Literature DB >> 23606664

A catalytic asymmetric synthesis of polysubstituted piperidines using a rhodium(I)-catalyzed [2+2+2] cycloaddition employing a cleavable tether.

Timothy J Martin1, Tomislav Rovis.   

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Year:  2013        PMID： 23606664      PMCID： PMC3820010          DOI： 10.1002/anie.201301741

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


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  34 in total

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2.  Synthesis of 2,4,6-trisubstituted chiral piperidines and (-)-dendroprimine by one-pot asymmetric azaelectrocyclization protocol.

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4.  Rhodium-catalyzed [2 + 2 + 2] cycloaddition of alkenyl isocyanates and alkynes.

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6.  Enantioselective Synthesis of the Tricyclic Core of FR901483 Featuring a Rh-Catalyzed [2+2+2] Cycloaddition.

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7.  A modular, efficient, and stereoselective synthesis of substituted piperidin-4-ols.

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Journal:  Angew Chem Int Ed Engl       Date:  2010-11-22       Impact factor: 15.336

8.  Catalytic enantioselective [4 + 2]-cycloaddition: a strategy to access aza-hexacycles.

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9.  Excess substrate is a spectator ligand in a rhodium-catalyzed asymmetric [2 + 2 + 2] cycloaddition of alkenyl isocyanates with tolanes.

Authors:  Mark Emil Oinen; Robert T Yu; Tomislav Rovis
Journal:  Org Lett       Date:  2009-11-05       Impact factor: 6.005

Review 10.  Indolizidine and quinolizidine alkaloids.

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Review 4.  Convergent Synthesis of Diverse Tetrahydropyridines via Rh(I)-Catalyzed C-H Functionalization Sequences.

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5.  Catalytic [2 + 2 + 2] cycloaddition with indium(iii)-activated formaldimines: a practical and selective access to hexahydropyrimidines and 1,3-diamines from alkenes.

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