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Literature DB >> 23589464

Diastereodivergent carbometalation/oxidation/selective ring opening: formation of all-carbon quaternary stereogenic centers in acyclic systems.

Pierre-Olivier Delaye¹, Dorian Didier, Ilan Marek.

Abstract

Entities: Chemical

Year: 2013 PMID： 23589464 DOI： 10.1002/anie.201300664

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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14 in total

1. Merging allylic carbon-hydrogen and selective carbon-carbon bond activation.

Authors: Ahmad Masarwa; Dorian Didier; Tamar Zabrodski; Marvin Schinkel; Lutz Ackermann; Ilan Marek
Journal: Nature Date: 2013-12-08 Impact factor: 49.962

2. Enzymatic construction of highly strained carbocycles.

Authors: Kai Chen; Xiongyi Huang; S B Jennifer Kan; Ruijie K Zhang; Frances H Arnold
Journal: Science Date: 2018-04-06 Impact factor: 47.728

3. Cascade bicyclizations of o-alkynyl aldehydes with thiazolium salts: a new access toward poly-functionalized indeno[2,1-b]pyrroles.

Authors: Peng Zhou; Wen-Juan Hao; Jin-Peng Zhang; Bo Jiang; Guigen Li; Shu-Jiang Tu
Journal: Chem Commun (Camb) Date: 2015-08-21 Impact factor: 6.222

4. Enantioselective Construction of Acyclic Quaternary Carbon Stereocenters: Palladium-Catalyzed Decarboxylative Allylic Alkylation of Fully Substituted Amide Enolates.

Authors: Pavel Starkov; Jared T Moore; Douglas C Duquette; Brian M Stoltz; Ilan Marek
Journal: J Am Chem Soc Date: 2017-07-07 Impact factor: 15.419

10. Diastereodivergent combined carbometalation/zinc homologation/C-C fragmentation reaction as an efficient tool to prepare acyclic allylic quaternary carbon stereocenters.

Authors: Sudipta Raha Roy; Dorian Didier; Amir Kleiner; Ilan Marek
Journal: Chem Sci Date: 2016-05-24 Impact factor: 9.825

Diastereodivergent carbometalation/oxidation/selective ring opening: formation of all-carbon quaternary stereogenic centers in acyclic systems.

1. Merging allylic carbon-hydrogen and selective carbon-carbon bond activation.

2. Enzymatic construction of highly strained carbocycles.

3. Cascade bicyclizations of o-alkynyl aldehydes with thiazolium salts: a new access toward poly-functionalized indeno[2,1-b]pyrroles.

4. Enantioselective Construction of Acyclic Quaternary Carbon Stereocenters: Palladium-Catalyzed Decarboxylative Allylic Alkylation of Fully Substituted Amide Enolates.

5. Directed nucleophilic addition of phenoxides to cyclopropenes.

6. Intramolecular nucleophilic addition of carbanions generated from N-benzylamides to cyclopropenes.

7. Zirconocene catalyzed diastereoselective carbometalation of cyclobutenes.

8. Remote functionalization of hydrocarbons with reversibility enhanced stereocontrol.

Review 9. Copper mediated carbometalation reactions.

10. Diastereodivergent combined carbometalation/zinc homologation/C-C fragmentation reaction as an efficient tool to prepare acyclic allylic quaternary carbon stereocenters.