[1,2-Bis(diisopropyl-phosphan-yl)ethane-κ(2) P,P'](carbonato-κ(2) O,O')nickel(II).

In the crystal of the title compound, [Ni(CO3)(C14H32P2)], the metal center in each of three independent mol-ecules shows slight tetra-hedral distortion from ideal square-planar coordination geometry, with angles between the normals to the planes defined by the cis-P-Ni-P and cis-O-Ni-O fragments of 3.92 (17), 0.70 (16) and 2.17 (14)° in the three mol-ecules. In the crystal, there are inter-molecular C-H⋯O hydrogen bonds that show a laminar growth in the ab plane.

Related literature

For the synthesis and related structures, see: González-Sebastián et al. (2012 ▶); Cañavera-Buelvas et al. (2011 ▶); Castellanos-Blanco et al. (2011 ▶); Angulo et al. (2003 ▶); Dahlenburg & Kurth (2001 ▶). For applications of nickel complexes to catalytic systems, see: Vicic & Jones (1997 ▶); Arévalo & García (2010 ▶). For nickel compounds in CO2 activation, see: Anderson et al. (2010 ▶); Aresta et al. (1975 ▶).

Experimental

Crystal data

[Ni(CO3)(C14H32P2)]

M = 381.06

Monoclinic,

a = 8.4974 (4) Å

b = 46.582 (2) Å

c = 14.7342 (7) Å

β = 103.618 (4)°

V = 5668.2 (5) Å3

Z = 12

Mo Kα radiation

μ = 1.20 mm−1

T = 130 K

0.33 × 0.06 × 0.03 mm

Data collection

Oxford Diffraction Xcalibur (Atlas, Gemini) diffractometer

Absorption correction: analytical (CrysAlis PRO; Oxford Diffraction, 2010 ▶) T min = 0.813, T max = 0.965

42978 measured reflections

10329 independent reflections

7642 reflections with I > 2σ(I)

R int = 0.088

Refinement

R[F 2 > 2σ(F 2)] = 0.062

wR(F 2) = 0.096

S = 1.09

10329 reflections

592 parameters

H-atom parameters constrained

Δρmax = 0.57 e Å−3

Δρmin = −0.59 e Å−3

Data collection: CrysAlis CCD (Oxford Diffraction, 2009 ▶); cell refinement: CrysAlis RED (Oxford Diffraction, 2009 ▶); data reduction: CrysAlis RED; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: ORTEP-3 for Windows (Farrugia, 2012 ▶); software used to prepare material for publication: WinGX (Farrugia, 2012 ▶).

Click here for additional data file.

Crystal structure: contains datablock(s) global, I. DOI: 10.1107/S1600536813006521/ru2049sup1.cif

Click here for additional data file.

Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536813006521/ru2049Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Ni(CO3)(C14H32P2)]	F(000) = 2448
Mr = 381.06	Dx = 1.34 Mg m−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71073 Å
a = 8.4974 (4) Å	Cell parameters from 6343 reflections
b = 46.582 (2) Å	θ = 3.4–29.5°
c = 14.7342 (7) Å	µ = 1.20 mm−1
β = 103.618 (4)°	T = 130 K
V = 5668.2 (5) Å3	Needle, pale yellow
Z = 12	0.33 × 0.06 × 0.03 mm

Oxford Diffraction Xcalibur (Atlas, Gemini) diffractometer	10329 independent reflections
Graphite monochromator	7642 reflections with I > 2σ(I)
Detector resolution: 10.4685 pixels mm-1	Rint = 0.088
ω scans	θmax = 25.4°, θmin = 3.4°
Absorption correction: analytical (CrysAlis PRO; Oxford Diffraction, 2010)	h = −10→10
Tmin = 0.813, Tmax = 0.965	k = −56→55
42978 measured reflections	l = −13→17

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.062	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.096	H-atom parameters constrained
S = 1.09	w = 1/[σ2(Fo2) + (0.0167P)2 + 0.6693P] where P = (Fo2 + 2Fc2)/3
10329 reflections	(Δ/σ)max = 0.001
592 parameters	Δρmax = 0.57 e Å−3
0 restraints	Δρmin = −0.59 e Å−3

