Ethyl 8,13-dioxa-21-aza-penta-cyclo-[18.5.1.0(2,7).0(14,19).0(21,25)]hexa-cosa-2(7),3,5,14,16,18-hexa-ene-26-carboxyl-ate.

In the title compound, C26H31NO4, the five-membered rings of the central pyrrolizine system adopt N-envelope conformations. The ethyl acetate group adopts an extended conformation. The dihedral angle between the benzene rings is 36.6 (1)°. In the crystal, C-H⋯O hydrogen bonds form a zigzag chain running along the b-axis directions. The crystal structure is futher consolidated by C-H⋯π inter-actions.

Related literature

For the biological activity of pyrrolidine derivatives, see: Pinna et al. (2002 ▶); Araki et al. (2002 ▶). For a related structure, see: Nirmala et al. (2008 ▶).

Experimental

Crystal data

C26H31NO4

M = 421.52

Monoclinic,

a = 10.4784 (5) Å

b = 10.2624 (4) Å

c = 21.0937 (10) Å

β = 95.350 (3)°

V = 2258.40 (18) Å3

Z = 4

Mo Kα radiation

μ = 0.08 mm−1

T = 293 K

0.25 × 0.22 × 0.19 mm

Data collection

Bruker APEXII CCD area-detector diffractometer

Absorption correction: multi-scan (SADABS; Bruker, 2008 ▶) T min = 0.979, T max = 0.984

20978 measured reflections

5598 independent reflections

3092 reflections with I > 2σ(I)

R int = 0.031

Refinement

R[F 2 > 2σ(F 2)] = 0.057

wR(F 2) = 0.180

S = 1.02

5598 reflections

281 parameters

H-atom parameters constrained

Δρmax = 0.35 e Å−3

Δρmin = −0.23 e Å−3

Data collection: APEX2 (Bruker, 2008 ▶); cell refinement: SAINT (Bruker, 2008 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: ORTEP-3 (Farrugia, 2012 ▶); software used to prepare material for publication: SHELXL97 and PLATON (Spek, 2009 ▶).

Click here for additional data file.

Crystal structure: contains datablock(s) global, I. DOI: 10.1107/S1600536812049094/pv2608sup1.cif

Click here for additional data file.

Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536812049094/pv2608Isup2.hkl

Click here for additional data file.

Supplementary material file. DOI: 10.1107/S1600536812049094/pv2608Isup3.cml

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

C26H31NO4	F(000) = 904
Mr = 421.52	Dx = 1.240 Mg m−3
Monoclinic, P21/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybc	Cell parameters from 5598 reflections
a = 10.4784 (5) Å	θ = 1.9–28.3°
b = 10.2624 (4) Å	µ = 0.08 mm−1
c = 21.0937 (10) Å	T = 293 K
β = 95.350 (3)°	Block, colorless
V = 2258.40 (18) Å3	0.25 × 0.22 × 0.19 mm
Z = 4

Bruker APEXII CCD area-detector diffractometer	5598 independent reflections
Radiation source: fine-focus sealed tube	3092 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.031
ω and φ scans	θmax = 28.3°, θmin = 1.9°
Absorption correction: multi-scan (SADABS; Bruker, 2008)	h = −13→11
Tmin = 0.979, Tmax = 0.984	k = −13→13
20978 measured reflections	l = −25→28

