| Literature DB >> 23470137 |
Jerome Canivet1, Sonia Aguado, Yves Schuurman, David Farrusseng.
Abstract
The one-pot postfunctionalization allows anchoring a molecular nickel complex into a mesoporous metal-organic framework (Ni@(Fe)MIL-101). It is generating a very active and reusable catalyst for the liquid-phase ethylene dimerization to selectively form 1-butene. Higher selectivity for 1-butene is found using the Ni@(Fe)MIL-101 catalyst than reported for molecular nickel diimino complexes.Entities:
Year: 2013 PMID: 23470137 DOI: 10.1021/ja312120x
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419