Geometry. All s.u.'s (except the s.u. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell s.u.'s are taken into account individually in the estimation of s.u.'s in distances, angles and torsion angles; correlations between s.u.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell s.u.'s is used for estimating s.u.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > 2σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
C1A	0.0622 (4)	0.19012 (9)	0.3969 (3)	0.0260 (11)
H1A1	0.0615	0.1964	0.4611	0.031*
H1A2	0.0722	0.169	0.3969	0.031*
C2A	0.2069 (5)	0.20374 (10)	0.3671 (3)	0.0317 (12)
H2A1	0.2366	0.1919	0.3179	0.038*
H2A2	0.3014	0.2046	0.4212	0.038*
C3A	0.2999 (5)	0.24984 (10)	0.2547 (3)	0.0295 (11)
H3A	0.4108	0.2472	0.2957	0.035*
C4A	0.2828 (5)	0.22929 (11)	0.1706 (3)	0.0365 (12)
H4A1	0.176	0.2318	0.1283	0.055*
H4A2	0.2944	0.2094	0.1929	0.055*
H4A3	0.3672	0.2336	0.1373	0.055*
C5A	0.2843 (5)	0.28071 (11)	0.2228 (4)	0.0429 (14)
H5A1	0.3655	0.2849	0.1872	0.064*
H5A2	0.3015	0.2934	0.2774	0.064*
H5A3	0.1757	0.2839	0.1833	0.064*
C6A	0.1872 (5)	0.26167 (10)	0.4291 (3)	0.0334 (12)
H6A	0.1319	0.2511	0.4719	0.04*
C7A	0.3645 (5)	0.26406 (12)	0.4821 (3)	0.0446 (14)
H7A1	0.4255	0.2745	0.444	0.067*
H7A2	0.4104	0.2448	0.4955	0.067*
H7A3	0.3714	0.2744	0.5409	0.067*
C8A	0.1082 (6)	0.29068 (12)	0.4154 (4)	0.0540 (16)
H8A1	0.0955	0.298	0.4756	0.081*
H8A2	0.0016	0.2891	0.3721	0.081*
H8A3	0.176	0.3039	0.3895	0.081*
C9A	−0.1868 (5)	0.17146 (9)	0.2339 (3)	0.0281 (11)
H9A	−0.1931	0.1536	0.2704	0.034*
C10A	−0.0589 (5)	0.16688 (11)	0.1779 (3)	0.0404 (13)
H10A	−0.0914	0.1509	0.1343	0.061*
H10B	0.0453	0.1624	0.2206	0.061*
H10C	−0.0484	0.1844	0.1428	0.061*
C11A	−0.3540 (5)	0.17688 (10)	0.1700 (3)	0.0396 (13)
H11A	−0.3556	0.1958	0.1409	0.059*
H11B	−0.4361	0.1762	0.2069	0.059*
H11C	−0.3775	0.1621	0.1214	0.059*
C12A	−0.2795 (5)	0.20298 (10)	0.3847 (3)	0.0304 (11)
H12A	−0.3867	0.2059	0.34	0.036*
C13A	−0.2494 (6)	0.22872 (12)	0.4501 (3)	0.0444 (14)
H13A	−0.3357	0.23	0.4838	0.067*
H13B	−0.2484	0.2463	0.4136	0.067*
H13C	−0.1448	0.2265	0.4948	0.067*
C14A	−0.2903 (6)	0.17527 (12)	0.4394 (4)	0.0522 (15)
H14A	−0.188	0.1722	0.4855	0.078*
H14B	−0.3113	0.159	0.3962	0.078*
H14C	−0.3787	0.177	0.4715	0.078*
C15A	−0.2766 (5)	0.27222 (9)	0.1602 (3)	0.0198 (10)
Ni1A	−0.09895 (6)	0.241123 (11)	0.25206 (4)	0.01761 (14)
O1A	−0.3167 (3)	0.24726 (6)	0.1911 (2)	0.0264 (7)
O2A	−0.1191 (3)	0.27667 (6)	0.18928 (19)	0.0223 (7)
O3A	−0.3730 (3)	0.28892 (6)	0.11296 (19)	0.0271 (7)
P1A	−0.12663 (12)	0.20091 (2)	0.31662 (8)	0.0214 (3)
P2A	0.15252 (12)	0.24007 (3)	0.32275 (8)	0.0228 (3)
C1B	0.4161 (4)	0.03946 (9)	0.1585 (3)	0.0208 (10)
H1B1	0.4405	0.0188	0.1704	0.025*
H1B2	0.297	0.0419	0.144	0.025*
C2B	0.4810 (4)	0.04938 (9)	0.0755 (3)	0.0201 (10)
H2B1	0.4232	0.0669	0.0478	0.024*
H2B2	0.4638	0.0342	0.0271	0.024*
C3B	0.7525 (5)	0.07725 (9)	0.0237 (3)	0.0240 (10)
H3B	0.7128	0.0666	−0.0362	0.029*
C4B	0.6691 (6)	0.10641 (10)	0.0144 (3)	0.0397 (13)
H4B1	0.6932	0.116	0.0753	0.06*
H4B2	0.5519	0.1038	−0.0073	0.06*
H4B3	0.7087	0.1182	−0.0307	0.06*
C5B	0.9357 (5)	0.08070 (11)	0.0401 (3)	0.0389 (13)
H5B1	0.9608	0.0925	−0.0097	0.058*
H5B2	0.986	0.0618	0.0401	0.058*
H5B3	0.9781	0.09	0.1006	0.058*
C6B	0.7921 (4)	0.02135 (9)	0.1257 (3)	0.0187 (10)
H6B	0.7227	0.0085	0.1542	0.022*
C7B	0.7946 (5)	0.00803 (10)	0.0308 (3)	0.0270 (11)
H7B1	0.8736	0.0182	0.0037	0.04*
H7B2	0.6868	0.0096	−0.0112	0.04*
H7B3	0.825	−0.0123	0.0393	0.04*
C8B	0.9599 (4)	0.02111 (10)	0.1927 (3)	0.0289 (11)
H8B1	0.9987	0.0013	0.2028	0.043*
H8B2	0.9531	0.0296	0.2526	0.043*
H8B3	1.0354	0.0323	0.1658	0.043*
C9B	0.3595 (4)	0.08739 (10)	0.2764 (3)	0.0267 (11)
H9B	0.2538	0.0774	0.2725	0.032*
C10B	0.4088 (5)	0.10235 (11)	0.3715 (4)	0.0437 (14)
H10D	0.515	0.1114	0.378	0.065*
H10E	0.4146	0.0882	0.4213	0.065*
H10F	0.3283	0.117	0.3759	0.065*
C11B	0.3360 (5)	0.10932 (11)	0.1977 (4)	0.0439 (14)
H11D	0.2513	0.123	0.2037	0.066*
H11E	0.3038	0.0994	0.1374	0.066*
H11F	0.4377	0.1197	0.2012	0.066*
C12B	0.5298 (4)	0.03565 (10)	0.3619 (3)	0.0239 (10)
H12B	0.5646	0.0473	0.4202	0.029*
C13B	0.6622 (5)	0.01380 (10)	0.3618 (3)	0.0307 (11)
H13D	0.6762	0.0016	0.4173	0.046*
H13E	0.7639	0.0238	0.3625	0.046*
H13F	0.632	0.0019	0.3055	0.046*
C14B	0.3705 (5)	0.02115 (11)	0.3657 (3)	0.0383 (13)
H14D	0.3359	0.0086	0.3113	0.057*
H14E	0.2876	0.0358	0.3651	0.057*
H14F	0.3857	0.0098	0.423	0.057*
C15B	0.9336 (4)	0.10590 (9)	0.3390 (3)	0.0195 (10)
Ni1B	0.73598 (5)	0.077729 (11)	0.24982 (4)	0.01499 (13)
O1B	0.7989 (3)	0.09799 (6)	0.36375 (18)	0.0198 (7)
O2B	0.9390 (3)	0.09517 (6)	0.25715 (19)	0.0204 (7)
O3B	1.0375 (3)	0.12153 (6)	0.38621 (19)	0.0250 (7)
P1B	0.50899 (11)	0.06037 (2)	0.26289 (7)	0.0180 (3)
P2B	0.69677 (11)	0.05682 (2)	0.11706 (7)	0.0153 (2)
C1C	0.0137 (4)	0.14384 (9)	0.6708 (3)	0.0212 (10)
H1C1	−0.0619	0.1474	0.7115	0.025*
H1C2	0.0272	0.162	0.6385	0.025*
C2C	−0.0556 (4)	0.12052 (9)	0.5987 (3)	0.0229 (10)
H2C1	−0.0037	0.1217	0.5453	0.027*
H2C2	−0.1735	0.1234	0.5749	0.027*
C3C	−0.0352 (4)	0.05938 (9)	0.5589 (3)	0.0188 (9)
H3C	−0.1338	0.0641	0.5091	0.023*
C4C	0.1129 (5)	0.06146 (10)	0.5169 (3)	0.0300 (11)
H4C1	0.2098	0.0556	0.5636	0.045*
H4C2	0.1257	0.0813	0.4978	0.045*
H4C3	0.098	0.0488	0.4624	0.045*
C5C	−0.0524 (5)	0.02856 (9)	0.5923 (3)	0.0237 (10)
H5C1	−0.0582	0.0152	0.5402	0.036*
H5C2	−0.1514	0.027	0.6152	0.036*
H5C3	0.0415	0.0238	0.6428	0.036*
C6C	−0.1881 (4)	0.08059 (10)	0.7094 (3)	0.0225 (10)
H6C	−0.2004	0.0993	0.7402	0.027*
C7C	−0.3499 (4)	0.07530 (10)	0.6393 (3)	0.0290 (11)
H7C1	−0.3472	0.0566	0.6094	0.044*
H7C2	−0.3682	0.0904	0.5916	0.044*
H7C3	−0.4379	0.0756	0.672	0.044*
C8C	−0.1566 (5)	0.05835 (10)	0.7871 (3)	0.0281 (11)
H8C1	−0.2466	0.0583	0.8181	0.042*
H8C2	−0.0558	0.063	0.8325	0.042*
H8C3	−0.147	0.0393	0.7605	0.042*
C9C	0.3637 (4)	0.14924 (9)	0.6907 (3)	0.0233 (10)
H9C	0.3468	0.1705	0.6917	0.028*
C10C	0.3441 (5)	0.14000 (11)	0.5898 (3)	0.0353 (12)
H10G	0.4288	0.1489	0.5643	0.053*
H10H	0.2376	0.146	0.5531	0.053*
H10I	0.3533	0.1191	0.5869	0.053*
C11C	0.5336 (4)	0.14270 (10)	0.7485 (3)	0.0286 (11)
H11G	0.5498	0.1219	0.7526	0.043*
H11H	0.5465	0.1507	0.8114	0.043*
H11I	0.6137	0.1514	0.7187	0.043*
C12C	0.2326 (5)	0.14893 (9)	0.8573 (3)	0.0241 (10)
H12C	0.3496	0.1475	0.8901	0.029*
C13C	0.1385 (6)	0.13196 (11)	0.9153 (3)	0.0457 (14)
H13G	0.159	0.1401	0.9784	0.069*
H13H	0.1734	0.1119	0.9188	0.069*
H13I	0.0225	0.133	0.886	0.069*
C14C	0.1893 (5)	0.18064 (10)	0.8518 (3)	0.0333 (12)
H14G	0.073	0.1829	0.8248	0.05*
H14H	0.2504	0.1905	0.8125	0.05*
H14I	0.2166	0.1889	0.9147	0.05*
C15C	0.3927 (4)	0.05090 (9)	0.8190 (3)	0.0196 (10)
Ni1C	0.21570 (5)	0.085830 (11)	0.74854 (4)	0.01691 (13)
O1C	0.4212 (3)	0.07890 (6)	0.82835 (19)	0.0234 (7)
O2C	0.2466 (3)	0.04613 (6)	0.76615 (19)	0.0220 (7)
O3C	0.4888 (3)	0.03226 (6)	0.85383 (19)	0.0231 (7)
P1C	0.21058 (12)	0.13190 (2)	0.74185 (8)	0.0189 (3)
P2C	−0.01785 (11)	0.08543 (2)	0.65341 (7)	0.0171 (2)

