Literature DB >> 23627864

Sultam synthesis via Cu-catalyzed intermolecular carboamination of alkenes with N-fluorobenzenesulfonimide.

Keiichi Kaneko1, Tatsuhiko Yoshino, Shigeki Matsunaga, Motomu Kanai.   

Abstract

Cu-catalyzed intermolecular carboamination of alkenes is described. The reaction of terminal alkenes and an internal alkene with N-fluorobenzenesulfonimide was promoted by 2.5 mol % of a Cu(I)-salt at 60 °C, and six-membered ring sultams were obtained in 91-44% yields.

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Year:  2013        PMID: 23627864     DOI: 10.1021/ol4009848

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  7 in total

1.  Pd-catalyzed aryl C-H imidation with arene as the limiting reagent.

Authors:  Gregory B Boursalian; Ming-Yu Ngai; Katarzyna N Hojczyk; Tobias Ritter
Journal:  J Am Chem Soc       Date:  2013-09-03       Impact factor: 15.419

2.  Radical cascade reaction of alkynes with N-fluoroarylsulfonimides and alcohols.

Authors:  Guangfan Zheng; Yan Li; Jingjie Han; Tao Xiong; Qian Zhang
Journal:  Nat Commun       Date:  2015-04-22       Impact factor: 14.919

3.  Cu-Catalyzed aromatic C-H imidation with N-fluorobenzenesulfonimide: mechanistic details and predictive models.

Authors:  Brandon E Haines; Takahiro Kawakami; Keiko Kuwata; Kei Murakami; Kenichiro Itami; Djamaladdin G Musaev
Journal:  Chem Sci       Date:  2016-10-19       Impact factor: 9.825

4.  Arene dearomatization through a catalytic N-centered radical cascade reaction.

Authors:  Rory C McAtee; Efrey A Noten; Corey R J Stephenson
Journal:  Nat Commun       Date:  2020-05-20       Impact factor: 14.919

5.  Bifunctional sulfilimines enable synthesis of multiple N-heterocycles from alkenes.

Authors:  Qiang Cheng; Zibo Bai; Srija Tewari; Tobias Ritter
Journal:  Nat Chem       Date:  2022-07-25       Impact factor: 24.274

6.  Catalytic intramolecular aminoarylation of unactivated alkenes with aryl sulfonamides.

Authors:  Efrey A Noten; Rory C McAtee; Corey R J Stephenson
Journal:  Chem Sci       Date:  2022-05-11       Impact factor: 9.969

7.  Nitrene Radical Intermediates in Catalytic Synthesis.

Authors:  Petrus F Kuijpers; Jarl Ivar van der Vlugt; Sven Schneider; Bas de Bruin
Journal:  Chemistry       Date:  2017-09-14       Impact factor: 5.236

  7 in total

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