Literature DB >> 23532183

Rhodium(III)-catalyzed oxidative olefination of N-allyl sulfonamides.

Shui Hu1, Dongqi Wang, Jiexiang Liu, Xingwei Li.   

Abstract

Rhodium(III)-catalyzed oxidative couplings between N-sulfonyl allylamines and activated olefins have been achieved. Only olefination occurred for acrylates, and the butadiene product can be further cyclized under palladium-catalyzed aerobic conditions. The coupling with N,N-dimethylacrylamide followed a cyclization pathway.

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Year:  2013        PMID: 23532183     DOI: 10.1039/c3ob40272j

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN: 1477-0520            Impact factor:   3.876


  1 in total

1.  Photocatalytic Late-Stage Functionalization of Sulfonamides via Sulfonyl Radical Intermediates.

Authors:  Michael J Tilby; Damien F Dewez; Loïc R E Pantaine; Adrian Hall; Carolina Martínez-Lamenca; Michael C Willis
Journal:  ACS Catal       Date:  2022-05-06       Impact factor: 13.700

  1 in total

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