Literature DB >> 23532937

Catalytic deoxydehydration of glycols with alcohol reductants.

Camille Boucher-Jacobs1, Kenneth M Nicholas.   

Abstract

Top shelf dehydration: Ammonium perrhenate catalysts combined with benzylic alcohol reductants are used for the efficient deoxydehydration of glycols to olefins. The olefin and aldehyde products can be easily separated and isolated. It is also demonstrated that the catalyst can be recovered and reused because of its low solubility in aromatic solvents.
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Year:  2013        PMID: 23532937     DOI: 10.1002/cssc.201200781

Source DB:  PubMed          Journal:  ChemSusChem        ISSN: 1864-5631            Impact factor:   8.928


  1 in total

1.  Direct Deoxydehydration of Cyclic trans-Diol Substrates: An Experimental and Computational Study of the Reaction Mechanism of Vanadium(V)-based Catalysis*.

Authors:  Ebru Aksanoglu; Yee Hwee Lim; Richard A Bryce
Journal:  ChemSusChem       Date:  2021-02-09       Impact factor: 8.928

  1 in total

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