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.057	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.180	H-atom parameters constrained
S = 1.02	w = 1/[σ2(Fo2) + (0.0815P)2 + 0.4765P] where P = (Fo2 + 2Fc2)/3
5598 reflections	(Δ/σ)max < 0.001
281 parameters	Δρmax = 0.35 e Å−3
0 restraints	Δρmin = −0.23 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
C1	0.8192 (2)	0.3134 (2)	0.22908 (12)	0.0675 (6)
H1A	0.8905	0.2679	0.2129	0.081*
H1B	0.8112	0.2856	0.2725	0.081*
C2	0.8361 (3)	0.4599 (3)	0.22534 (16)	0.0992 (10)
H2A	0.8050	0.5013	0.2623	0.119*
H2B	0.9261	0.4812	0.2245	0.119*
C3	0.7632 (3)	0.5066 (2)	0.16699 (14)	0.0835 (8)
H3A	0.8199	0.5460	0.1386	0.100*
H3B	0.6999	0.5705	0.1769	0.100*
C4	0.6989 (2)	0.38673 (18)	0.13682 (10)	0.0549 (5)
H4	0.6104	0.4070	0.1207	0.066*
C5	0.7702 (2)	0.32113 (19)	0.08370 (10)	0.0530 (5)
H5	0.8609	0.3446	0.0914	0.064*
C6	0.75954 (17)	0.17292 (18)	0.09547 (9)	0.0456 (4)
H6	0.7077	0.1345	0.0591	0.055*
C7	0.67976 (17)	0.16759 (17)	0.15509 (9)	0.0448 (4)
H7	0.5906	0.1727	0.1366	0.054*
C8	0.68313 (18)	0.04520 (18)	0.19466 (9)	0.0485 (5)
C9	0.7948 (2)	−0.0100 (2)	0.22369 (11)	0.0618 (6)
H9	0.8724	0.0329	0.2213	0.074*
C10	0.7937 (2)	−0.1271 (2)	0.25608 (11)	0.0709 (6)
H10	0.8698	−0.1622	0.2749	0.085*
C11	0.6808 (3)	−0.1907 (2)	0.26029 (11)	0.0721 (7)
H11	0.6803	−0.2705	0.2811	0.087*
C12	0.5678 (2)	−0.1378 (2)	0.23405 (11)	0.0669 (6)
H12	0.4908	−0.1808	0.2380	0.080*
C13	0.56846 (19)	−0.02010 (19)	0.20165 (10)	0.0520 (5)
C14	0.3735 (3)	−0.0270 (3)	0.13226 (14)	0.0883 (8)
H14A	0.2849	−0.0179	0.1414	0.106*
H14B	0.3944	−0.1191	0.1327	0.106*
C15	0.3897 (3)	0.0281 (3)	0.06888 (13)	0.0850 (8)
H15A	0.3445	−0.0267	0.0367	0.102*
H15B	0.4800	0.0259	0.0621	0.102*
C16	0.3404 (2)	0.1700 (3)	0.05960 (13)	0.0819 (8)
H16A	0.2478	0.1684	0.0516	0.098*
H16B	0.3618	0.2181	0.0987	0.098*
C17	0.3953 (2)	0.2410 (3)	0.00565 (12)	0.0754 (7)
H17A	0.3845	0.1895	−0.0330	0.090*
H17B	0.3524	0.3240	−0.0021	0.090*
C18	0.6024 (2)	0.3342 (2)	−0.01145 (10)	0.0632 (6)
C19	0.7248 (2)	0.3648 (2)	0.01703 (10)	0.0590 (5)
C20	0.8025 (3)	0.4390 (2)	−0.01830 (13)	0.0795 (7)
H20	0.8837	0.4618	−0.0002	0.095*
C21	0.7642 (4)	0.4804 (3)	−0.07941 (16)	0.1016 (11)
H21	0.8190	0.5300	−0.1020	0.122*
C22	0.6452 (4)	0.4479 (3)	−0.10624 (14)	0.1009 (11)
H22	0.6191	0.4750	−0.1475	0.121*
C23	0.5625 (3)	0.3748 (3)	−0.07280 (12)	0.0836 (8)
H23	0.4813	0.3533	−0.0913	0.100*
C24	0.8885 (2)	0.1065 (2)	0.10175 (10)	0.0535 (5)
C25	0.9933 (3)	−0.0951 (3)	0.08828 (19)	0.1080 (11)
H25A	1.0491	−0.0726	0.0558	0.130*
H25B	1.0390	−0.0777	0.1295	0.130*
C26	0.9634 (5)	−0.2220 (4)	0.0838 (3)	0.211 (3)
H26A	0.9064	−0.2437	0.1153	0.316*
H26B	1.0401	−0.2731	0.0908	0.316*
H26C	0.9222	−0.2401	0.0422	0.316*
N1	0.70022 (15)	0.29156 (15)	0.18853 (8)	0.0499 (4)
O1	0.98902 (15)	0.15226 (17)	0.12248 (9)	0.0811 (5)
O2	0.87743 (14)	−0.01498 (15)	0.08036 (8)	0.0720 (5)
O3	0.52806 (14)	0.26037 (15)	0.02487 (7)	0.0661 (4)
O4	0.45450 (13)	0.03858 (14)	0.17936 (7)	0.0621 (4)

