5-Benzoyl-2-(1H-indol-3-yl)-4-[4-(propan-2-yl)phen-yl]-4,5-dihydro-furan-3-carbonitrile.

In the title compound, C29H24N2O2, the hydrofuran ring is twisted with puckering parameters Q = 0.1553 (16) Å and ϕ = 305.0 (6)°. In the crystal, the graph-set motifs of the inter-action pattern are an R2(2)(16) motif involving dimers through N-H⋯N hydrogen bonds across centres of inversion and a C(6) motif through C-H⋯O hydrogen-bond between glide-related mol-ecules. Together, these generate [101] ladder-like chains.

Related literature

For related structures, see: Suresh et al. (2012a ▶,b ▶,c ▶). For discussion on aromatic inter­actions, see: Bloom & Wheeler (2011 ▶); Martinez & Iverson (2012 ▶). For graph-set motifs, see: Bernstein et al. (1995 ▶). For puckering analysis, see: Cremer & Pople (1975 ▶).

Experimental

Crystal data

C29H24N2O2

M = 432.50

Monoclinic,

a = 17.1073 (4) Å

b = 8.1230 (2) Å

c = 17.6160 (4) Å

β = 110.325 (1)°

V = 2295.55 (9) Å3

Z = 4

Mo Kα radiation

μ = 0.08 mm−1

T = 298 K

0.30 × 0.24 × 0.18 mm

Data collection

Bruker SMART APEXII CCD diffractometer

Absorption correction: multi-scan (SADABS; Bruker, 2009 ▶) T min = 0.978, T max = 0.986

21711 measured reflections

4455 independent reflections

2979 reflections with I > 2σ(I)

R int = 0.031

Refinement

R[F 2 > 2σ(F 2)] = 0.040

wR(F 2) = 0.115

S = 1.03

4455 reflections

313 parameters

H atoms treated by a mixture of independent and constrained refinement

Δρmax = 0.14 e Å−3

Δρmin = −0.15 e Å−3

Data collection: APEX2 (Bruker, 2009 ▶); cell refinement: SAINT (Bruker, 2009 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: PLATON (Spek, 2009 ▶); software used to prepare material for publication: SHELXL97.

Click here for additional data file.

Crystal structure: contains datablock(s) I, global. DOI: 10.1107/S1600536812046764/rz5022sup1.cif

Click here for additional data file.

Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536812046764/rz5022Isup2.hkl

Click here for additional data file.

Supplementary material file. DOI: 10.1107/S1600536812046764/rz5022Isup3.cml

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

C29H24N2O2	F(000) = 912
Mr = 432.50	Dx = 1.251 Mg m−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2yn	Cell parameters from 4455 reflections
a = 17.1073 (4) Å	θ = 2.5–25.9°
b = 8.1230 (2) Å	µ = 0.08 mm−1
c = 17.6160 (4) Å	T = 298 K
β = 110.325 (1)°	Block, yellow
V = 2295.55 (9) Å3	0.30 × 0.24 × 0.18 mm
Z = 4

Bruker SMART APEXII CCD diffractometer	4455 independent reflections
Radiation source: fine-focus sealed tube	2979 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.031
ω and φ scans	θmax = 25.9°, θmin = 2.5°
Absorption correction: multi-scan (SADABS; Bruker, 2009)	h = −21→20
Tmin = 0.978, Tmax = 0.986	k = −9→9
21711 measured reflections	l = −21→21

Refinement on F2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.040	H atoms treated by a mixture of independent and constrained refinement
wR(F2) = 0.115	w = 1/[σ2(Fo2) + (0.0478P)2 + 0.3844P] where P = (Fo2 + 2Fc2)/3
S = 1.03	(Δ/σ)max < 0.001
4455 reflections	Δρmax = 0.14 e Å−3
313 parameters	Δρmin = −0.15 e Å−3
0 restraints	Extinction correction: SHELXL97 (Sheldrick, 2008), Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4
Primary atom site location: structure-invariant direct methods	Extinction coefficient: 0.0037 (8)

