorinated second-generation Julia-Kocienski reagents.

Authors:  Rakesh Kumar; Govindra Singh; Louis J Todaro; Lijia Yang; Barbara Zajc
Journal:  Org Biomol Chem       Date:  2015-02-07       Impact factor: 3.876

2.  Ni-catalyzed migratory fluoro-alkenylation of unactivated alkyl bromides with gem-difluoroalkenes.

Authors:  Lu Zhou; Chuan Zhu; Peijia Bi; Chao Feng
Journal:  Chem Sci       Date:  2018-11-09       Impact factor: 9.825

3.  Synthesis of regiospecifically fluorinated conjugated dienamides.

Authors:  Mohammad Chowdhury; Samir K Mandal; Shaibal Banerjee; Barbara Zajc
Journal:  Molecules       Date:  2014-04-10       Impact factor: 4.411

  3 in total

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