	U11	U22	U33	U12	U13	U23
C1	0.0656 (14)	0.0668 (14)	0.0663 (14)	0.0016 (11)	−0.0136 (11)	−0.0109 (12)
C2	0.097 (2)	0.0708 (17)	0.121 (2)	−0.0092 (15)	−0.0377 (18)	−0.0207 (17)
C3	0.109 (2)	0.0525 (13)	0.0868 (18)	−0.0092 (13)	−0.0011 (16)	−0.0116 (13)
C4	0.0623 (12)	0.0417 (10)	0.0593 (12)	0.0048 (9)	−0.0021 (10)	−0.0014 (9)
C5	0.0510 (11)	0.0489 (11)	0.0587 (12)	0.0030 (9)	0.0023 (9)	0.0060 (9)
C6	0.0431 (10)	0.0465 (10)	0.0460 (10)	0.0047 (8)	−0.0023 (8)	0.0008 (8)
C7	0.0373 (9)	0.0449 (10)	0.0514 (11)	0.0019 (7)	0.0004 (8)	−0.0001 (8)
C8	0.0492 (11)	0.0465 (10)	0.0503 (11)	0.0015 (8)	0.0078 (8)	−0.0012 (8)
C9	0.0551 (12)	0.0651 (13)	0.0656 (13)	0.0085 (10)	0.0073 (10)	0.0154 (11)
C10	0.0783 (16)	0.0695 (15)	0.0662 (14)	0.0199 (13)	0.0133 (12)	0.0177 (12)
C11	0.107 (2)	0.0504 (12)	0.0629 (14)	0.0079 (13)	0.0286 (14)	0.0091 (11)
C12	0.0791 (16)	0.0552 (13)	0.0706 (15)	−0.0138 (12)	0.0285 (12)	−0.0063 (11)
C13	0.0549 (12)	0.0489 (11)	0.0537 (12)	−0.0024 (9)	0.0131 (9)	−0.0100 (9)
C14	0.0753 (17)	0.0911 (19)	0.097 (2)	−0.0247 (14)	0.0025 (15)	−0.0211 (16)
C15	0.0890 (19)	0.0872 (19)	0.0787 (18)	−0.0212 (15)	0.0070 (14)	−0.0342 (15)
C16	0.0521 (13)	0.119 (2)	0.0720 (16)	0.0111 (14)	−0.0090 (11)	−0.0198 (16)
C17	0.0604 (14)	0.0939 (18)	0.0671 (15)	0.0243 (13)	−0.0197 (12)	−0.0130 (14)
C18	0.0819 (16)	0.0564 (13)	0.0509 (12)	0.0268 (11)	0.0040 (11)	0.0060 (10)
C19	0.0708 (14)	0.0510 (11)	0.0561 (12)	0.0179 (10)	0.0105 (10)	0.0085 (10)
C20	0.0900 (18)	0.0721 (16)	0.0801 (17)	0.0206 (13)	0.0275 (14)	0.0236 (13)
C21	0.127 (3)	0.098 (2)	0.087 (2)	0.045 (2)	0.045 (2)	0.0428 (17)
C22	0.145 (3)	0.099 (2)	0.0618 (17)	0.060 (2)	0.0245 (19)	0.0282 (16)
C23	0.109 (2)	0.0799 (17)	0.0597 (15)	0.0417 (16)	−0.0056 (14)	0.0068 (13)
C24	0.0504 (12)	0.0560 (12)	0.0544 (12)	0.0093 (10)	0.0058 (9)	0.0045 (10)
C25	0.0796 (19)	0.082 (2)	0.160 (3)	0.0404 (15)	0.0002 (19)	−0.009 (2)
C26	0.146 (4)	0.091 (3)	0.388 (10)	0.064 (3)	−0.015 (5)	−0.020 (4)
N1	0.0486 (9)	0.0483 (9)	0.0519 (9)	0.0028 (7)	−0.0004 (7)	−0.0038 (7)
O1	0.0442 (9)	0.0862 (12)	0.1114 (14)	0.0063 (8)	−0.0005 (9)	−0.0067 (10)
O2	0.0611 (10)	0.0598 (9)	0.0935 (12)	0.0227 (7)	−0.0021 (8)	−0.0092 (8)
O3	0.0603 (9)	0.0730 (10)	0.0612 (9)	0.0098 (7)	−0.0146 (7)	0.0074 (8)
O4	0.0460 (8)	0.0626 (9)	0.0775 (10)	−0.0076 (7)	0.0047 (7)	−0.0152 (7)

