| Literature DB >> 23549197 |
Małgorzata Zienkiewicz1, Jakub Szlachetko, Christian Lothschütz, Maciej Hodorowicz, Agnieszka Jabłońska-Wawrzycka, Jacinto Sá, Barbara Barszcz.
Abstract
A novel single site Mn(II) complex was successfully synthesized and tested in the aqueous disproportionation of hydrogen peroxide. The complex was found to be stable (HR-XAS) and exhibits catalase-like activity in neutral pH. Theoretical calculations suggested a reaction mechanism involving two complexes, changes in metal oxidation state and proton shuttling.Entities:
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Year: 2013 PMID: 23549197 DOI: 10.1039/c3dt50288k
Source DB: PubMed Journal: Dalton Trans ISSN: 1477-9226 Impact factor: 4.390