Literature DB >> 23607873

Palladium-catalyzed formal hydroacylation of allenes employing acid chlorides and hydrosilanes.

Tetsuaki Fujihara1, Kenta Tatsumi, Jun Terao, Yasushi Tsuji.   

Abstract

The palladium-catalyzed formal hydroacylation of allenes employing acid chlorides and hydrosilanes has been achieved. The reactions proceed with commercially available Pd(OAc)2 as a catalyst and HSi(iPr)3 as a reducing reagent, giving the corresponding α,β-unsaturated ketones regio- and stereoselectively.

Entities:  

Year:  2013        PMID： 23607873     DOI： 10.1021/ol400862k

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  5 in total

1.  Mechanisms for nickel(0)/N-heterocyclic carbene-catalyzed intramolecular alkene hydroacylation: insights from a DFT study.

Authors:  Qingxi Meng; Fen Wang
Journal:  J Mol Model       Date:  2016-12-21       Impact factor: 1.810

2.  Palladium-catalysed carboformylation of alkynes using acid chlorides as a dual carbon monoxide and carbon source.

Authors:  Yong Ho Lee; Elliott H Denton; Bill Morandi
Journal:  Nat Chem       Date:  2021-01-29       Impact factor: 24.427

3.  Theoretical studies of nickel-catalyzed ring-opening hydroacylation of methylenecyclopropanes and benzaldehydes.

Authors:  Fen Wang; Shuhua Zhu; Qingxi Meng; Hongzong Yin
Journal:  J Mol Model       Date:  2015-07-22       Impact factor: 1.810

4.  Mechanisms and reactivity differences for the cobalt-catalyzed enantioselective intramolecular hydroacylation of ketones and alkenes: insights from density functional calculations.

Authors:  Qingxi Meng; Fen Wang
Journal:  J Mol Model       Date:  2016-02-18       Impact factor: 1.810

5.  Enantioselective CuH-Catalyzed Reductive Coupling of Aryl Alkenes and Activated Carboxylic Acids.

Authors:  Jeffrey S Bandar; Erhad Ascic; Stephen L Buchwald
Journal:  J Am Chem Soc       Date:  2016-04-29       Impact factor: 15.419
  5 in total

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