Literature DB >> 23620223

Single-pot synthesis of zinc nanoparticles, borane (BH3) and closo-dodecaborate (B12H12)(2-) using LiBH4 under mild conditions.

Sekher Reddy Ghanta1, Muddamarri Hanumantha Rao, Krishnamurthi Muralidharan.   

Abstract

Reduction of ZnCl2 using LiBH4 in mesitylene yielded zinc nanoparticles (Zn-NPs), borane (BH3) and closo-dodecaborate (B12H12)(2-). The BH3 evolved gas was trapped as Ph3P:BH3 adduct while closo-(B12H12)(2-) was extracted by methanol and characterized from spectral data.

Entities:  

Year:  2013        PMID: 23620223     DOI: 10.1039/c3dt00092c

Source DB:  PubMed          Journal:  Dalton Trans        ISSN: 1477-9226            Impact factor:   4.390


  3 in total

1.  Development of bimetallic (Zn@Au) nanoparticles as potential PET-imageable radiosensitizers.

Authors:  Jongmin Cho; Min Wang; Carlos Gonzalez-Lepera; Osama Mawlawi; Sang Hyun Cho
Journal:  Med Phys       Date:  2016-08       Impact factor: 4.071

2.  Effect of Zinc Supplementation on the Serum Metabolites Profile at the Early Stage of Breast Cancer in Rats.

Authors:  Barbara Bobrowska-Korczak; Paulina Gątarek; Dorota Skrajnowska; Wojciech Bielecki; Rafal Wyrebiak; Tomas Kovalczuk; Robert Wrzesień; Joanna Kałużna-Czaplińska
Journal:  Nutrients       Date:  2020-11-11       Impact factor: 5.717

3.  Nucleophilic Substitution Reactions in the [B3H8]- Anion in the Presence of Lewis Acids.

Authors:  Alexandra T Shulyak; Evgeniy O Bortnikov; Nikita A Selivanov; Mikhail S Grigoriev; Alexey S Kubasov; Andrey P Zhdanov; Alexander Y Bykov; Konstantin Y Zhizhin; Nikolai T Kuznetsov
Journal:  Molecules       Date:  2022-01-24       Impact factor: 4.411

  3 in total

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