Literature DB >> 23468798

[2,7-Dibut-oxy-8-(4-fluoro-benzo-yl)naphthalen-1-yl](4-fluoro-phen-yl)methanone.

Daichi Hijikata1, Kosuke Sasagawa, Sayaka Yoshiwaka, Akiko Okamoto, Noriyuki Yonezawa.   

Abstract

In the title compound, C32H30F2O4, the benzene rings of the benzoyl groups make dihedral angles of 74.55 (6) and 74.39 (7)° with the naphthalene ring system. In the crystal, intra- and inter-molecular C-H⋯π inter-actions are observed between the but-oxy group and the aromatic rings. There are also C-H⋯F hydrogen bonds present that link the mol-ecules into chains propagating along [010].

Entities:  

Year:  2012        PMID： 23468798      PMCID： PMC3588833          DOI： 10.1107/S1600536812044923

Source DB:  PubMed          Journal:  Acta Crystallogr Sect E Struct Rep Online        ISSN： 1600-5368


Related literature

For the electrophilic aromatic aroylation of 2,7-dimeth­oxy­naphthalene, see: Okamoto & Yonezawa (2009 ▶); Okamoto et al. (2011 ▶, 2012 ▶). For the crystal structures of similar compounds, see: Sasagawa et al. (2011 ▶); Watanabe et al. (2010 ▶).

Experimental

Crystal data

C32H30F2O4 M = 516.56 Monoclinic, a = 8.26012 (15) Å b = 20.2309 (4) Å c = 16.5268 (3) Å β = 99.918 (1)° V = 2720.51 (9) Å3 Z = 4 Cu Kα radiation μ = 0.75 mm−1 T = 193 K 0.60 × 0.50 × 0.50 mm

Data collection

Rigaku R-AXIS RAPID diffractometer Absorption correction: numerical (NUMABS; Higashi, 1999 ▶) T min = 0.661, T max = 0.705 50395 measured reflections 4971 independent reflections 4715 reflections with I > 2σ(I) R int = 0.047

