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Literature DB >> 23486774

Reactions of organolithiums with dialkyl oxalates. A flow microreactor approach to synthesis of functionalized α-keto esters.

Aiichiro Nagaki¹, Daisuke Ichinari, Jun-ichi Yoshida.

Abstract

Reactions of functionalized aryllithiums with dialkyl oxalates were achieved using a flow microreactor to obtain α-keto esters with high selectivity by virtue of fast 1 : 1 micromixing.

Entities: Chemical Gene

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Year: 2013 PMID： 23486774 DOI： 10.1039/c3cc40392k

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Review 1. Contribution of microreactor technology and flow chemistry to the development of green and sustainable synthesis.

Authors: Flavio Fanelli; Giovanna Parisi; Leonardo Degennaro; Renzo Luisi
Journal: Beilstein J Org Chem Date: 2017-03-14 Impact factor: 2.883

1 in total