Literature DB >> 23540374

Iodine(III)-mediated umpolung of bromide salts for the ethoxybromination of enamides.

Sophie Nocquet-Thibault1, Pascal Retailleau, Kevin Cariou, Robert H Dodd.   

Abstract

Using (diacetoxyiodo)benzene in conjunction with simple bromide salts in ethanol allows the regioselective ethoxybromination of a wide range of enamides, thus yielding highly versatile α-bromo hemiaminals, which can then be engaged in a broad array of transformations.

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Year:  2013        PMID: 23540374     DOI: 10.1021/ol400453b

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  1 in total

1.  Iodine(III)-mediated halogenations of acyclic monoterpenoids.

Authors:  Laure Peilleron; Tatyana D Grayfer; Joëlle Dubois; Robert H Dodd; Kevin Cariou
Journal:  Beilstein J Org Chem       Date:  2018-05-18       Impact factor: 2.883

  1 in total

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