	U11	U22	U33	U12	U13	U23
C1A	0.030 (2)	0.016 (3)	0.028 (3)	0.0080 (19)	−0.0017 (19)	0.005 (2)
C2A	0.026 (2)	0.030 (3)	0.035 (3)	0.009 (2)	−0.001 (2)	0.006 (2)
C3A	0.018 (2)	0.035 (3)	0.034 (3)	−0.001 (2)	0.0039 (19)	−0.001 (2)
C4A	0.034 (3)	0.041 (3)	0.037 (3)	−0.001 (2)	0.015 (2)	−0.003 (3)
C5A	0.038 (3)	0.047 (4)	0.047 (4)	−0.008 (2)	0.016 (2)	0.012 (3)
C6A	0.027 (2)	0.035 (3)	0.034 (3)	−0.004 (2)	0.000 (2)	−0.010 (2)
C7A	0.032 (3)	0.054 (4)	0.042 (3)	−0.004 (2)	−0.005 (2)	−0.014 (3)
C8A	0.061 (3)	0.046 (4)	0.046 (4)	0.009 (3)	−0.006 (3)	−0.017 (3)
C9A	0.035 (2)	0.011 (2)	0.033 (3)	−0.0028 (19)	−0.004 (2)	0.002 (2)
C10A	0.050 (3)	0.029 (3)	0.039 (3)	0.003 (2)	0.004 (2)	−0.014 (2)
C11A	0.041 (3)	0.022 (3)	0.045 (3)	0.001 (2)	−0.011 (2)	−0.003 (2)
C12A	0.034 (2)	0.026 (3)	0.033 (3)	−0.003 (2)	0.011 (2)	0.007 (2)
C13A	0.048 (3)	0.052 (4)	0.039 (3)	0.019 (3)	0.021 (2)	0.005 (3)
C14A	0.054 (3)	0.049 (4)	0.060 (4)	0.001 (3)	0.027 (3)	0.025 (3)
C15A	0.031 (2)	0.014 (2)	0.013 (2)	0.0052 (19)	0.0028 (18)	−0.0026 (19)
Ni1A	0.0189 (3)	0.0126 (3)	0.0195 (3)	0.0011 (2)	0.0009 (2)	0.0015 (2)
O1A	0.0207 (15)	0.0216 (18)	0.0339 (19)	−0.0012 (13)	0.0005 (12)	0.0099 (15)
O2A	0.0219 (15)	0.0147 (17)	0.0279 (18)	0.0003 (12)	0.0011 (12)	0.0043 (13)
O3A	0.0320 (16)	0.0214 (18)	0.0234 (18)	0.0081 (14)	−0.0024 (13)	0.0046 (14)
P1A	0.0227 (6)	0.0149 (6)	0.0240 (7)	0.0013 (5)	0.0001 (5)	0.0031 (5)
P2A	0.0190 (5)	0.0212 (7)	0.0257 (7)	−0.0001 (5)	0.0004 (5)	0.0001 (5)
C1B	0.0146 (19)	0.024 (3)	0.021 (3)	−0.0017 (18)	0.0000 (17)	−0.003 (2)
C2B	0.0146 (19)	0.027 (3)	0.018 (2)	0.0008 (18)	0.0021 (16)	−0.004 (2)
C3B	0.036 (2)	0.023 (3)	0.014 (2)	−0.010 (2)	0.0070 (18)	0.000 (2)
C4B	0.064 (3)	0.022 (3)	0.031 (3)	−0.012 (2)	0.007 (2)	0.006 (2)
C5B	0.045 (3)	0.049 (4)	0.027 (3)	−0.024 (3)	0.018 (2)	0.002 (2)
C6B	0.018 (2)	0.014 (2)	0.023 (3)	−0.0004 (17)	0.0038 (17)	0.0015 (19)
C7B	0.024 (2)	0.025 (3)	0.031 (3)	0.0029 (19)	0.0052 (19)	−0.011 (2)
C8B	0.023 (2)	0.029 (3)	0.032 (3)	0.002 (2)	0.0027 (19)	−0.001 (2)
C9B	0.019 (2)	0.032 (3)	0.031 (3)	0.000 (2)	0.0095 (18)	−0.011 (2)
C10B	0.027 (2)	0.049 (4)	0.056 (4)	0.003 (2)	0.012 (2)	−0.027 (3)
C11B	0.036 (3)	0.034 (3)	0.062 (4)	0.013 (2)	0.012 (2)	−0.002 (3)
C12B	0.023 (2)	0.032 (3)	0.018 (3)	−0.010 (2)	0.0069 (18)	−0.005 (2)
C13B	0.037 (3)	0.034 (3)	0.022 (3)	−0.003 (2)	0.008 (2)	0.007 (2)
C14B	0.034 (3)	0.053 (4)	0.030 (3)	−0.011 (2)	0.012 (2)	0.008 (3)
C15B	0.023 (2)	0.013 (2)	0.018 (3)	−0.0016 (18)	−0.0032 (18)	0.0047 (19)
Ni1B	0.0141 (2)	0.0162 (3)	0.0144 (3)	−0.0024 (2)	0.0028 (2)	−0.0025 (2)
O1B	0.0186 (14)	0.0237 (17)	0.0173 (17)	−0.0043 (12)	0.0044 (12)	−0.0058 (13)
O2B	0.0173 (14)	0.0265 (18)	0.0169 (17)	−0.0090 (12)	0.0031 (11)	−0.0040 (14)
O3B	0.0250 (15)	0.0214 (18)	0.0246 (18)	−0.0047 (13)	−0.0021 (12)	−0.0014 (14)
P1B	0.0153 (5)	0.0207 (6)	0.0184 (7)	−0.0013 (5)	0.0047 (4)	−0.0047 (5)
P2B	0.0162 (5)	0.0151 (6)	0.0145 (6)	−0.0025 (4)	0.0036 (4)	−0.0006 (5)
C1C	0.025 (2)	0.013 (2)	0.028 (3)	0.0046 (18)	0.0096 (18)	0.009 (2)
C2C	0.020 (2)	0.022 (3)	0.025 (3)	0.0040 (19)	0.0026 (18)	0.001 (2)
C3C	0.020 (2)	0.021 (3)	0.015 (2)	0.0029 (18)	0.0052 (17)	−0.0022 (19)
C4C	0.041 (3)	0.029 (3)	0.023 (3)	0.006 (2)	0.014 (2)	0.002 (2)
C5C	0.026 (2)	0.022 (3)	0.024 (3)	0.0001 (19)	0.0064 (18)	−0.007 (2)
C6C	0.020 (2)	0.027 (3)	0.022 (3)	0.0052 (19)	0.0075 (17)	−0.005 (2)
C7C	0.023 (2)	0.030 (3)	0.035 (3)	−0.002 (2)	0.0091 (19)	−0.004 (2)
C8C	0.033 (2)	0.031 (3)	0.023 (3)	−0.004 (2)	0.013 (2)	0.001 (2)
C9C	0.027 (2)	0.013 (2)	0.032 (3)	−0.0003 (18)	0.0121 (19)	0.004 (2)
C10C	0.034 (3)	0.044 (3)	0.032 (3)	0.001 (2)	0.015 (2)	0.012 (2)
C11C	0.021 (2)	0.028 (3)	0.037 (3)	−0.004 (2)	0.0090 (19)	−0.004 (2)
C12C	0.032 (2)	0.019 (3)	0.023 (3)	−0.0006 (19)	0.0099 (19)	0.000 (2)
C13C	0.074 (4)	0.034 (3)	0.040 (4)	−0.012 (3)	0.034 (3)	−0.006 (3)
C14C	0.044 (3)	0.023 (3)	0.034 (3)	−0.001 (2)	0.010 (2)	−0.008 (2)
C15C	0.019 (2)	0.024 (3)	0.017 (3)	−0.002 (2)	0.0054 (18)	−0.004 (2)
Ni1C	0.0175 (3)	0.0123 (3)	0.0202 (3)	0.0011 (2)	0.0029 (2)	0.0022 (2)
O1C	0.0202 (14)	0.0162 (17)	0.0295 (19)	−0.0020 (12)	−0.0030 (12)	−0.0007 (14)
O2C	0.0171 (14)	0.0165 (16)	0.0277 (18)	0.0028 (12)	−0.0039 (12)	0.0004 (13)
O3C	0.0216 (14)	0.0179 (17)	0.0268 (18)	0.0047 (13)	−0.0004 (12)	0.0065 (14)
P1C	0.0198 (5)	0.0145 (6)	0.0228 (7)	0.0012 (5)	0.0061 (4)	0.0027 (5)
P2C	0.0183 (5)	0.0142 (6)	0.0185 (6)	0.0021 (5)	0.0039 (4)	0.0007 (5)

