Literature DB >> 23527827

C-acylation of cyclopropanols: preparation of functionalized 1,4-diketones.

Bibhuti Bhusan Parida1, Pragna Pratic Das, Mathilde Niocel, Jin Kun Cha.   

Abstract

A convenient method for preparing attractively functionalized 1,4-diketones has been devised by palladium-catalyzed cross-coupling of cyclopropanols and acyl chlorides. The utility of this method has been demonstrated in an enantioselective synthesis of (+)-myrmicarin 217.

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Year:  2013        PMID: 23527827     DOI: 10.1021/ol400666x

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  10 in total

1.  An Umpolung Strategy for the Synthesis of β-Aminoketones via Copper-Catalyzed Electrophilic Amination of Cyclopropanols.

Authors:  Zhishi Ye; Mingji Dai
Journal:  Org Lett       Date:  2015-04-17       Impact factor: 6.005

2.  Rh(I)/Sc(OTf)3-co-catalyzed Michael addition of ammonium ylide to (E)-1,4-enediones: synthesis of functionalized 1,4-diketones.

Authors:  Qinghua Wei; Zi Li; Xi Yang; Jianghui Chen; Xiaohua Liu; Wenhao Hu; Shunying Liu
Journal:  Mol Divers       Date:  2019-04-05       Impact factor: 2.943

3.  Catalytic Net Oxidative C-C Activation and Silylation of Cyclopropanols with a Traceless Acetal Directing Group.

Authors:  Thirupataiah Avullala; Hiep H Nguyen; Udaya Sree Dakarapu; Parham Asgari; Yuanda Hua; Junha Jeon
Journal:  ACS Catal       Date:  2022-01-18       Impact factor: 13.700

4.  Photocatalytic Radical Aroylation of Unactivated Alkenes: Pathway to β-Functionalized 1,4-, 1,6-, and 1,7-Diketones.

Authors:  Satavisha Sarkar; Arghya Banerjee; Wang Yao; Eric V Patterson; Ming-Yu Ngai
Journal:  ACS Catal       Date:  2019-10-17       Impact factor: 13.084

5.  Catalytic Carbonylative Spirolactonization of Hydroxycyclopropanols.

Authors:  Dexter C Davis; Katherine L Walker; Chunhua Hu; Richard N Zare; Robert M Waymouth; Mingji Dai
Journal:  J Am Chem Soc       Date:  2016-08-11       Impact factor: 15.419

6.  Copper-Catalyzed Cyclopropanol Ring Opening Csp(3)-Csp(3) Cross-Couplings with (Fluoro)Alkyl Halides.

Authors:  Zhishi Ye; Kristen E Gettys; Xingyu Shen; Mingji Dai
Journal:  Org Lett       Date:  2015-12-04       Impact factor: 6.005

7.  Efficient Synthesis of β-CF3/SCF3-Substituted Carbonyls via Copper-Catalyzed Electrophilic Ring-Opening Cross-Coupling of Cyclopropanols.

Authors:  Yong Li; Zhishi Ye; Tabitha M Bellman; Teng Chi; Mingji Dai
Journal:  Org Lett       Date:  2015-04-17       Impact factor: 6.072

8.  Divergent ring-opening coupling between cyclopropanols and alkynes under cobalt catalysis.

Authors:  Junfeng Yang; Yixiao Shen; Yang Jie Lim; Naohiko Yoshikai
Journal:  Chem Sci       Date:  2018-07-16       Impact factor: 9.825

9.  TBAI-Catalyzed Oxidative Coupling of Benzyl Ketones to Synthesize 2,3-Diaryl-1,4-Diketones in Water.

Authors:  Lingkai Kong; Xueping Hu; Li-Ping Bai
Journal:  ACS Omega       Date:  2022-01-07

10.  Palladium-catalyzed selective C-C bond cleavage and stereoselective alkenylation between cyclopropanol and 1,3-diyne: one-step synthesis of diverse conjugated enynes.

Authors:  Bedadyuti Vedvyas Pati; Asit Ghosh; Komal Yadav; Shyam Kumar Banjare; Shalini Pandey; Upakarasamy Lourderaj; Ponneri C Ravikumar
Journal:  Chem Sci       Date:  2022-02-08       Impact factor: 9.825

  10 in total

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