Literature DB >> 23485151

Postsynthesis modification of a porous coordination polymer by LiCl To enhance H+ transport.

Satoshi Horike1, Yusuke Kamitsubo, Munehiro Inukai, Tomohiro Fukushima, Daiki Umeyama, Tomoya Itakura, Susumu Kitagawa.   

Abstract

A Ca(2+) porous coordination polymer with 1D channels was functionalized by the postsynthesis addition of LiCl to enhance the H(+) conductivity. The compound showed over 10(-2) S cm(-1) at 25 °C and 20% relative humidity. Pulse-field gradient NMR elucidated that the fast H(+) conductivity was achieved by the support of Li(+) ion movements in the channel.

Entities:  

Year:  2013        PMID: 23485151     DOI: 10.1021/ja3122872

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  5 in total

1.  Entrapment of metal clusters in metal-organic framework channels by extended hooks anchored at open metal sites.

Authors:  Shou-Tian Zheng; Xiang Zhao; Samuel Lau; Addis Fuhr; Pingyun Feng; Xianhui Bu
Journal:  J Am Chem Soc       Date:  2013-07-05       Impact factor: 15.419

2.  Highly Efficient Proton Conduction in the Metal-Organic Framework Material MFM-300(Cr)·SO4(H3O)2.

Authors:  Jin Chen; Qingqing Mei; Yinlin Chen; Christopher Marsh; Bing An; Xue Han; Ian P Silverwood; Ming Li; Yongqiang Cheng; Meng He; Xi Chen; Weiyao Li; Meredydd Kippax-Jones; Danielle Crawshaw; Mark D Frogley; Sarah J Day; Victoria García-Sakai; Pascal Manuel; Anibal J Ramirez-Cuesta; Sihai Yang; Martin Schröder
Journal:  J Am Chem Soc       Date:  2022-07-01       Impact factor: 16.383

3.  Superprotonic conduction of intrinsically zwitterionic microporous polymers based on easy-to-make squaraine, croconaine and rhodizaine dyes.

Authors:  Dominic Taylor; Xuanhe Hu; Can-Min Wu; John M Tobin; Zuzana Oriou; Jun He; Zhengtao Xu; Filipe Vilela
Journal:  Nanoscale Adv       Date:  2022-06-08

4.  Proton Conduction in a Phosphonate-Based Metal-Organic Framework Mediated by Intrinsic "Free Diffusion inside a Sphere".

Authors:  Simona Pili; Stephen P Argent; Christopher G Morris; Peter Rought; Victoria García-Sakai; Ian P Silverwood; Timothy L Easun; Ming Li; Mark R Warren; Claire A Murray; Chiu C Tang; Sihai Yang; Martin Schröder
Journal:  J Am Chem Soc       Date:  2016-05-16       Impact factor: 15.419

5.  1000-fold enhancement in proton conductivity of a MOF using post-synthetically anchored proton transporters.

Authors:  Sorout Shalini; Vishal M Dhavale; Kavalakal M Eldho; Sreekumar Kurungot; Thallaseril G Ajithkumar; Ramanathan Vaidhyanathan
Journal:  Sci Rep       Date:  2016-08-31       Impact factor: 4.379

  5 in total

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