C1A—C2A	1.537 (6)	C9B—C10B	1.532 (6)
C1A—P1A	1.825 (4)	C9B—P1B	1.832 (4)
C1A—H1A1	0.99	C9B—H9B	1
C1A—H1A2	0.99	C10B—H10D	0.98
C2A—P2A	1.833 (4)	C10B—H10E	0.98
C2A—H2A1	0.99	C10B—H10F	0.98
C2A—H2A2	0.99	C11B—H11D	0.98
C3A—C5A	1.509 (6)	C11B—H11E	0.98
C3A—C4A	1.545 (6)	C11B—H11F	0.98
C3A—P2A	1.837 (4)	C12B—C13B	1.517 (6)
C3A—H3A	1	C12B—C14B	1.525 (5)
C4A—H4A1	0.98	C12B—P1B	1.834 (4)
C4A—H4A2	0.98	C12B—H12B	1
C4A—H4A3	0.98	C13B—H13D	0.98
C5A—H5A1	0.98	C13B—H13E	0.98
C5A—H5A2	0.98	C13B—H13F	0.98
C5A—H5A3	0.98	C14B—H14D	0.98
C6A—C8A	1.501 (6)	C14B—H14E	0.98
C6A—C7A	1.530 (5)	C14B—H14F	0.98
C6A—P2A	1.827 (5)	C15B—O3B	1.227 (4)
C6A—H6A	1	C15B—O2B	1.316 (5)
C7A—H7A1	0.98	C15B—O1B	1.332 (4)
C7A—H7A2	0.98	C15B—Ni1B	2.287 (4)
C7A—H7A3	0.98	Ni1B—O2B	1.887 (2)
C8A—H8A1	0.98	Ni1B—O1B	1.890 (3)
C8A—H8A2	0.98	Ni1B—P2B	2.1399 (12)
C8A—H8A3	0.98	Ni1B—P1B	2.1415 (11)
C9A—C10A	1.526 (6)	C1C—C2C	1.536 (6)
C9A—C11A	1.529 (5)	C1C—P1C	1.838 (4)
C9A—P1A	1.826 (4)	C1C—H1C1	0.99
C9A—H9A	1	C1C—H1C2	0.99
C10A—H10A	0.98	C2C—P2C	1.817 (4)
C10A—H10B	0.98	C2C—H2C1	0.99
C10A—H10C	0.98	C2C—H2C2	0.99
C11A—H11A	0.98	C3C—C4C	1.531 (5)
C11A—H11B	0.98	C3C—C5C	1.536 (6)
C11A—H11C	0.98	C3C—P2C	1.827 (4)
C12A—C13A	1.521 (7)	C3C—H3C	1
C12A—C14A	1.536 (6)	C4C—H4C1	0.98
C12A—P1A	1.821 (4)	C4C—H4C2	0.98
C12A—H12A	1	C4C—H4C3	0.98
C13A—H13A	0.98	C5C—H5C1	0.98
C13A—H13B	0.98	C5C—H5C2	0.98
C13A—H13C	0.98	C5C—H5C3	0.98
C14A—H14A	0.98	C6C—C8C	1.520 (6)
C14A—H14B	0.98	C6C—C7C	1.533 (5)
C14A—H14C	0.98	C6C—P2C	1.841 (4)
C15A—O3A	1.221 (4)	C6C—H6C	1
C15A—O2A	1.322 (4)	C7C—H7C1	0.98
C15A—O1A	1.322 (5)	C7C—H7C2	0.98
C15A—Ni1A	2.291 (4)	C7C—H7C3	0.98
Ni1A—O1A	1.879 (2)	C8C—H8C1	0.98
Ni1A—O2A	1.885 (3)	C8C—H8C2	0.98
Ni1A—P1A	2.1390 (12)	C8C—H8C3	0.98
Ni1A—P2A	2.1460 (11)	C9C—C10C	1.520 (6)
C1B—C2B	1.526 (5)	C9C—C11C	1.524 (5)
C1B—P1B	1.835 (4)	C9C—P1C	1.837 (4)
C1B—H1B1	0.99	C9C—H9C	1
C1B—H1B2	0.99	C10C—H10G	0.98
C2B—P2B	1.825 (3)	C10C—H10H	0.98
C2B—H2B1	0.99	C10C—H10I	0.98
C2B—H2B2	0.99	C11C—H11G	0.98
C3B—C4B	1.523 (6)	C11C—H11H	0.98
C3B—C5B	1.527 (5)	C11C—H11I	0.98
C3B—P2B	1.825 (4)	C12C—C14C	1.520 (6)
C3B—H3B	1	C12C—C13C	1.522 (6)
C4B—H4B1	0.98	C12C—P1C	1.847 (4)
C4B—H4B2	0.98	C12C—H12C	1
C4B—H4B3	0.98	C13C—H13G	0.98
C5B—H5B1	0.98	C13C—H13H	0.98
C5B—H5B2	0.98	C13C—H13I	0.98
C5B—H5B3	0.98	C14C—H14G	0.98
C6B—C8B	1.532 (5)	C14C—H14H	0.98
C6B—C7B	1.535 (5)	C14C—H14I	0.98
C6B—P2B	1.831 (4)	C15C—O3C	1.220 (4)
C6B—H6B	1	C15C—O2C	1.320 (4)
C7B—H7B1	0.98	C15C—O1C	1.328 (5)
C7B—H7B2	0.98	C15C—Ni1C	2.291 (4)
C7B—H7B3	0.98	Ni1C—O2C	1.877 (3)
C8B—H8B1	0.98	Ni1C—O1C	1.889 (2)
C8B—H8B2	0.98	Ni1C—P2C	2.1433 (10)
C8B—H8B3	0.98	Ni1C—P1C	2.1481 (12)
C9B—C11B	1.523 (6)
C2A—C1A—P1A	110.0 (3)	C9B—C10B—H10F	109.5
C2A—C1A—H1A1	109.7	H10D—C10B—H10F	109.5
P1A—C1A—H1A1	109.7	H10E—C10B—H10F	109.5
C2A—C1A—H1A2	109.7	C9B—C11B—H11D	109.5
P1A—C1A—H1A2	109.7	C9B—C11B—H11E	109.5
H1A1—C1A—H1A2	108.2	H11D—C11B—H11E	109.5
C1A—C2A—P2A	109.4 (3)	C9B—C11B—H11F	109.5
C1A—C2A—H2A1	109.8	H11D—C11B—H11F	109.5
P2A—C2A—H2A1	109.8	H11E—C11B—H11F	109.5
C1A—C2A—H2A2	109.8	C13B—C12B—C14B	111.6 (4)
P2A—C2A—H2A2	109.8	C13B—C12B—P1B	110.7 (3)
H2A1—C2A—H2A2	108.2	C14B—C12B—P1B	112.8 (3)
C5A—C3A—C4A	110.9 (4)	C13B—C12B—H12B	107.2
C5A—C3A—P2A	112.6 (3)	C14B—C12B—H12B	107.2
C4A—C3A—P2A	109.7 (3)	P1B—C12B—H12B	107.2
C5A—C3A—H3A	107.8	C12B—C13B—H13D	109.5
C4A—C3A—H3A	107.8	C12B—C13B—H13E	109.5
P2A—C3A—H3A	107.8	H13D—C13B—H13E	109.5
C3A—C4A—H4A1	109.5	C12B—C13B—H13F	109.5
C3A—C4A—H4A2	109.5	H13D—C13B—H13F	109.5
H4A1—C4A—H4A2	109.5	H13E—C13B—H13F	109.5
C3A—C4A—H4A3	109.5	C12B—C14B—H14D	109.5
H4A1—C4A—H4A3	109.5	C12B—C14B—H14E	109.5
H4A2—C4A—H4A3	109.5	H14D—C14B—H14E	109.5
C3A—C5A—H5A1	109.5	C12B—C14B—H14F	109.5
C3A—C5A—H5A2	109.5	H14D—C14B—H14F	109.5
H5A1—C5A—H5A2	109.5	H14E—C14B—H14F	109.5
C3A—C5A—H5A3	109.5	O3B—C15B—O2B	124.7 (4)
H5A1—C5A—H5A3	109.5	O3B—C15B—O1B	124.0 (4)
H5A2—C5A—H5A3	109.5	O2B—C15B—O1B	111.3 (3)
C8A—C6A—C7A	111.0 (4)	O3B—C15B—Ni1B	178.6 (3)
C8A—C6A—P2A	113.8 (3)	O2B—C15B—Ni1B	55.59 (18)
C7A—C6A—P2A	114.8 (3)	O1B—C15B—Ni1B	55.71 (18)
