| Literature DB >> 23571480 |
Wei Li1, M S R N Kiran, Jamie L Manson, John A Schlueter, A Thirumurugan, U Ramamurty, Anthony K Cheetham.
Abstract
We report the mechanical properties of a framework structure, [Cu2F(HF)(HF2)(pyz)4][(SbF6)2]n (pyz = pyrazine), in which [Cu(pyz)2](2+) layers are pillared by HF2(-) anions containing the exceptionally strong F-H···F hydrogen bonds. Nanoindentation studies on single-crystals clearly demonstrate that such bonds are extremely robust and mechanically comparable with coordination bonds in this system.Entities:
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Year: 2013 PMID： 23571480 DOI： 10.1039/c3cc41357h
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222