Literature DB >> 23556788

A small subset of normal modes mimics the properties of dynamical heterogeneity in a model supercooled liquid.

Glen M Hocky1, David R Reichman.   

Abstract

In this work, we study the nature of transitions between inherent structures of a two-dimensional model supercooled liquid. We demonstrate that these transitions occur predominately along a small number of directions on the energy landscape. Moreover, we show that the number of such directions decreases as the temperature of the liquid is decreased in the mildly supercooled regime, in concert with earlier studies on an athermal jamming system. We show that this decrease happens in parallel with a change in character of the transitions as dynamics in the system become more heterogeneous and localized. We investigate the origin of these trends, which suggests interesting connections between jamming and thermal glassy phenomena.

Year:  2013        PMID: 23556788     DOI: 10.1063/1.4790799

Source DB:  PubMed          Journal:  J Chem Phys        ISSN: 0021-9606            Impact factor:   3.488


  1 in total

1.  What is special about how roaming chemical reactions traverse their potential surfaces? Differences in geodesic paths between roaming and non-roaming events.

Authors:  D Vale Cofer-Shabica; Richard M Stratt
Journal:  J Chem Phys       Date:  2017-06-07       Impact factor: 3.488

  1 in total

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