C8A—C6A—H6A	105.4	O2B—Ni1B—O1B	70.75 (11)
C7A—C6A—H6A	105.4	O2B—Ni1B—P2B	101.06 (9)
P2A—C6A—H6A	105.4	O1B—Ni1B—P2B	171.81 (8)
C6A—C7A—H7A1	109.5	O2B—Ni1B—P1B	171.17 (9)
C6A—C7A—H7A2	109.5	O1B—Ni1B—P1B	100.44 (8)
H7A1—C7A—H7A2	109.5	P2B—Ni1B—P1B	87.75 (4)
C6A—C7A—H7A3	109.5	O2B—Ni1B—C15B	35.14 (13)
H7A1—C7A—H7A3	109.5	O1B—Ni1B—C15B	35.62 (13)
H7A2—C7A—H7A3	109.5	P2B—Ni1B—C15B	136.19 (11)
C6A—C8A—H8A1	109.5	P1B—Ni1B—C15B	136.06 (12)
C6A—C8A—H8A2	109.5	C15B—O1B—Ni1B	88.7 (2)
H8A1—C8A—H8A2	109.5	C15B—O2B—Ni1B	89.3 (2)
C6A—C8A—H8A3	109.5	C9B—P1B—C12B	106.5 (2)
H8A1—C8A—H8A3	109.5	C9B—P1B—C1B	106.47 (18)
H8A2—C8A—H8A3	109.5	C12B—P1B—C1B	106.0 (2)
C10A—C9A—C11A	111.6 (4)	C9B—P1B—Ni1B	114.38 (15)
C10A—C9A—P1A	110.0 (3)	C12B—P1B—Ni1B	112.86 (12)
C11A—C9A—P1A	111.1 (3)	C1B—P1B—Ni1B	110.11 (13)
C10A—C9A—H9A	108	C2B—P2B—C3B	105.38 (18)
C11A—C9A—H9A	108	C2B—P2B—C6B	104.17 (18)
P1A—C9A—H9A	108	C3B—P2B—C6B	109.5 (2)
C9A—C10A—H10A	109.5	C2B—P2B—Ni1B	108.71 (14)
C9A—C10A—H10B	109.5	C3B—P2B—Ni1B	116.09 (15)
H10A—C10A—H10B	109.5	C6B—P2B—Ni1B	112.08 (13)
C9A—C10A—H10C	109.5	C2C—C1C—P1C	109.2 (3)
H10A—C10A—H10C	109.5	C2C—C1C—H1C1	109.8
H10B—C10A—H10C	109.5	P1C—C1C—H1C1	109.8
C9A—C11A—H11A	109.5	C2C—C1C—H1C2	109.8
C9A—C11A—H11B	109.5	P1C—C1C—H1C2	109.8
H11A—C11A—H11B	109.5	H1C1—C1C—H1C2	108.3
C9A—C11A—H11C	109.5	C1C—C2C—P2C	109.3 (3)
H11A—C11A—H11C	109.5	C1C—C2C—H2C1	109.8
H11B—C11A—H11C	109.5	P2C—C2C—H2C1	109.8
C13A—C12A—C14A	110.6 (4)	C1C—C2C—H2C2	109.8
C13A—C12A—P1A	110.8 (3)	P2C—C2C—H2C2	109.8
C14A—C12A—P1A	112.5 (3)	H2C1—C2C—H2C2	108.3
C13A—C12A—H12A	107.5	C4C—C3C—C5C	109.7 (3)
C14A—C12A—H12A	107.5	C4C—C3C—P2C	109.8 (3)
P1A—C12A—H12A	107.5	C5C—C3C—P2C	111.9 (3)
C12A—C13A—H13A	109.5	C4C—C3C—H3C	108.4
C12A—C13A—H13B	109.5	C5C—C3C—H3C	108.4
H13A—C13A—H13B	109.5	P2C—C3C—H3C	108.4
C12A—C13A—H13C	109.5	C3C—C4C—H4C1	109.5
H13A—C13A—H13C	109.5	C3C—C4C—H4C2	109.5
H13B—C13A—H13C	109.5	H4C1—C4C—H4C2	109.5
C12A—C14A—H14A	109.5	C3C—C4C—H4C3	109.5
C12A—C14A—H14B	109.5	H4C1—C4C—H4C3	109.5
H14A—C14A—H14B	109.5	H4C2—C4C—H4C3	109.5
C12A—C14A—H14C	109.5	C3C—C5C—H5C1	109.5
H14A—C14A—H14C	109.5	C3C—C5C—H5C2	109.5
H14B—C14A—H14C	109.5	H5C1—C5C—H5C2	109.5
O3A—C15A—O2A	125.2 (4)	C3C—C5C—H5C3	109.5
O3A—C15A—O1A	124.3 (4)	H5C1—C5C—H5C3	109.5
O2A—C15A—O1A	110.5 (3)	H5C2—C5C—H5C3	109.5
O3A—C15A—Ni1A	178.5 (3)	C8C—C6C—C7C	111.7 (4)
O2A—C15A—Ni1A	55.36 (18)	C8C—C6C—P2C	113.8 (3)
O1A—C15A—Ni1A	55.10 (18)	C7C—C6C—P2C	113.1 (3)
O1A—Ni1A—O2A	70.50 (11)	C8C—C6C—H6C	105.8
O1A—Ni1A—P1A	98.44 (9)	C7C—C6C—H6C	105.8
O2A—Ni1A—P1A	168.79 (8)	P2C—C6C—H6C	105.8
O1A—Ni1A—P2A	172.56 (10)	C6C—C7C—H7C1	109.5
O2A—Ni1A—P2A	102.91 (8)	C6C—C7C—H7C2	109.5
P1A—Ni1A—P2A	88.01 (4)	H7C1—C7C—H7C2	109.5
O1A—Ni1A—C15A	35.25 (13)	C6C—C7C—H7C3	109.5
O2A—Ni1A—C15A	35.25 (12)	H7C1—C7C—H7C3	109.5
P1A—Ni1A—C15A	133.66 (11)	H7C2—C7C—H7C3	109.5
P2A—Ni1A—C15A	138.05 (11)	C6C—C8C—H8C1	109.5
C15A—O1A—Ni1A	89.7 (2)	C6C—C8C—H8C2	109.5
C15A—O2A—Ni1A	89.4 (2)	H8C1—C8C—H8C2	109.5
C12A—P1A—C1A	106.8 (2)	C6C—C8C—H8C3	109.5
C12A—P1A—C9A	106.5 (2)	H8C1—C8C—H8C3	109.5
C1A—P1A—C9A	106.93 (19)	H8C2—C8C—H8C3	109.5
C12A—P1A—Ni1A	111.46 (15)	C10C—C9C—C11C	111.2 (3)
C1A—P1A—Ni1A	110.94 (14)	C10C—C9C—P1C	110.6 (3)
C9A—P1A—Ni1A	113.81 (16)	C11C—C9C—P1C	110.6 (3)
C6A—P2A—C2A	103.1 (2)	C10C—C9C—H9C	108.1
C6A—P2A—C3A	109.8 (2)	C11C—C9C—H9C	108.1
C2A—P2A—C3A	106.0 (2)	P1C—C9C—H9C	108.1
C6A—P2A—Ni1A	110.17 (14)	C9C—C10C—H10G	109.5
C2A—P2A—Ni1A	109.42 (14)	C9C—C10C—H10H	109.5
C3A—P2A—Ni1A	117.29 (15)	H10G—C10C—H10H	109.5
C2B—C1B—P1B	110.2 (3)	C9C—C10C—H10I	109.5
C2B—C1B—H1B1	109.6	H10G—C10C—H10I	109.5
P1B—C1B—H1B1	109.6	H10H—C10C—H10I	109.5
C2B—C1B—H1B2	109.6	C9C—C11C—H11G	109.5
P1B—C1B—H1B2	109.6	C9C—C11C—H11H	109.5
H1B1—C1B—H1B2	108.1	H11G—C11C—H11H	109.5
C1B—C2B—P2B	108.3 (3)	C9C—C11C—H11I	109.5
C1B—C2B—H2B1	110	H11G—C11C—H11I	109.5
P2B—C2B—H2B1	110	H11H—C11C—H11I	109.5
C1B—C2B—H2B2	110	C14C—C12C—C13C	112.5 (4)
P2B—C2B—H2B2	110	C14C—C12C—P1C	113.4 (3)
H2B1—C2B—H2B2	108.4	C13C—C12C—P1C	110.0 (3)
C4B—C3B—C5B	110.8 (4)	C14C—C12C—H12C	106.8
C4B—C3B—P2B	109.6 (3)	C13C—C12C—H12C	106.8
