Literature DB >> 23503621

Palladium(II)-catalyzed synthesis of functionalized indenones via oxidation and cyclization of 2-(2-arylethynylphenyl)acetonitriles.

Xuxing Chen1, Qian He, Yuyuan Xie, Chunhao Yang.   

Abstract

A one-pot two-step synthesis of versatile indenones has been developed. This palladium(II)-catalyzed transformation involves generation and condensation of ortho-functionalized 1,2-benzils from 2-(2-arylethynylphenyl)acetonitriles using Ph2SO as the oxidant. The resulting 3-cyanoindenones can be converted to various valuable molecules.

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Year:  2013        PMID: 23503621     DOI: 10.1039/c3ob40103k

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN: 1477-0520            Impact factor:   3.876


  1 in total

1.  Palladium(ii)-catalyzed synthesis of indenones through the cyclization of benzenecarbaldehydes with internal alkynes.

Authors:  Jajula Kashanna; Rathod Aravind Kumar; Ravada Kishore
Journal:  RSC Adv       Date:  2019-10-02       Impact factor: 4.036

  1 in total

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