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
O1	0.27185 (7)	0.17860 (13)	0.26234 (6)	0.0553 (3)
O2	0.14529 (8)	0.34499 (18)	0.16547 (7)	0.0792 (4)
N1	0.49191 (10)	0.5602 (2)	0.31131 (9)	0.0752 (5)
N2	0.40406 (11)	0.3263 (2)	0.52408 (9)	0.0694 (5)
H2	0.4434 (13)	0.352 (3)	0.5722 (13)	0.088 (6)*
C38	0.41572 (11)	0.3360 (2)	0.45193 (10)	0.0611 (5)
H38	0.4652	0.3669	0.4451	0.073*
C37	0.32392 (12)	0.2788 (2)	0.51144 (10)	0.0623 (5)
C36	0.28453 (16)	0.2536 (3)	0.56731 (12)	0.0808 (6)
H36	0.3124	0.2690	0.6224	0.097*
C35	0.20349 (17)	0.2056 (3)	0.53802 (15)	0.0907 (7)
H35	0.1756	0.1862	0.5740	0.109*
C34	0.16088 (14)	0.1847 (3)	0.45517 (14)	0.0828 (6)
H34	0.1051	0.1537	0.4371	0.099*
C33	0.20012 (12)	0.2091 (2)	0.39978 (12)	0.0640 (5)
H33	0.1721 (10)	0.194 (2)	0.3426 (10)	0.063 (5)*
C32	0.28362 (11)	0.25594 (19)	0.42818 (9)	0.0527 (4)
C31	0.34395 (10)	0.29363 (19)	0.39077 (9)	0.0510 (4)
C3	0.33352 (9)	0.28117 (19)	0.30620 (9)	0.0481 (4)
C2	0.37493 (10)	0.34966 (19)	0.26182 (9)	0.0486 (4)
C1	0.43942 (11)	0.4654 (2)	0.28977 (9)	0.0544 (4)
C5	0.34552 (9)	0.27757 (19)	0.17735 (9)	0.0477 (4)
H5	0.3302	0.3663	0.1371	0.057*
C4	0.26595 (9)	0.18830 (19)	0.17900 (8)	0.0483 (4)
H4	0.2641	0.0769	0.1571	0.058*
C41	0.18682 (10)	0.2796 (2)	0.13117 (9)	0.0505 (4)
C42	0.16376 (9)	0.28783 (19)	0.04210 (9)	0.0472 (4)
C43	0.20139 (11)	0.1912 (2)	0.00015 (10)	0.0613 (5)
H43	0.2440	0.1194	0.0281	0.074*
C44	0.17592 (13)	0.2007 (3)	−0.08313 (11)	0.0751 (6)
H44	0.2012	0.1348	−0.1111	0.090*
C45	0.11360 (13)	0.3069 (2)	−0.12478 (11)	0.0725 (5)
H45	0.0966	0.3129	−0.1809	0.087*
C46	0.07638 (12)	0.4040 (3)	−0.08392 (11)	0.0741 (5)
H46	0.0343	0.4767	−0.1121	0.089*
C47	0.10122 (11)	0.3943 (2)	−0.00096 (10)	0.0633 (5)
H47	0.0755	0.4604	0.0265	0.076*
C51	0.41055 (9)	0.16822 (19)	0.16311 (9)	0.0486 (4)
C52	0.44866 (12)	0.2118 (2)	0.10860 (11)	0.0718 (5)
H52	0.4313	0.3059	0.0772	0.086*
C53	0.51201 (13)	0.1176 (3)	0.10024 (12)	0.0803 (6)
H53	0.5365	0.1498	0.0630	0.096*
C54	0.54025 (11)	−0.0221 (2)	0.14503 (10)	0.0631 (5)
C55	0.49997 (10)	−0.0680 (2)	0.19778 (10)	0.0579 (4)
H55	0.5163	−0.1640	0.2280	0.070*
C56	0.43633 (10)	0.0251 (2)	0.20650 (9)	0.0518 (4)
H56	0.4086 (9)	−0.0097 (19)	0.2440 (9)	0.059 (4)*
C6	0.61471 (13)	−0.1150 (3)	0.14021 (12)	0.0827 (6)
H6	0.6245	−0.0765	0.0916	0.099*
C7	0.69188 (13)	−0.0692 (4)	0.21299 (13)	0.1129 (9)
H7A	0.6812	−0.0901	0.2621	0.169*
H7B	0.7043	0.0453	0.2101	0.169*
H7C	0.7385	−0.1343	0.2123	0.169*
C8	0.60164 (18)	−0.2977 (3)	0.1318 (2)	0.1309 (11)
H8A	0.5946	−0.3408	0.1797	0.196*
H8B	0.6492	−0.3484	0.1244	0.196*
H8C	0.5528	−0.3208	0.0857	0.196*