C5B—C3B—P2B	111.8 (3)	P1C—C12C—H12C	106.8
C4B—C3B—H3B	108.2	C12C—C13C—H13G	109.5
C5B—C3B—H3B	108.2	C12C—C13C—H13H	109.5
P2B—C3B—H3B	108.2	H13G—C13C—H13H	109.5
C3B—C4B—H4B1	109.5	C12C—C13C—H13I	109.5
C3B—C4B—H4B2	109.5	H13G—C13C—H13I	109.5
H4B1—C4B—H4B2	109.5	H13H—C13C—H13I	109.5
C3B—C4B—H4B3	109.5	C12C—C14C—H14G	109.5
H4B1—C4B—H4B3	109.5	C12C—C14C—H14H	109.5
H4B2—C4B—H4B3	109.5	H14G—C14C—H14H	109.5
C3B—C5B—H5B1	109.5	C12C—C14C—H14I	109.5
C3B—C5B—H5B2	109.5	H14G—C14C—H14I	109.5
H5B1—C5B—H5B2	109.5	H14H—C14C—H14I	109.5
C3B—C5B—H5B3	109.5	O3C—C15C—O2C	124.9 (4)
H5B1—C5B—H5B3	109.5	O3C—C15C—O1C	124.6 (3)
H5B2—C5B—H5B3	109.5	O2C—C15C—O1C	110.5 (3)
C8B—C6B—C7B	112.0 (3)	O3C—C15C—Ni1C	177.9 (3)
C8B—C6B—P2B	112.4 (3)	O2C—C15C—Ni1C	55.01 (19)
C7B—C6B—P2B	113.7 (3)	O1C—C15C—Ni1C	55.54 (19)
C8B—C6B—H6B	106	O2C—Ni1C—O1C	70.55 (11)
C7B—C6B—H6B	106	O2C—Ni1C—P2C	99.18 (8)
P2B—C6B—H6B	106	O1C—Ni1C—P2C	169.54 (9)
C6B—C7B—H7B1	109.5	O2C—Ni1C—P1C	172.35 (8)
C6B—C7B—H7B2	109.5	O1C—Ni1C—P1C	101.83 (9)
H7B1—C7B—H7B2	109.5	P2C—Ni1C—P1C	88.46 (4)
C6B—C7B—H7B3	109.5	O2C—Ni1C—C15C	35.16 (12)
H7B1—C7B—H7B3	109.5	O1C—Ni1C—C15C	35.40 (12)
H7B2—C7B—H7B3	109.5	P2C—Ni1C—C15C	134.25 (11)
C6B—C8B—H8B1	109.5	P1C—Ni1C—C15C	137.23 (11)
C6B—C8B—H8B2	109.5	C15C—O1C—Ni1C	89.1 (2)
H8B1—C8B—H8B2	109.5	C15C—O2C—Ni1C	89.8 (2)
C6B—C8B—H8B3	109.5	C9C—P1C—C1C	105.72 (19)
H8B1—C8B—H8B3	109.5	C9C—P1C—C12C	105.13 (19)
H8B2—C8B—H8B3	109.5	C1C—P1C—C12C	106.01 (19)
C11B—C9B—C10B	110.5 (4)	C9C—P1C—Ni1C	116.71 (14)
C11B—C9B—P1B	110.3 (3)	C1C—P1C—Ni1C	109.53 (14)
C10B—C9B—P1B	111.4 (3)	C12C—P1C—Ni1C	112.98 (14)
C11B—C9B—H9B	108.2	C2C—P2C—C3C	106.6 (2)
C10B—C9B—H9B	108.2	C2C—P2C—C6C	103.51 (19)
P1B—C9B—H9B	108.2	C3C—P2C—C6C	109.25 (18)
C9B—C10B—H10D	109.5	C2C—P2C—Ni1C	108.77 (13)
C9B—C10B—H10E	109.5	C3C—P2C—Ni1C	113.61 (13)
H10D—C10B—H10E	109.5	C6C—P2C—Ni1C	114.35 (13)
P1A—C1A—C2A—P2A	37.1 (4)	P2B—Ni1B—P1B—C9B	−120.77 (16)
O3A—C15A—Ni1A—O1A	68 (13)	C15B—Ni1B—P1B—C9B	59.6 (2)
O2A—C15A—Ni1A—O1A	−179.5 (4)	O2B—Ni1B—P1B—C12B	−58.2 (6)
O3A—C15A—Ni1A—O2A	−112 (13)	O1B—Ni1B—P1B—C12B	−62.57 (18)
O1A—C15A—Ni1A—O2A	179.5 (4)	P2B—Ni1B—P1B—C12B	117.26 (16)
O3A—C15A—Ni1A—P1A	65 (13)	C15B—Ni1B—P1B—C12B	−62.4 (2)
O2A—C15A—Ni1A—P1A	177.52 (17)	O2B—Ni1B—P1B—C1B	−176.4 (6)
O1A—C15A—Ni1A—P1A	−2.9 (3)	O1B—Ni1B—P1B—C1B	179.23 (17)
O3A—C15A—Ni1A—P2A	−106 (13)	P2B—Ni1B—P1B—C1B	−0.95 (15)
O2A—C15A—Ni1A—P2A	5.7 (3)	C15B—Ni1B—P1B—C1B	179.4 (2)
O1A—C15A—Ni1A—P2A	−174.78 (18)	C1B—C2B—P2B—C3B	−165.3 (3)
O3A—C15A—O1A—Ni1A	−178.3 (4)	C1B—C2B—P2B—C6B	79.5 (3)
O2A—C15A—O1A—Ni1A	0.4 (3)	C1B—C2B—P2B—Ni1B	−40.2 (3)
O2A—Ni1A—O1A—C15A	−0.3 (2)	C4B—C3B—P2B—C2B	66.7 (3)
P1A—Ni1A—O1A—C15A	177.8 (2)	C5B—C3B—P2B—C2B	−170.0 (3)
P2A—Ni1A—O1A—C15A	28.0 (9)	C4B—C3B—P2B—C6B	178.3 (3)
O3A—C15A—O2A—Ni1A	178.3 (4)	C5B—C3B—P2B—C6B	−58.5 (4)
O1A—C15A—O2A—Ni1A	−0.4 (3)	C4B—C3B—P2B—Ni1B	−53.6 (3)
O1A—Ni1A—O2A—C15A	0.3 (2)	C5B—C3B—P2B—Ni1B	69.7 (3)
P1A—Ni1A—O2A—C15A	−9.3 (6)	C8B—C6B—P2B—C2B	−158.0 (3)
P2A—Ni1A—O2A—C15A	−176.1 (2)	C7B—C6B—P2B—C2B	73.5 (3)
C13A—C12A—P1A—C1A	71.3 (4)	C8B—C6B—P2B—C3B	89.7 (3)
C14A—C12A—P1A—C1A	−53.2 (4)	C7B—C6B—P2B—C3B	−38.8 (3)
C13A—C12A—P1A—C9A	−174.7 (3)	C8B—C6B—P2B—Ni1B	−40.6 (3)
C14A—C12A—P1A—C9A	60.8 (4)	C7B—C6B—P2B—Ni1B	−169.2 (2)
C13A—C12A—P1A—Ni1A	−50.1 (4)	O2B—Ni1B—P2B—C2B	−159.86 (17)
C14A—C12A—P1A—Ni1A	−174.5 (3)	O1B—Ni1B—P2B—C2B	−160.4 (6)
C2A—C1A—P1A—C12A	−147.5 (3)	P1B—Ni1B—P2B—C2B	20.84 (15)
C2A—C1A—P1A—C9A	98.8 (3)	C15B—Ni1B—P2B—C2B	−159.5 (2)
C2A—C1A—P1A—Ni1A	−25.9 (3)	O2B—Ni1B—P2B—C3B	−41.33 (17)
C10A—C9A—P1A—C12A	−176.3 (3)	O1B—Ni1B—P2B—C3B	−41.8 (7)
C11A—C9A—P1A—C12A	59.6 (4)	P1B—Ni1B—P2B—C3B	139.38 (15)
C10A—C9A—P1A—C1A	−62.3 (4)	C15B—Ni1B—P2B—C3B	−41.0 (2)
C11A—C9A—P1A—C1A	173.6 (3)	O2B—Ni1B—P2B—C6B	85.53 (16)
C10A—C9A—P1A—Ni1A	60.5 (3)	O1B—Ni1B—P2B—C6B	85.0 (7)
C11A—C9A—P1A—Ni1A	−63.6 (3)	P1B—Ni1B—P2B—C6B	−93.76 (14)
O1A—Ni1A—P1A—C12A	−53.44 (19)	C15B—Ni1B—P2B—C6B	85.9 (2)
O2A—Ni1A—P1A—C12A	−44.3 (5)	P1C—C1C—C2C—P2C	40.7 (3)
P2A—Ni1A—P1A—C12A	122.83 (16)	O3C—C15C—Ni1C—O2C	89 (9)
