Literature DB >> 23620277

A synthesis of α-amino acids via direct reductive carboxylation of imines with carbon dioxide.

Ajay A Sathe1, Douglas R Hartline, Alexander T Radosevich.   

Abstract

A method for the synthesis of α-amino acids by direct reductive carboxylation of aromatic imines with CO2 is described. The protocol employs readily available commercial reagents and serves as a one-step alternative to the Strecker synthesis.

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Year:  2013        PMID： 23620277     DOI： 10.1039/c3cc42057d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  Synthesis and stereochemical assignments of diastereomeric Ni(II) complexes of glycine Schiff base with (R)-2-(N-{2-[N-alkyl-N-(1-phenylethyl)amino]acetyl}amino)benzophenone; a case of configurationally stable stereogenic nitrogen.

Authors:  Hiroki Moriwaki; Daniel Resch; Hengguang Li; Iwao Ojima; Ryosuke Takeda; José Luis Aceña; Vadim A Soloshonok
Journal:  Beilstein J Org Chem       Date:  2014-02-19       Impact factor: 2.883

2.  Ruthenium-catalyzed umpolung carboxylation of hydrazones with CO2.

Authors:  Si-Shun Yan; Lei Zhu; Jian-Heng Ye; Zhen Zhang; He Huang; Huiying Zeng; Chao-Jun Li; Yu Lan; Da-Gang Yu
Journal:  Chem Sci       Date:  2018-04-30       Impact factor: 9.825

3.  Visible light-promoted CO2 fixation with imines to synthesize diaryl α-amino acids.

Authors:  Xinyuan Fan; Xu Gong; Mengyue Ma; Rui Wang; Patrick J Walsh
Journal:  Nat Commun       Date:  2018-11-22       Impact factor: 14.919

Review 4.  Radical-Based Synthesis and Modification of Amino Acids.

Authors:  Francisco José Aguilar Troyano; Kay Merkens; Khadijah Anwar; Adrián Gómez-Suárez
Journal:  Angew Chem Int Ed Engl       Date:  2020-11-04       Impact factor: 15.336
  4 in total

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