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Literature DB >> 23525236

Diverse topologies in dynamic combinatorial libraries from tri- and mono-thiols in water: sensitivity to weak supramolecular interactions.

Artur R Stefankiewicz¹, Jeremy K M Sanders.

Abstract

We describe here the use of disulfide exchange reactions to generate distinct supramolecular topologies within a dynamic combinatorial library (DCL) derived from tri- and mono-functionalised thiol components in water. This approach allows for the effective expansion of structural diversity within a DCL, and also provides a sensitive probe for weak supramolecular interactions.

Entities: Chemical

Year: 2013 PMID： 23525236 DOI： 10.1039/c3cc41158c

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

6 in total

1. Generation of a Multicomponent Library of Disulfide Donor-Acceptor Architectures Using Dynamic Combinatorial Chemistry.

Authors: Wojciech Drożdż; Michał Kołodziejski; Grzegorz Markiewicz; Anna Jenczak; Artur R Stefankiewicz
Journal: Int J Mol Sci Date: 2015-07-17 Impact factor: 5.923

Diverse topologies in dynamic combinatorial libraries from tri- and mono-thiols in water: sensitivity to weak supramolecular interactions.

1. Generation of a Multicomponent Library of Disulfide Donor-Acceptor Architectures Using Dynamic Combinatorial Chemistry.

2. Catenation and encapsulation induce distinct reconstitutions within a dynamic library of mixed-ligand Zn₄L₆ cages.

3. Selective C₇₀ encapsulation by a robust octameric nanospheroid held together by 48 cooperative hydrogen bonds.

4. Dynamic polyimine macrobicyclic cryptands - self-sorting with component selection.

5. Expanding structural diversity in a library of disulfide macrocycles through in-situ imide hydrolysis.

6. Factors that determine thione(thiol)-disulfide interconversion in a bis(thiosemicarbazone) copper(ii) complex.

Diverse topologies in dynamic combinatorial libraries from tri- and mono-thiols in water: sensitivity to weak supramolecular interactions.

1. Generation of a Multicomponent Library of Disulfide Donor-Acceptor Architectures Using Dynamic Combinatorial Chemistry.

2. Catenation and encapsulation induce distinct reconstitutions within a dynamic library of mixed-ligand Zn4L6 cages.

3. Selective C70 encapsulation by a robust octameric nanospheroid held together by 48 cooperative hydrogen bonds.

4. Dynamic polyimine macrobicyclic cryptands - self-sorting with component selection.

5. Expanding structural diversity in a library of disulfide macrocycles through in-situ imide hydrolysis.

6. Factors that determine thione(thiol)-disulfide interconversion in a bis(thiosemicarbazone) copper(ii) complex.

2. Catenation and encapsulation induce distinct reconstitutions within a dynamic library of mixed-ligand Zn₄L₆ cages.

3. Selective C₇₀ encapsulation by a robust octameric nanospheroid held together by 48 cooperative hydrogen bonds.