C15A—Ni1A—P1A—C12A	−51.7 (2)	O1C—C15C—Ni1C—O2C	−177.6 (4)
O1A—Ni1A—P1A—C1A	−172.34 (19)	O3C—C15C—Ni1C—O1C	−94 (9)
O2A—Ni1A—P1A—C1A	−163.2 (5)	O2C—C15C—Ni1C—O1C	177.6 (4)
P2A—Ni1A—P1A—C1A	3.92 (17)	O3C—C15C—Ni1C—P2C	84 (9)
C15A—Ni1A—P1A—C1A	−170.6 (2)	O2C—C15C—Ni1C—P2C	−4.9 (3)
O1A—Ni1A—P1A—C9A	67.01 (17)	O1C—C15C—Ni1C—P2C	177.53 (16)
O2A—Ni1A—P1A—C9A	76.1 (5)	O3C—C15C—Ni1C—P1C	−93 (9)
P2A—Ni1A—P1A—C9A	−116.72 (15)	O2C—C15C—Ni1C—P1C	178.66 (16)
C15A—Ni1A—P1A—C9A	68.7 (2)	O1C—C15C—Ni1C—P1C	1.1 (3)
C8A—C6A—P2A—C2A	−163.5 (4)	O3C—C15C—O1C—Ni1C	177.4 (4)
C7A—C6A—P2A—C2A	67.0 (4)	O2C—C15C—O1C—Ni1C	−2.1 (3)
C8A—C6A—P2A—C3A	83.8 (4)	O2C—Ni1C—O1C—C15C	1.5 (2)
C7A—C6A—P2A—C3A	−45.6 (4)	P2C—Ni1C—O1C—C15C	−9.8 (6)
C8A—C6A—P2A—Ni1A	−46.8 (4)	P1C—Ni1C—O1C—C15C	−179.3 (2)
C7A—C6A—P2A—Ni1A	−176.3 (3)	O3C—C15C—O2C—Ni1C	−177.4 (4)
C1A—C2A—P2A—C6A	82.8 (3)	O1C—C15C—O2C—Ni1C	2.1 (3)
C1A—C2A—P2A—C3A	−161.8 (3)	O1C—Ni1C—O2C—C15C	−1.5 (2)
C1A—C2A—P2A—Ni1A	−34.4 (3)	P2C—Ni1C—O2C—C15C	176.5 (2)
C5A—C3A—P2A—C6A	−62.3 (4)	P1C—Ni1C—O2C—C15C	−6.9 (8)
C4A—C3A—P2A—C6A	173.7 (3)	C10C—C9C—P1C—C1C	−60.6 (3)
C5A—C3A—P2A—C2A	−173.0 (3)	C11C—C9C—P1C—C1C	175.8 (3)
C4A—C3A—P2A—C2A	63.0 (3)	C10C—C9C—P1C—C12C	−172.5 (3)
C5A—C3A—P2A—Ni1A	64.4 (4)	C11C—C9C—P1C—C12C	63.9 (3)
C4A—C3A—P2A—Ni1A	−59.5 (3)	C10C—C9C—P1C—Ni1C	61.4 (3)
O1A—Ni1A—P2A—C6A	52.5 (8)	C11C—C9C—P1C—Ni1C	−62.2 (3)
O2A—Ni1A—P2A—C6A	79.8 (2)	C2C—C1C—P1C—C9C	98.3 (3)
P1A—Ni1A—P2A—C6A	−97.68 (18)	C2C—C1C—P1C—C12C	−150.4 (3)
C15A—Ni1A—P2A—C6A	76.4 (2)	C2C—C1C—P1C—Ni1C	−28.2 (3)
O1A—Ni1A—P2A—C2A	165.2 (8)	C14C—C12C—P1C—C9C	65.5 (3)
O2A—Ni1A—P2A—C2A	−167.56 (19)	C13C—C12C—P1C—C9C	−167.6 (3)
P1A—Ni1A—P2A—C2A	14.98 (17)	C14C—C12C—P1C—C1C	−46.2 (3)
C15A—Ni1A—P2A—C2A	−170.9 (2)	C13C—C12C—P1C—C1C	80.7 (3)
O1A—Ni1A—P2A—C3A	−74.1 (8)	C14C—C12C—P1C—Ni1C	−166.1 (3)
O2A—Ni1A—P2A—C3A	−46.8 (2)	C13C—C12C—P1C—Ni1C	−39.2 (3)
P1A—Ni1A—P2A—C3A	135.75 (18)	O2C—Ni1C—P1C—C9C	67.8 (7)
C15A—Ni1A—P2A—C3A	−50.1 (2)	O1C—Ni1C—P1C—C9C	62.63 (18)
P1B—C1B—C2B—P2B	39.2 (3)	P2C—Ni1C—P1C—C9C	−115.47 (16)
O3B—C15B—Ni1B—O2B	102 (14)	C15C—Ni1C—P1C—C9C	62.0 (2)
O1B—C15B—Ni1B—O2B	−179.2 (4)	O2C—Ni1C—P1C—C1C	−172.2 (7)
O3B—C15B—Ni1B—O1B	−79 (14)	O1C—Ni1C—P1C—C1C	−177.35 (17)
O2B—C15B—Ni1B—O1B	179.2 (4)	P2C—Ni1C—P1C—C1C	4.55 (15)
O3B—C15B—Ni1B—P2B	101 (14)	C15C—Ni1C—P1C—C1C	−178.0 (2)
O2B—C15B—Ni1B—P2B	−0.6 (3)	O2C—Ni1C—P1C—C12C	−54.2 (7)
O1B—C15B—Ni1B—P2B	−179.80 (16)	O1C—Ni1C—P1C—C12C	−59.43 (17)
O3B—C15B—Ni1B—P1B	−79 (14)	P2C—Ni1C—P1C—C12C	122.47 (15)
O2B—C15B—Ni1B—P1B	178.89 (16)	C15C—Ni1C—P1C—C12C	−60.1 (2)
O1B—C15B—Ni1B—P1B	−0.4 (3)	C1C—C2C—P2C—C3C	−160.3 (3)
O3B—C15B—O1B—Ni1B	178.3 (4)	C1C—C2C—P2C—C6C	84.6 (3)
O2B—C15B—O1B—Ni1B	−0.7 (3)	C1C—C2C—P2C—Ni1C	−37.4 (3)
O2B—Ni1B—O1B—C15B	0.5 (2)	C4C—C3C—P2C—C2C	73.4 (3)
P2B—Ni1B—O1B—C15B	1.0 (8)	C5C—C3C—P2C—C2C	−164.4 (3)
P1B—Ni1B—O1B—C15B	179.7 (2)	C4C—C3C—P2C—C6C	−175.3 (3)
O3B—C15B—O2B—Ni1B	−178.3 (4)	C5C—C3C—P2C—C6C	−53.2 (3)
O1B—C15B—O2B—Ni1B	0.7 (3)	C4C—C3C—P2C—Ni1C	−46.3 (3)
O1B—Ni1B—O2B—C15B	−0.5 (2)	C5C—C3C—P2C—Ni1C	75.8 (3)
P2B—Ni1B—O2B—C15B	179.6 (2)	C8C—C6C—P2C—C2C	−159.7 (3)
P1B—Ni1B—O2B—C15B	−5.0 (7)	C7C—C6C—P2C—C2C	71.6 (3)
C11B—C9B—P1B—C12B	179.1 (3)	C8C—C6C—P2C—C3C	87.1 (3)
C10B—C9B—P1B—C12B	56.0 (4)	C7C—C6C—P2C—C3C	−41.7 (4)
C11B—C9B—P1B—C1B	−68.2 (3)	C8C—C6C—P2C—Ni1C	−41.5 (4)
C10B—C9B—P1B—C1B	168.7 (3)	C7C—C6C—P2C—Ni1C	−170.3 (3)
C11B—C9B—P1B—Ni1B	53.7 (3)	O2C—Ni1C—P2C—C2C	−164.43 (17)
C10B—C9B—P1B—Ni1B	−69.4 (4)	O1C—Ni1C—P2C—C2C	−153.7 (5)
C13B—C12B—P1B—C9B	−175.1 (3)	P1C—Ni1C—P2C—C2C	16.01 (15)
C14B—C12B—P1B—C9B	59.1 (4)	C15C—Ni1C—P2C—C2C	−161.6 (2)
C13B—C12B—P1B—C1B	71.8 (3)	O2C—Ni1C—P2C—C3C	−45.93 (17)
C14B—C12B—P1B—C1B	−54.0 (4)	O1C—Ni1C—P2C—C3C	−35.2 (6)
C13B—C12B—P1B—Ni1B	−48.8 (3)	P1C—Ni1C—P2C—C3C	134.52 (15)
C14B—C12B—P1B—Ni1B	−174.6 (3)	C15C—Ni1C—P2C—C3C	−43.1 (2)
C2B—C1B—P1B—C9B	101.0 (3)	O2C—Ni1C—P2C—C6C	80.43 (18)
C2B—C1B—P1B—C12B	−145.9 (3)	O1C—Ni1C—P2C—C6C	91.2 (5)
C2B—C1B—P1B—Ni1B	−23.5 (3)	P1C—Ni1C—P2C—C6C	−99.12 (16)
O2B—Ni1B—P1B—C9B	63.8 (6)	C15C—Ni1C—P2C—C6C	83.3 (2)
O1B—Ni1B—P1B—C9B	59.40 (18)