	U11	U22	U33	U12	U13	U23
O1	0.0631 (7)	0.0602 (7)	0.0400 (6)	−0.0138 (6)	0.0145 (5)	−0.0035 (5)
O2	0.0800 (9)	0.1019 (10)	0.0621 (8)	0.0212 (8)	0.0331 (7)	−0.0097 (7)
N1	0.0769 (11)	0.0719 (11)	0.0629 (10)	−0.0211 (9)	0.0067 (8)	−0.0012 (8)
N2	0.0827 (12)	0.0747 (11)	0.0406 (9)	−0.0067 (9)	0.0087 (8)	−0.0032 (7)
C38	0.0699 (11)	0.0623 (11)	0.0458 (10)	−0.0031 (9)	0.0134 (8)	−0.0008 (8)
C37	0.0830 (14)	0.0546 (10)	0.0484 (10)	0.0046 (10)	0.0217 (9)	0.0016 (8)
C36	0.1129 (18)	0.0812 (14)	0.0558 (12)	0.0064 (13)	0.0389 (12)	0.0030 (10)
C35	0.1152 (19)	0.0943 (17)	0.0842 (16)	0.0108 (15)	0.0619 (15)	0.0097 (13)
C34	0.0788 (14)	0.0842 (15)	0.0955 (17)	0.0055 (12)	0.0432 (13)	0.0062 (12)
C33	0.0687 (12)	0.0613 (11)	0.0629 (12)	0.0076 (9)	0.0242 (10)	0.0011 (9)
C32	0.0651 (11)	0.0443 (9)	0.0472 (9)	0.0069 (8)	0.0176 (8)	0.0011 (7)
C31	0.0603 (10)	0.0470 (9)	0.0413 (9)	0.0028 (8)	0.0120 (7)	0.0004 (7)
C3	0.0512 (9)	0.0442 (9)	0.0435 (9)	0.0018 (7)	0.0094 (7)	−0.0024 (7)
C2	0.0511 (9)	0.0465 (9)	0.0438 (8)	−0.0020 (8)	0.0107 (7)	−0.0027 (7)
C1	0.0584 (10)	0.0531 (10)	0.0450 (9)	−0.0036 (9)	0.0095 (8)	−0.0004 (8)
C5	0.0520 (9)	0.0473 (9)	0.0402 (8)	−0.0047 (7)	0.0115 (7)	0.0002 (7)
C4	0.0556 (9)	0.0490 (9)	0.0394 (8)	−0.0055 (7)	0.0155 (7)	−0.0059 (7)
C41	0.0511 (9)	0.0531 (9)	0.0485 (9)	−0.0050 (8)	0.0188 (8)	−0.0101 (7)
C42	0.0453 (9)	0.0486 (9)	0.0460 (9)	−0.0057 (7)	0.0137 (7)	−0.0074 (7)
C43	0.0677 (11)	0.0652 (11)	0.0506 (10)	0.0086 (9)	0.0199 (8)	−0.0026 (8)
C44	0.0912 (14)	0.0846 (14)	0.0548 (11)	0.0057 (12)	0.0320 (11)	−0.0082 (10)
C45	0.0856 (14)	0.0795 (14)	0.0462 (10)	−0.0104 (11)	0.0149 (10)	0.0021 (10)
C46	0.0728 (12)	0.0755 (13)	0.0581 (12)	0.0063 (10)	0.0030 (10)	0.0016 (10)
C47	0.0568 (10)	0.0696 (12)	0.0568 (11)	0.0039 (9)	0.0110 (8)	−0.0088 (9)
C51	0.0525 (9)	0.0532 (9)	0.0392 (8)	−0.0068 (8)	0.0148 (7)	−0.0013 (7)
C52	0.0848 (13)	0.0751 (13)	0.0671 (12)	0.0079 (11)	0.0410 (11)	0.0220 (10)
C53	0.0857 (14)	0.1008 (16)	0.0742 (13)	0.0119 (12)	0.0528 (11)	0.0227 (12)
C54	0.0628 (11)	0.0780 (13)	0.0539 (10)	0.0029 (10)	0.0271 (9)	−0.0005 (9)
C55	0.0620 (11)	0.0598 (11)	0.0529 (10)	0.0034 (9)	0.0212 (8)	0.0046 (8)
C56	0.0579 (10)	0.0575 (10)	0.0445 (9)	−0.0049 (8)	0.0234 (8)	0.0026 (8)
C6	0.0760 (13)	0.1117 (18)	0.0713 (13)	0.0184 (13)	0.0393 (11)	0.0067 (12)
C7	0.0725 (15)	0.190 (3)	0.0792 (16)	0.0226 (16)	0.0300 (13)	0.0053 (16)
C8	0.125 (2)	0.110 (2)	0.182 (3)	0.0356 (18)	0.084 (2)	−0.005 (2)