Refinement

R[F 2 > 2σ(F 2)] = 0.045 wR(F 2) = 0.116 S = 1.03 4971 reflections 346 parameters H-atom parameters constrained Δρmax = 0.35 e Å−3 Δρmin = −0.41 e Å−3 Data collection: PROCESS-AUTO (Rigaku, 1998 ▶); cell refinement: PROCESS-AUTO; data reduction: PROCESS-AUTO; program(s) used to solve structure: Il Milione (Burla et al., 2007 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: ORTEPIII (Burnett & Johnson, 1996 ▶); software used to prepare material for publication: SHELXL97. Click here for additional data file. Crystal structure: contains datablock(s) I, global. DOI: 10.1107/S1600536812044923/su2520sup1.cif Click here for additional data file. Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536812044923/su2520Isup2.hkl Click here for additional data file. Supplementary material file. DOI: 10.1107/S1600536812044923/su2520Isup3.cml Additional supplementary materials: crystallographic information; 3D view; checkCIF report
C32H30F2O4F(000) = 1088
Mr = 516.56Dx = 1.261 Mg m−3
Monoclinic, P21/cCu Kα radiation, λ = 1.54187 Å
Hall symbol: -P 2ybcCell parameters from 45409 reflections
a = 8.26012 (15) Åθ = 3.5–68.2°
b = 20.2309 (4) ŵ = 0.75 mm−1
c = 16.5268 (3) ÅT = 193 K
β = 99.918 (1)°Block, colourless
V = 2720.51 (9) Å30.60 × 0.50 × 0.50 mm
Z = 4
Rigaku R-AXIS RAPID diffractometer4971 independent reflections
Radiation source: rotating anode4715 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.047
Detector resolution: 10.000 pixels mm-1θmax = 68.2°, θmin = 3.5°
ω scansh = −9→9
Absorption correction: numerical (NUMABS; Higashi, 1999)k = −24→24
Tmin = 0.661, Tmax = 0.705l = −19→19
50395 measured reflections
Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.045H-atom parameters constrained
wR(F2) = 0.116w = 1/[σ2(Fo2) + (0.0573P)2 + 1.0814P] where P = (Fo2 + 2Fc2)/3
S = 1.03(Δ/σ)max < 0.001
4971 reflectionsΔρmax = 0.35 e Å−3
346 parametersΔρmin = −0.41 e Å−3
0 restraintsExtinction correction: SHELXL97 (Sheldrick, 2008), Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4
Primary atom site location: structure-invariant direct methodsExtinction coefficient: 0.0198 (6)
Experimental. Spectroscopic data for the title compound:1HNMR δ (300 MHz, CDCl3): 0.68 (6H, t, J=7.5 Hz), 0.90–1.02 (4H, m), 1.27–1.36 (4H, m) 3.89 (4H, t, J=6.1 Hz), 7.04 (4H, t, J=8.5 Hz), 7.15 (2H, d, J=8.9 Hz), 7.75 (4H, dd, J=8.5, 5.1 Hz), 7.91 (2H, d, J=8.9 Hz) p.p.m.13CNMR δ (75 MHz, CDCl3): 13.49, 18.63, 30.93, 68.55, 111.63, 114.93 (d, 2JC—F=21.6 Hz), 120.78, 125.28, 130.33, 131.49 (d, 3JC—F=7.9 Hz), 132.23, 135.68(d, 4JC—F=2.8 Hz), 155.94, 165.45(d, 1JC—F=253.5 Hz), 196.16 p.p.m.IR (KBr): 1659 (C═O), 1595, 1508, 1466 (Ar, naphthalene), 1236 (═C—O—C) cm-1.
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.
xyzUiso*/Ueq
F11.2676 (2)0.02657 (7)0.89453 (9)0.1074 (6)
F20.04618 (12)−0.02158 (5)0.58323 (6)0.0579 (3)
O10.56247 (13)0.14733 (5)0.77614 (7)0.0455 (3)
O20.72484 (11)0.12311 (5)0.61173 (6)0.0383 (3)
O30.84151 (15)0.25811 (5)0.87922 (6)0.0486 (3)
O40.44905 (13)0.20244 (5)0.46369 (6)0.0405 (3)
C10.71284 (15)0.24026 (6)0.74515 (8)0.0313 (3)
C20.78418 (17)0.28485 (7)0.80412 (9)0.0353 (3)
C30.79004 (17)0.35302 (7)0.78743 (9)0.0381 (3)
H30.84290.38270.82810.046*
C40.71875 (17)0.37570 (7)0.71201 (9)0.0376 (3)
H40.72080.42180.70100.045*
C50.56894 (17)0.35703 (7)0.57188 (10)0.0392 (3)
H50.56840.40330.56240.047*
C60.49959 (18)0.31636 (7)0.51018 (9)0.0393 (3)
H60.45010.33400.45860.047*
C70.50210 (16)0.24734 (7)0.52385 (8)0.0335 (3)