C1—N1	1.462 (3)	C14—O4	1.415 (3)
C1—C2	1.516 (4)	C14—C15	1.476 (4)
C1—H1A	0.9700	C14—H14A	0.9700
C1—H1B	0.9700	C14—H14B	0.9700
C2—C3	1.467 (4)	C15—C16	1.552 (4)
C2—H2A	0.9700	C15—H15A	0.9700
C2—H2B	0.9700	C15—H15B	0.9700
C3—C4	1.514 (3)	C16—C17	1.509 (4)
C3—H3A	0.9700	C16—H16A	0.9700
C3—H3B	0.9700	C16—H16B	0.9700
C4—N1	1.463 (3)	C17—O3	1.427 (3)
C4—C5	1.556 (3)	C17—H17A	0.9700
C4—H4	0.9800	C17—H17B	0.9700
C5—C19	1.510 (3)	C18—O3	1.371 (3)
C5—C6	1.547 (3)	C18—C23	1.386 (3)
C5—H5	0.9800	C18—C19	1.400 (3)
C6—C24	1.508 (3)	C19—C20	1.382 (3)
C6—C7	1.575 (3)	C20—C21	1.381 (4)
C6—H6	0.9800	C20—H20	0.9300
C7—N1	1.461 (2)	C21—C22	1.362 (5)
C7—C8	1.507 (3)	C21—H21	0.9300
C7—H7	0.9800	C22—C23	1.387 (4)
C8—C9	1.390 (3)	C22—H22	0.9300
C8—C13	1.396 (3)	C23—H23	0.9300
C9—C10	1.382 (3)	C24—O1	1.198 (2)
C9—H9	0.9300	C24—O2	1.328 (3)
C10—C11	1.361 (4)	C25—C26	1.341 (6)
C10—H10	0.9300	C25—O2	1.463 (3)
C11—C12	1.371 (4)	C25—H25A	0.9700
C11—H11	0.9300	C25—H25B	0.9700
C12—C13	1.388 (3)	C26—H26A	0.9600
C12—H12	0.9300	C26—H26B	0.9600
C13—O4	1.380 (2)	C26—H26C	0.9600
N1—C1—C2	102.65 (19)	C15—C14—H14A	109.7
N1—C1—H1A	111.2	O4—C14—H14B	109.7
C2—C1—H1A	111.2	C15—C14—H14B	109.7
N1—C1—H1B	111.2	H14A—C14—H14B	108.2
C2—C1—H1B	111.2	C14—C15—C16	114.1 (2)
H1A—C1—H1B	109.2	C14—C15—H15A	108.7
C3—C2—C1	108.3 (2)	C16—C15—H15A	108.7
C3—C2—H2A	110.0	C14—C15—H15B	108.7
C1—C2—H2A	110.0	C16—C15—H15B	108.7
C3—C2—H2B	110.0	H15A—C15—H15B	107.6
C1—C2—H2B	110.0	C17—C16—C15	113.7 (2)
H2A—C2—H2B	108.4	C17—C16—H16A	108.8
C2—C3—C4	105.3 (2)	C15—C16—H16A	108.8
C2—C3—H3A	110.7	C17—C16—H16B	108.8
C4—C3—H3A	110.7	C15—C16—H16B	108.8
C2—C3—H3B	110.7	H16A—C16—H16B	107.7
C4—C3—H3B	110.7	O3—C17—C16	106.44 (18)
H3A—C3—H3B	108.8	O3—C17—H17A	110.4
N1—C4—C3	104.83 (18)	C16—C17—H17A	110.4
N1—C4—C5	106.03 (15)	O3—C17—H17B	110.4
C3—C4—C5	115.4 (2)	C16—C17—H17B	110.4
N1—C4—H4	110.1	H17A—C17—H17B	108.6