O1—C3	1.3557 (18)	C42—C43	1.381 (2)
O1—C4	1.4384 (17)	C43—C44	1.380 (2)
O2—C41	1.2043 (18)	C43—H43	0.9300
N1—C1	1.143 (2)	C44—C45	1.370 (3)
N2—C38	1.356 (2)	C44—H44	0.9300
N2—C37	1.366 (2)	C45—C46	1.365 (3)
N2—H2	0.91 (2)	C45—H45	0.9300
C38—C31	1.367 (2)	C46—C47	1.375 (2)
C38—H38	0.9300	C46—H46	0.9300
C37—C36	1.388 (3)	C47—H47	0.9300
C37—C32	1.399 (2)	C51—C56	1.377 (2)
C36—C35	1.358 (3)	C51—C52	1.381 (2)
C36—H36	0.9300	C52—C53	1.376 (3)
C35—C34	1.397 (3)	C52—H52	0.9300
C35—H35	0.9300	C53—C54	1.371 (3)
C34—C33	1.378 (3)	C53—H53	0.9300
C34—H34	0.9300	C54—C55	1.387 (2)
C33—C32	1.392 (2)	C54—C6	1.508 (3)
C33—H33	0.961 (16)	C55—C56	1.377 (2)
C32—C31	1.437 (2)	C55—H55	0.9300
C31—C3	1.441 (2)	C56—H56	0.978 (15)
C3—C2	1.344 (2)	C6—C8	1.501 (3)
C2—C1	1.402 (2)	C6—C7	1.533 (3)
C2—C5	1.513 (2)	C6—H6	0.9800
C5—C51	1.511 (2)	C7—H7A	0.9600
C5—C4	1.552 (2)	C7—H7B	0.9600
C5—H5	0.9800	C7—H7C	0.9600
C4—C41	1.516 (2)	C8—H8A	0.9600
C4—H4	0.9800	C8—H8B	0.9600
C41—C42	1.480 (2)	C8—H8C	0.9600
C42—C47	1.380 (2)
C3—O1—C4	108.23 (11)	C43—C42—C41	122.63 (15)
C38—N2—C37	109.26 (16)	C44—C43—C42	120.21 (17)
C38—N2—H2	124.0 (13)	C44—C43—H43	119.9
C37—N2—H2	126.6 (12)	C42—C43—H43	119.9
N2—C38—C31	109.88 (16)	C45—C44—C43	120.31 (17)
N2—C38—H38	125.1	C45—C44—H44	119.8
C31—C38—H38	125.1	C43—C44—H44	119.8
N2—C37—C36	129.28 (18)	C46—C45—C44	120.01 (17)
N2—C37—C32	108.03 (15)	C46—C45—H45	120.0
C36—C37—C32	122.68 (19)	C44—C45—H45	120.0
C35—C36—C37	117.1 (2)	C45—C46—C47	119.89 (18)
C35—C36—H36	121.4	C45—C46—H46	120.1
C37—C36—H36	121.4	C47—C46—H46	120.1
C36—C35—C34	121.69 (19)	C46—C47—C42	120.99 (17)
C36—C35—H35	119.2	C46—C47—H47	119.5
C34—C35—H35	119.2	C42—C47—H47	119.5
C33—C34—C35	121.1 (2)	C56—C51—C52	117.70 (15)
C33—C34—H34	119.4	C56—C51—C5	121.09 (13)
C35—C34—H34	119.4	C52—C51—C5	121.15 (15)