D—H···A	D—H	H···A	D···A	D—H···A
C5A—H5A1···O3Ai	0.98	2.7	3.670 (5)	169
C4A—H4A3···O1Ai	0.98	2.69	3.448 (5)	134
C8C—H8C1···O3Cii	0.98	2.71	3.595 (5)	150
C10B—H10F···O3Bii	0.98	2.52	3.335 (5)	141
C1A—H1A2···O3Bii	0.99	2.23	3.204 (5)	168
C1C—H1C2···O3Aiii	0.99	2.5	3.443 (5)	159
C9C—H9C···O2Aiii	1	2.48	3.455 (5)	165
C1B—H1B1···O3Civ	0.99	2.5	3.452 (5)	161
C6B—H6B···O3Civ	1	2.6	3.516 (5)	153

Table 1

Selected bond lengths (Å)

Ni1A—O1A	1.879 (2)
Ni1A—O2A	1.885 (3)
Ni1A—P1A	2.1390 (12)
Ni1A—P2A	2.1460 (11)
Ni1B—O2B	1.887 (2)
Ni1B—O1B	1.890 (3)
Ni1B—P2B	2.1399 (12)
Ni1B—P1B	2.1415 (11)
Ni1C—O2C	1.877 (3)
Ni1C—O1C	1.889 (2)
Ni1C—P2C	2.1433 (10)
Ni1C—P1C	2.1481 (12)

Table 2

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C5A—H5A1⋯O3A i	0.98	2.70	3.670 (5)	169
C4A—H4A3⋯O1A i	0.98	2.69	3.448 (5)	134
C8C—H8C1⋯O3C ii	0.98	2.71	3.595 (5)	150
C10B—H10F⋯O3B ii	0.98	2.52	3.335 (5)	141
C1A—H1A2⋯O3B ii	0.99	2.23	3.204 (5)	168
C1C—H1C2⋯O3A iii	0.99	2.50	3.443 (5)	159
C9C—H9C⋯O2A iii	1.00	2.48	3.455 (5)	165
C1B—H1B1⋯O3C iv	0.99	2.50	3.452 (5)	161
C6B—H6B⋯O3C iv	1.00	2.60	3.516 (5)	153

Symmetry codes: (i) ; (ii) ; (iii) ; (iv) .