Literature DB >> 23552965

Anti-Bredt N-heterocyclic carbene: an efficient ligand for the gold(I)-catalyzed hydroamination of terminal alkynes with parent hydrazine.

María J López-Gómez1, David Martin, Guy Bertrand.   

Abstract

An anti-Bredt N-heterocyclic carbene gold(I) chloride complex was synthesized by taking advantage of the reversible insertion of the free carbene into the NH bond of hexamethyldisilazane. This precatalyst promotes the parent hydrazine hydroamination of terminal alkynes at room temperature.

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Year:  2013        PMID： 23552965     DOI： 10.1039/c3cc41279b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  6 in total

1.  A Ruthenium Catalyst for Olefin Metathesis Featuring an Anti-Bredt N-Heterocyclic Carbene Ligand.

Authors:  David Martin; Vanessa M Marx; Robert H Grubbs; Guy Bertrand
Journal:  Adv Synth Catal       Date:  2016-02-09       Impact factor: 5.837

2.  Intriguing mechanistic labyrinths in gold(I) catalysis.

Authors:  Carla Obradors; Antonio M Echavarren
Journal:  Chem Commun (Camb)       Date:  2014-01-04       Impact factor: 6.222

3.  Pyridylidene ligand facilitates gold-catalyzed oxidative C-H arylation of heterocycles.

Authors:  Kazuhiro Hata; Hideto Ito; Yasutomo Segawa; Kenichiro Itami
Journal:  Beilstein J Org Chem       Date:  2015-12-28       Impact factor: 2.883

4.  External electric field: a new catalytic strategy for the anti-Markovnikov hydrohydrazination of parent hydrazine.

Authors:  Ming-Xia Zhang; Wen-Zuo Li; Hong-Liang Xu; Zi-Yan Zhou; Shu-Ping Zhuo
Journal:  RSC Adv       Date:  2021-03-22       Impact factor: 3.361

5.  Fullerene C60 promoted photochemical hydroamination reactions of an electron deficient alkyne with trimethylsilyl group containing tertiary N-alkylbenzylamines.

Authors:  Suk Hyun Lim; Hannara Jang; Dae Won Cho
Journal:  RSC Adv       Date:  2021-02-03       Impact factor: 3.361

6.  A hybrid bipy-NHC ligand for the construction of group 11 mixed-metal bimetallic complexes.

Authors:  Benson M Kariuki; James A Platts; Paul D Newman
Journal:  RSC Adv       Date:  2021-10-21       Impact factor: 4.036
  6 in total

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