Literature DB >> 23568783

Alcohol-promoted ring-opening alkyne metathesis polymerization.

Daniel W Paley1, Danielle F Sedbrook, John Decatur, Felix R Fischer, Michael L Steigerwald, Colin Nuckolls.   

Abstract

Alcohol is the answer! An inactive, air-stable, dimeric molybdenum alkylidyne complex is activated toward ring-opening alkyne metathesis polymerization (ROAMP) by the addition of methanol. The ROAMP is compatible with water and phenol-containing substrates and with the in situ photochemical generation of alkyne monomers from cyclopropenones.
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Year:  2013        PMID： 23568783     DOI： 10.1002/anie.201300758

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  9 in total

1.  Highly selective molybdenum ONO pincer complex initiates the living ring-opening metathesis polymerization of strained alkynes with exceptionally low polydispersity indices.

Authors:  Donatela E Bellone; Justin Bours; Elisabeth H Menke; Felix R Fischer
Journal:  J Am Chem Soc       Date:  2015-01-06       Impact factor: 15.419

2.  Multicolor live-cell chemical imaging by isotopically edited alkyne vibrational palette.

Authors:  Zhixing Chen; Daniel W Paley; Lu Wei; Andrew L Weisman; Richard A Friesner; Colin Nuckolls; Wei Min
Journal:  J Am Chem Soc       Date:  2014-05-21       Impact factor: 15.419

3.  Molybdenum Alkylidyne Complexes with Tripodal Silanolate Ligands: The Next Generation of Alkyne Metathesis Catalysts.

Authors:  Julius Hillenbrand; Markus Leutzsch; Alois Fürstner
Journal:  Angew Chem Int Ed Engl       Date:  2019-09-17       Impact factor: 15.336

4.  Formation of alkyne-bridged ferrocenophanes using ring-closing alkyne metathesis on 1,1'-diacetylenic ferrocenes.

Authors:  Celine Bittner; Dirk Bockfeld; Matthias Tamm
Journal:  Beilstein J Org Chem       Date:  2019-10-24       Impact factor: 2.883

5.  The Ascent of Alkyne Metathesis to Strategy-Level Status.

Authors:  Alois Fürstner
Journal:  J Am Chem Soc       Date:  2021-09-14       Impact factor: 15.419

Review 6.  By-design molecular architectures via alkyne metathesis.

Authors:  Shaofeng Huang; Zepeng Lei; Yinghua Jin; Wei Zhang
Journal:  Chem Sci       Date:  2021-05-22       Impact factor: 9.825

7.  "Canopy Catalysts" for Alkyne Metathesis: Molybdenum Alkylidyne Complexes with a Tripodal Ligand Framework.

Authors:  Julius Hillenbrand; Markus Leutzsch; Ektoras Yiannakas; Christopher P Gordon; Christian Wille; Nils Nöthling; Christophe Copéret; Alois Fürstner
Journal:  J Am Chem Soc       Date:  2020-06-09       Impact factor: 15.419

8.  Efficient catalytic alkyne metathesis with a fluoroalkoxy-supported ditungsten(III) complex.

Authors:  Henrike Ehrhorn; Janin Schlösser; Dirk Bockfeld; Matthias Tamm
Journal:  Beilstein J Org Chem       Date:  2018-09-18       Impact factor: 2.883

9.  Canopy Catalysts for Alkyne Metathesis: Investigations into a Bimolecular Decomposition Pathway and the Stability of the Podand Cap.

Authors:  Julius Hillenbrand; J Nepomuk Korber; Markus Leutzsch; Nils Nöthling; Alois Fürstner
Journal:  Chemistry       Date:  2021-08-26       Impact factor: 5.236
  9 in total

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