Literature DB >> 23607928

Rhodium-catalyzed olefin isomerization/allyl Claisen rearrangement/intramolecular hydroacylation cascade.

Ryuichi Okamoto1, Ken Tanaka.   

Abstract

It has been established that a cationic Rh(I)/dppf complex catalyzes the olefin isomerization/allyl Claisen rearrangement/intramolecular hydroacylation cascade of di(allyl) ethers to produce substituted cyclopentanones in good yields under mild conditions.

Entities:  

Year:  2013        PMID： 23607928     DOI： 10.1021/ol400574s

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  3 in total

1.  Isomerization of Olefins Triggered by Rhodium-Catalyzed C-H Bond Activation: Control of Endocyclic β-Hydrogen Elimination.

Authors:  Stephanie Y Y Yip; Christophe Aïssa
Journal:  Angew Chem Int Ed Engl       Date:  2015-04-23       Impact factor: 15.336

2.  [3+2] Cycloaddition of alkyl aldehydes and alkynes enabled by photoinduced hydrogen atom transfer.

Authors:  Siya Le; Ji Li; Jian Feng; Zuxiao Zhang; Yihui Bai; Zheliang Yuan; Gangguo Zhu
Journal:  Nat Commun       Date:  2022-08-12       Impact factor: 17.694

3.  Rh-Catalyzed Desymmetrization of α-Quaternary Centers by Isomerization-Hydroacylation.

Authors:  Jung-Woo Park; Kevin G M Kou; Daniel K Kim; Vy M Dong
Journal:  Chem Sci       Date:  2015-06-12       Impact factor: 9.825
  3 in total

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