Literature DB >> 23591969

Asymmetric transformation by dynamic crystallization of achiral succinimides.

Shoko Hachiya1, Yoshio Kasashima, Fumitoshi Yagishita, Takashi Mino, Hyuma Masu, Masami Sakamoto.   

Abstract

Optically active materials could be generated by simple solidification of achiral materials without an external chiral source. When achiral cis-3,4-diphenylsuccinimides were solidified in the presence of a catalytic amount of DBU by evaporating the solvent with stirring, optically active trans-3,4-diphenylsuccinimides were obtained quantitatively with high enantiomeric excesses.

Entities:  

Year:  2013        PMID： 23591969     DOI： 10.1039/c3cc41678j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Solid-Phase Conversion of Four Stereoisomers into a Single Enantiomer.

Authors:  Anthonius H J Engwerda; Johannes C J Mertens; Paul Tinnemans; Hugo Meekes; Floris P J T Rutjes; Elias Vlieg
Journal:  Angew Chem Int Ed Engl       Date:  2018-10-19       Impact factor: 15.336

2.  Photoracemization-Based Viedma Ripening of a BINOL Derivative.

Authors:  Giuseppe Belletti; Carola Tortora; Indradevi D Mellema; Paul Tinnemans; Hugo Meekes; Floris P J T Rutjes; Svetlana B Tsogoeva; Elias Vlieg
Journal:  Chemistry       Date:  2019-12-12       Impact factor: 5.236
  2 in total

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