C34—C33—C32	118.44 (19)	C53—C52—C51	120.76 (17)
C34—C33—H33	122.3 (10)	C53—C52—H52	119.6
C32—C33—H33	119.2 (10)	C51—C52—H52	119.6
C33—C32—C37	118.90 (16)	C54—C53—C52	122.15 (16)
C33—C32—C31	134.73 (15)	C54—C53—H53	118.9
C37—C32—C31	106.34 (15)	C52—C53—H53	118.9
C38—C31—C32	106.48 (14)	C53—C54—C55	116.79 (16)
C38—C31—C3	125.98 (15)	C53—C54—C6	121.17 (16)
C32—C31—C3	127.46 (15)	C55—C54—C6	121.95 (17)
C2—C3—O1	112.70 (13)	C56—C55—C54	121.53 (17)
C2—C3—C31	132.15 (15)	C56—C55—H55	119.2
O1—C3—C31	115.13 (13)	C54—C55—H55	119.2
C3—C2—C1	125.62 (14)	C51—C56—C55	121.00 (15)
C3—C2—C5	110.44 (13)	C51—C56—H56	118.8 (9)
C1—C2—C5	123.86 (14)	C55—C56—H56	120.2 (9)
N1—C1—C2	178.90 (18)	C8—C6—C54	113.64 (18)
C51—C5—C2	112.23 (12)	C8—C6—C7	112.2 (2)
C51—C5—C4	115.45 (13)	C54—C6—C7	109.29 (17)
C2—C5—C4	99.01 (11)	C8—C6—H6	107.1
C51—C5—H5	109.9	C54—C6—H6	107.1
C2—C5—H5	109.9	C7—C6—H6	107.1
C4—C5—H5	109.9	C6—C7—H7A	109.5
O1—C4—C41	109.06 (12)	C6—C7—H7B	109.5
O1—C4—C5	107.08 (11)	H7A—C7—H7B	109.5
C41—C4—C5	112.38 (12)	C6—C7—H7C	109.5
O1—C4—H4	109.4	H7A—C7—H7C	109.5
C41—C4—H4	109.4	H7B—C7—H7C	109.5
C5—C4—H4	109.4	C6—C8—H8A	109.5
O2—C41—C42	121.68 (15)	C6—C8—H8B	109.5
O2—C41—C4	120.35 (14)	H8A—C8—H8B	109.5
C42—C41—C4	117.96 (13)	C6—C8—H8C	109.5
C47—C42—C43	118.59 (15)	H8A—C8—H8C	109.5
C47—C42—C41	118.78 (14)	H8B—C8—H8C	109.5
C37—N2—C38—C31	−0.6 (2)	C2—C5—C4—O1	−15.46 (14)
C38—N2—C37—C36	−179.78 (19)	C51—C5—C4—C41	−135.75 (13)
C38—N2—C37—C32	0.6 (2)	C2—C5—C4—C41	104.28 (13)
N2—C37—C36—C35	−179.8 (2)	O1—C4—C41—O2	7.6 (2)
C32—C37—C36—C35	−0.3 (3)	C5—C4—C41—O2	−110.94 (17)
C37—C36—C35—C34	−1.0 (3)	O1—C4—C41—C42	−173.49 (12)
C36—C35—C34—C33	1.3 (3)	C5—C4—C41—C42	67.93 (17)
C35—C34—C33—C32	−0.2 (3)	O2—C41—C42—C47	10.5 (2)
C34—C33—C32—C37	−1.0 (3)	C4—C41—C42—C47	−168.32 (14)
