Literature DB >> 23612503

Catalytic hydrogen production by a Ni-Ru mimic of NiFe hydrogenases involves a proton-coupled electron transfer step.

Sigolène Canaguier1, Vincent Fourmond, Carlo U Perotto, Jennifer Fize, Jacques Pécaut, Marc Fontecave, Martin J Field, Vincent Artero.   

Abstract

A combined electrochemical and theoretical study suggests that hydrogen evolution from weak acids catalyzed by a structural mimic of the active site of NiFe hydrogenases [Ni(xbsms)Ru(C6Me6)Cl](+) proceeds through proton-coupled electron transfer steps.

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Year:  2013        PMID： 23612503     DOI： 10.1039/c3cc40987b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  Nickel-centred proton reduction catalysis in a model of [NiFe] hydrogenase.

Authors:  Deborah Brazzolotto; Marcello Gennari; Nicolas Queyriaux; Trevor R Simmons; Jacques Pécaut; Serhiy Demeshko; Franc Meyer; Maylis Orio; Vincent Artero; Carole Duboc
Journal:  Nat Chem       Date:  2016-07-18       Impact factor: 24.427

2.  Synthetic Active Site Model of the [NiFeSe] Hydrogenase.

Authors:  Claire Wombwell; Erwin Reisner
Journal:  Chemistry       Date:  2015-04-02       Impact factor: 5.236

3.  Proton reduction reaction catalyzed by homoleptic nickel bis-1,2-dithiolate complexes: Experimental and theoretical mechanistic investigations.

Authors:  Athanasios Zarkadoulas; Martin J Field; Vincent Artero; Christiana A Mitsopoulou
Journal:  ChemCatChem       Date:  2017-04-21       Impact factor: 5.686

4.  Catalytic hydrogen oxidation: dawn of a new iron age.

Authors:  Trevor R Simmons; Vincent Artero
Journal:  Angew Chem Int Ed Engl       Date:  2013-05-21       Impact factor: 15.336
  4 in total

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