| Literature DB >> 23594038 |
Rahul Kumar1, Tarun Kumar, Shaikh M Mobin, Irishi N N Nambothiri.
Abstract
The Rauhut-Currier reaction between nitroalkenes and vinyl sulfones has been successfully carried out for the first time. The reaction proceeds in the presence of an imidazole/LiCl catalyst system in dioxane to provide the adducts possessing a synthetically useful 1-bis-sulfonyl-3-nitroalkene moiety in good to excellent yield. A one-pot transformation of the products to β-sulfonyl-α,β-unsaturated ketoximes has also been demonstrated.Entities:
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Year: 2013 PMID: 23594038 DOI: 10.1021/jo400528j
Source DB: PubMed Journal: J Org Chem ISSN: 0022-3263 Impact factor: 4.354