| Literature DB >> 23537339 |
Qing-Hai Deng1, Tim Bleith, Hubert Wadepohl, Lutz H Gade.
Abstract
The first example of Fe-catalyzed enantioselective azidations of β-keto esters and oxindoles using a readily available N3-transfer reagent is reported. A number of α-azido-β-keto esters were obtained with up to 93% ee, and this methodology also generates 3-substitued 3-azidooxindoles with high enantioselectivities (up to 94%).Entities:
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Year: 2013 PMID： 23537339 DOI： 10.1021/ja402082p
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419