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Literature DB >> 23512136

Two birds with one stone: anion templated ball-shaped Ag56 and disc-like Ag20 clusters.

Di Sun¹, Hua Wang, Hai-Feng Lu, Sheng-Yu Feng, Zhen-Wei Zhang, Guo-Xin Sun, Dao-Feng Sun.

Abstract

One-pot reaction of AgSBu(t) and AgOAc in the methanol-ethanol-DMF solvent system under room temperature gave a ball-shaped Ag56 cluster and a disc-like Ag20 cluster. The formations of clusters and are templated by an in situ generated S(2-) ion from the cleavage of the S-C bond of SBu(t) and CO3(2-) ion from the fixation of atmospheric carbon dioxide, respectively. Interestingly, cluster 1 only emits bright-red light in the solid state at 77 K and is not emissive at room temperature.

Entities: Chemical

Year: 2013 PMID： 23512136 DOI： 10.1039/c3dt50342a

Source DB: PubMed Journal: Dalton Trans ISSN： 1477-9226 Impact factor: 4.390

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Cited

5 in total

1. Chiral Nanocluster Complexes Formed by Host-Guest Interaction between Enantiomeric 2,6-Helic[6]arenes and Silver Cluster Ag₂₀: Emission Enhancement and Chirality Transfer.

Authors: Yan Guo; Ying Han; Chuanfeng Chen
Journal: Molecules Date: 2022-06-19 Impact factor: 4.927

2. Trapping an octahedral Ag₆ kernel in a seven-fold symmetric Ag₅₆ nanowheel.

Authors: Zhi Wang; Hai-Feng Su; Mohamedally Kurmoo; Chen-Ho Tung; Di Sun; Lan-Sun Zheng
Journal: Nat Commun Date: 2018-05-29 Impact factor: 14.919

3. A Keplerian Ag₉₀ nest of Platonic and Archimedean polyhedra in different symmetry groups.

Authors: Yan-Min Su; Zhi Wang; Stan Schein; Chen-Ho Tung; Di Sun
Journal: Nat Commun Date: 2020-07-03 Impact factor: 14.919

4. An atomically precise silver nanocluster for artificial light-harvesting system through supramolecular functionalization.

Authors: Anish Kumar Das; Sourav Biswas; Surya Sekhar Manna; Biswarup Pathak; Sukhendu Mandal
Journal: Chem Sci Date: 2022-06-20 Impact factor: 9.969

5. Observation of Contrary Thermo-responsive Trend for Single Crystal and Powder Samples in Mechano-, Thermo- and Solvato-responsive Luminescent Cubane [Ag₄I₄L₄] Cluster.

Authors: Shi-Li Li; Min Han; Bin Wu; Jie Wang; Fu-Qiang Zhang; Xian-Ming Zhang
Journal: Sci Rep Date: 2017-10-12 Impact factor: 4.379

5 in total

Two birds with one stone: anion templated ball-shaped Ag56 and disc-like Ag20 clusters.

1. Chiral Nanocluster Complexes Formed by Host-Guest Interaction between Enantiomeric 2,6-Helic[6]arenes and Silver Cluster Ag20: Emission Enhancement and Chirality Transfer.

2. Trapping an octahedral Ag6 kernel in a seven-fold symmetric Ag56 nanowheel.

3. A Keplerian Ag90 nest of Platonic and Archimedean polyhedra in different symmetry groups.

4. An atomically precise silver nanocluster for artificial light-harvesting system through supramolecular functionalization.

5. Observation of Contrary Thermo-responsive Trend for Single Crystal and Powder Samples in Mechano-, Thermo- and Solvato-responsive Luminescent Cubane [Ag4I4L4] Cluster.

1. Chiral Nanocluster Complexes Formed by Host-Guest Interaction between Enantiomeric 2,6-Helic[6]arenes and Silver Cluster Ag₂₀: Emission Enhancement and Chirality Transfer.

2. Trapping an octahedral Ag₆ kernel in a seven-fold symmetric Ag₅₆ nanowheel.

3. A Keplerian Ag₉₀ nest of Platonic and Archimedean polyhedra in different symmetry groups.

5. Observation of Contrary Thermo-responsive Trend for Single Crystal and Powder Samples in Mechano-, Thermo- and Solvato-responsive Luminescent Cubane [Ag₄I₄L₄] Cluster.