C34—C33—C32—C31	−179.20 (18)	O2—C41—C42—C43	−168.36 (17)
N2—C37—C32—C33	−179.12 (16)	C4—C41—C42—C43	12.8 (2)
C36—C37—C32—C33	1.3 (3)	C47—C42—C43—C44	−0.6 (3)
N2—C37—C32—C31	−0.42 (19)	C41—C42—C43—C44	178.27 (16)
C36—C37—C32—C31	179.96 (16)	C42—C43—C44—C45	0.5 (3)
N2—C38—C31—C32	0.32 (19)	C43—C44—C45—C46	0.0 (3)
N2—C38—C31—C3	−176.61 (15)	C44—C45—C46—C47	−0.4 (3)
C33—C32—C31—C38	178.46 (19)	C45—C46—C47—C42	0.3 (3)
C37—C32—C31—C38	0.07 (18)	C43—C42—C47—C46	0.3 (3)
C33—C32—C31—C3	−4.7 (3)	C41—C42—C47—C46	−178.69 (16)
C37—C32—C31—C3	176.94 (15)	C2—C5—C51—C56	63.99 (19)
C4—O1—C3—C2	−5.21 (17)	C4—C5—C51—C56	−48.45 (19)
C4—O1—C3—C31	176.25 (13)	C2—C5—C51—C52	−113.25 (17)
C38—C31—C3—C2	−23.4 (3)	C4—C5—C51—C52	134.30 (16)
C32—C31—C3—C2	160.29 (17)	C56—C51—C52—C53	−2.1 (3)
C38—C31—C3—O1	154.78 (15)	C5—C51—C52—C53	175.27 (17)
C32—C31—C3—O1	−21.5 (2)	C51—C52—C53—C54	−0.1 (3)
O1—C3—C2—C1	177.33 (14)	C52—C53—C54—C55	2.1 (3)
C31—C3—C2—C1	−4.4 (3)	C52—C53—C54—C6	−174.53 (19)
O1—C3—C2—C5	−5.75 (18)	C53—C54—C55—C56	−1.9 (3)
C31—C3—C2—C5	172.48 (16)	C6—C54—C55—C56	174.67 (17)
C3—C2—C5—C51	−109.41 (15)	C52—C51—C56—C55	2.2 (2)
C1—C2—C5—C51	67.58 (19)	C5—C51—C56—C55	−175.12 (14)
C3—C2—C5—C4	12.92 (16)	C54—C55—C56—C51	−0.2 (3)
C1—C2—C5—C4	−170.09 (15)	C53—C54—C6—C8	−133.9 (2)
C3—O1—C4—C41	−108.29 (13)	C55—C54—C6—C8	49.6 (3)
C3—O1—C4—C5	13.55 (15)	C53—C54—C6—C7	99.9 (2)
C51—C5—C4—O1	104.52 (14)	C55—C54—C6—C7	−76.6 (2)

D—H···A	D—H	H···A	D···A	D—H···A
C33—H33···O1	0.961 (16)	2.569 (15)	3.081 (2)	113.5 (11)
N2—H2···N1i	0.91 (2)	2.09 (2)	2.973 (2)	165.2 (17)
C56—H56···O2ii	0.978 (15)	2.411 (16)	3.371 (2)	166.9 (13)

Table 1

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
N2—H2⋯N1i	0.91 (2)	2.09 (2)	2.973 (2)	165.2 (17)
C56—H56⋯O2ii	0.978 (15)	2.411 (16)	3.371 (2)	166.9 (13)

Symmetry codes: (i) ; (ii) .