Synthesis and characterization of the hole-conducting silica/polymer nanocomposites and application in solid-state dye-sensitized solar cell.

Hole-conducting silica/polymer nanocomposites exhibit interesting physical and chemical properties with important applications in the field of energy storage and hybrid solar cells. Although the conventional strategy of grafting hole-conducting polymer onto the surface of silica nanoparticles is to use in situ oxidative polymerization, a promising alternative of using surface-initiated controlled living radical polymerization has arisen to anchor the polymer on the silica. The resulting silica/polymer nanocomposites from the latter method are more chemically and thermally stable because of the strong covalent bonding compared to the electrostatic interaction from in situ polymerization. The use of these nanocomposites mixed with spiro-MeOTAD (2,2',7,7'-tetrakis(N,N-di-p-methoxyphenylamine)-9,9'-spirobifluorene) as a new hole conductor in the application of solid-state dye-sensitized solar cell (ss-DSSC) is reported here. The power conversion efficiency of this ss-DSSC is higher than the full spiro-MeOTAD ss-DSSC. Notably, the short circuit current improves by 26%. It is explained by large size silica/polymer nanocomposites forming an additional light scattering layer on the top of photoanode. This is the first time a conductive light scattering layer is introduced into ss-DSSC to enhance cell performance.