C3—C4—H4	110.1	O3—C18—C23	123.4 (2)
C5—C4—H4	110.1	O3—C18—C19	115.44 (18)
C19—C5—C6	114.87 (17)	C23—C18—C19	121.2 (3)
C19—C5—C4	114.30 (16)	C20—C19—C18	117.0 (2)
C6—C5—C4	105.27 (16)	C20—C19—C5	121.0 (2)
C19—C5—H5	107.3	C18—C19—C5	122.0 (2)
C6—C5—H5	107.3	C21—C20—C19	122.6 (3)
C4—C5—H5	107.3	C21—C20—H20	118.7
C24—C6—C5	112.41 (16)	C19—C20—H20	118.7
C24—C6—C7	116.88 (15)	C22—C21—C20	119.2 (3)
C5—C6—C7	102.34 (14)	C22—C21—H21	120.4
C24—C6—H6	108.3	C20—C21—H21	120.4
C5—C6—H6	108.3	C21—C22—C23	120.8 (3)
C7—C6—H6	108.3	C21—C22—H22	119.6
N1—C7—C8	117.63 (15)	C23—C22—H22	119.6
N1—C7—C6	106.88 (14)	C18—C23—C22	119.3 (3)
C8—C7—C6	118.99 (15)	C18—C23—H23	120.4
N1—C7—H7	103.7	C22—C23—H23	120.4
C8—C7—H7	103.7	O1—C24—O2	122.53 (19)
C6—C7—H7	103.7	O1—C24—C6	127.2 (2)
C9—C8—C13	117.10 (19)	O2—C24—C6	110.22 (17)
C9—C8—C7	124.01 (17)	C26—C25—O2	110.6 (3)
C13—C8—C7	118.87 (17)	C26—C25—H25A	109.5
C10—C9—C8	121.8 (2)	O2—C25—H25A	109.5
C10—C9—H9	119.1	C26—C25—H25B	109.5
C8—C9—H9	119.1	O2—C25—H25B	109.5
C11—C10—C9	119.8 (2)	H25A—C25—H25B	108.1
C11—C10—H10	120.1	C25—C26—H26A	109.5
C9—C10—H10	120.1	C25—C26—H26B	109.5
C10—C11—C12	120.5 (2)	H26A—C26—H26B	109.5
C10—C11—H11	119.8	C25—C26—H26C	109.5
C12—C11—H11	119.8	H26A—C26—H26C	109.5
C11—C12—C13	119.9 (2)	H26B—C26—H26C	109.5
C11—C12—H12	120.0	C7—N1—C1	119.67 (15)
C13—C12—H12	120.0	C7—N1—C4	103.34 (14)
O4—C13—C12	120.23 (19)	C1—N1—C4	106.37 (16)
O4—C13—C8	118.72 (18)	C24—O2—C25	116.4 (2)
C12—C13—C8	120.9 (2)	C18—O3—C17	120.56 (17)
O4—C14—C15	110.0 (2)	C13—O4—C14	118.34 (18)
O4—C14—H14A	109.7
N1—C1—C2—C3	−22.2 (3)	O3—C18—C19—C5	−1.1 (3)
C1—C2—C3—C4	1.8 (4)	C23—C18—C19—C5	−179.8 (2)
C2—C3—C4—N1	19.5 (3)	C6—C5—C19—C20	−126.8 (2)
C2—C3—C4—C5	−96.7 (3)	C4—C5—C19—C20	111.3 (2)
N1—C4—C5—C19	150.07 (17)	C6—C5—C19—C18	54.1 (3)
C3—C4—C5—C19	−94.4 (2)	C4—C5—C19—C18	−67.7 (3)
N1—C4—C5—C6	23.1 (2)	C18—C19—C20—C21	−1.0 (4)
