| Literature DB >> 23485063 |
Sihai Yang1, Leifeng Liu, Junliang Sun, K Mark Thomas, Andrew J Davies, Michael W George, Alexander J Blake, Adrian H Hill, Andrew N Fitch, Chiu C Tang, Martin Schröder.
Abstract
Porous NOTT-202a shows exceptionally high uptake of SO2, 13.6 mmol g(-1) (87.0 wt %) at 268 K and 1.0 bar, representing the highest value reported to date for a framework material. NOTT-202a undergoes a distinct irreversible framework phase transition upon SO2 uptake at 268-283 K to give NOTT-202b which has enhanced stability due to the formation of strong π···π interactions between interpenetrated networks.Entities:
Year: 2013 PMID: 23485063 DOI: 10.1021/ja401061m
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419