Literature DB >> 23472715

Copper catalyzed decarboxylative alkynylation of quaternary α-cyano acetate salts.

Yi-Si Feng1, Zhong-Qiu Xu, Long Mao, Feng-Feng Zhang, Hua-Jian Xu.   

Abstract

Cu-catalyzed decarboxylative alkynylation of quaternary α-cyano acetate salts with alkynyl bromides and alkynyl chlorides is described. This new reaction can be used for preparing functionalized butynenitrile derivatives.

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Year:  2013        PMID: 23472715     DOI: 10.1021/ol400197y

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

1.  Decarboxylative Alkynylation.

Authors:  Joel M Smith; Tian Qin; Rohan R Merchant; Jacob T Edwards; Lara R Malins; Zhiqing Liu; Guanda Che; Zichao Shen; Scott A Shaw; Martin D Eastgate; Phil S Baran
Journal:  Angew Chem Int Ed Engl       Date:  2017-08-01       Impact factor: 15.336

2.  SOMOphilic Alkynylation of Unreactive Alkenes Enabled by Iron-Catalyzed Hydrogen Atom Transfer.

Authors:  Binlin Zhao; Tianxiang Zhu; Mengtao Ma; Zhuangzhi Shi
Journal:  Molecules       Date:  2021-12-22       Impact factor: 4.411

  2 in total

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