C3—C4—C5—C6	138.66 (19)	C5—C19—C20—C21	179.9 (2)
C19—C5—C6—C24	107.9 (2)	C19—C20—C21—C22	0.2 (4)
C4—C5—C6—C24	−125.50 (17)	C20—C21—C22—C23	0.4 (5)
C19—C5—C6—C7	−125.90 (18)	O3—C18—C23—C22	−179.1 (2)
C4—C5—C6—C7	0.73 (18)	C19—C18—C23—C22	−0.5 (4)
C24—C6—C7—N1	98.75 (19)	C21—C22—C23—C18	−0.3 (4)
C5—C6—C7—N1	−24.51 (18)	C5—C6—C24—O1	30.9 (3)
C24—C6—C7—C8	−37.5 (2)	C7—C6—C24—O1	−87.0 (3)
C5—C6—C7—C8	−160.75 (16)	C5—C6—C24—O2	−148.88 (17)
N1—C7—C8—C9	−74.5 (2)	C7—C6—C24—O2	93.2 (2)
C6—C7—C8—C9	57.2 (3)	C8—C7—N1—C1	58.7 (2)
N1—C7—C8—C13	107.4 (2)	C6—C7—N1—C1	−78.3 (2)
C6—C7—C8—C13	−120.91 (19)	C8—C7—N1—C4	176.60 (16)
C13—C8—C9—C10	2.4 (3)	C6—C7—N1—C4	39.67 (17)
C7—C8—C9—C10	−175.7 (2)	C2—C1—N1—C7	151.1 (2)
C8—C9—C10—C11	−0.3 (4)	C2—C1—N1—C4	34.8 (3)
C9—C10—C11—C12	−1.7 (4)	C3—C4—N1—C7	−161.31 (18)
C10—C11—C12—C13	1.5 (3)	C5—C4—N1—C7	−38.75 (18)
C11—C12—C13—O4	−175.03 (19)	C3—C4—N1—C1	−34.5 (2)
C11—C12—C13—C8	0.7 (3)	C5—C4—N1—C1	88.11 (18)
C9—C8—C13—O4	173.20 (17)	O1—C24—O2—C25	5.0 (3)
C7—C8—C13—O4	−8.6 (3)	C6—C24—O2—C25	−175.1 (2)
C9—C8—C13—C12	−2.6 (3)	C26—C25—O2—C24	160.8 (4)
C7—C8—C13—C12	175.65 (18)	C23—C18—O3—C17	−11.7 (3)
O4—C14—C15—C16	−67.6 (3)	C19—C18—O3—C17	169.63 (19)
C14—C15—C16—C17	160.5 (2)	C16—C17—O3—C18	−173.41 (19)
C15—C16—C17—O3	−68.4 (3)	C12—C13—O4—C14	−63.7 (3)
O3—C18—C19—C20	179.87 (19)	C8—C13—O4—C14	120.5 (2)
C23—C18—C19—C20	1.1 (3)	C15—C14—O4—C13	−100.1 (3)

D—H···A	D—H	H···A	D···A	D—H···A
C11—H11···O4i	0.93	2.60	3.419 (3)	148
C17—H17B···Cg4ii	0.97	2.97	3.817 (3)	146
C22—H22···Cg3iii	0.93	2.94	3.770 (3)	150

Table 1

Hydrogen-bond geometry (Å, °)

Cg3 and Cg4 are the centroids of the C8–C13 and C18–C23 rings, respectively.

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C11—H11⋯O4i	0.93	2.60	3.419 (3)	148
C17—H17B⋯Cg4ii	0.97	2.97	3.817 (3)	146
C22—H22⋯Cg3iii	0.93	2.94	3.770 (3)	150

Symmetry codes: (i) ; (ii) ; (iii) .