C80.56831 (15)0.22084 (6)0.59952 (8)0.0301 (3)
C90.64011 (15)0.26306 (6)0.66526 (8)0.0298 (3)
C100.64187 (16)0.33263 (7)0.64976 (9)0.0338 (3)
C110.69783 (18)0.17029 (7)0.77425 (8)0.0347 (3)
C120.8510 (2)0.13180 (7)0.80393 (9)0.0406 (4)
C130.8421 (3)0.07733 (8)0.85437 (11)0.0577 (5)
H130.73980.06430.86820.069*
C140.9857 (4)0.04188 (9)0.88456 (13)0.0755 (7)
H140.98210.00480.91940.091*
C151.1306 (3)0.06148 (10)0.86313 (13)0.0699 (6)
C161.1431 (2)0.11352 (10)0.81259 (12)0.0608 (5)
H161.24550.12510.79770.073*
C171.0016 (2)0.14922 (8)0.78338 (10)0.0462 (4)
H171.00780.18620.74870.055*
C180.58717 (16)0.14675 (6)0.60404 (8)0.0302 (3)
C190.43961 (16)0.10364 (6)0.59768 (8)0.0314 (3)
C200.45880 (19)0.03641 (7)0.58633 (10)0.0414 (3)
H200.56430.01930.58250.050*
C210.3262 (2)−0.00605 (8)0.58051 (11)0.0492 (4)
H210.3386−0.05200.57170.059*
C220.17610 (19)0.02009 (8)0.58782 (9)0.0419 (4)
C230.15121 (18)0.08624 (8)0.59960 (9)0.0413 (3)
H230.04560.10270.60450.050*
C240.28524 (17)0.12828 (7)0.60418 (9)0.0369 (3)
H240.27140.17430.61180.044*
C250.88713 (18)0.29933 (7)0.94971 (9)0.0382 (3)
H25A0.79520.32890.95690.046*
H25B0.98360.32680.94380.046*
C260.92802 (18)0.25342 (8)1.02206 (9)0.0398 (3)
H26A0.83010.22611.02570.048*
H26B0.95220.28031.07280.048*
C271.07163 (19)0.20804 (9)1.01883 (10)0.0479 (4)
H27A1.17070.23491.01620.057*
H27B1.04860.18100.96820.057*
C281.1057 (3)0.16282 (13)1.09237 (14)0.0802 (7)
H28A1.00700.13691.09610.096*
H28B1.13590.18931.14240.096*
H28C1.19630.13291.08640.096*
C290.3849 (2)0.22518 (8)0.38231 (9)0.0450 (4)
H29A0.46140.25730.36400.054*
H29B0.27750.24710.38120.054*
C300.3653 (2)0.16535 (9)0.32649 (10)0.0513 (4)
H30A0.32800.18050.26930.062*
H30B0.47430.14440.32880.062*
C310.2476 (2)0.11429 (10)0.34659 (12)0.0576 (5)
H31A0.14050.13560.34850.069*
H31B0.28950.09610.40180.069*
C320.2216 (3)0.05793 (10)0.28513 (12)0.0640 (5)
H32A0.32840.04040.27730.077*
H32B0.16160.07420.23250.077*
H32C0.15790.02280.30590.077*
U11U22U33U12U13U23
F10.1195 (12)0.0818 (9)0.0989 (10)0.0636 (9)−0.0436 (9)−0.0190 (8)
F20.0509 (6)0.0487 (5)0.0696 (7)−0.0224 (4)−0.0023 (5)0.0128 (5)
O10.0498 (6)0.0446 (6)0.0423 (6)−0.0115 (5)0.0087 (5)−0.0009 (5)
O20.0314 (5)0.0375 (5)0.0448 (6)0.0028 (4)0.0034 (4)−0.0010 (4)
O30.0672 (7)0.0353 (5)0.0363 (6)0.0048 (5)−0.0103 (5)−0.0082 (4)
O40.0463 (6)0.0388 (5)0.0322 (5)−0.0041 (4)−0.0056 (4)0.0028 (4)
C10.0283 (6)0.0300 (7)0.0351 (7)0.0008 (5)0.0040 (5)−0.0022 (5)
C20.0325 (7)0.0353 (7)0.0367 (7)0.0024 (5)0.0017 (6)−0.0040 (6)
C30.0348 (7)0.0335 (7)0.0450 (8)−0.0030 (6)0.0040 (6)−0.0093 (6)
C40.0354 (7)0.0281 (7)0.0494 (8)−0.0024 (5)0.0082 (6)−0.0016 (6)
C50.0373 (7)0.0292 (7)0.0501 (9)−0.0004 (6)0.0048 (6)0.0070 (6)
C60.0354 (7)0.0390 (8)0.0410 (8)−0.0004 (6)−0.0008 (6)0.0101 (6)
C70.0267 (6)0.0365 (7)0.0360 (7)−0.0029 (5)0.0016 (5)0.0016 (6)
C80.0250 (6)0.0307 (7)0.0343 (7)−0.0020 (5)0.0043 (5)0.0012 (5)
C90.0238 (6)0.0306 (7)0.0350 (7)−0.0009 (5)0.0054 (5)−0.0002 (5)
C100.0288 (6)0.0309 (7)0.0421 (8)−0.0007 (5)0.0073 (6)0.0008 (6)
C110.0439 (8)0.0330 (7)0.0262 (6)−0.0036 (6)0.0030 (5)−0.0040 (5)
C120.0572 (9)0.0293 (7)0.0307 (7)0.0032 (6)−0.0050 (6)−0.0053 (6)
C130.0858 (13)0.0362 (8)0.0443 (9)−0.0033 (8)−0.0083 (9)0.0017 (7)
C140.124 (2)0.0338 (9)0.0534 (11)0.0130 (11)−0.0264 (12)0.0031 (8)
C150.0836 (15)0.0515 (11)0.0615 (12)0.0295 (11)−0.0238 (11)−0.0164 (9)
C160.0592 (11)0.0634 (12)0.0534 (10)0.0226 (9)−0.0078 (8)−0.0186 (9)
C170.0502 (9)0.0459 (9)0.0392 (8)0.0112 (7)−0.0014 (7)−0.0071 (7)
C180.0312 (7)0.0328 (7)0.0253 (6)0.0001 (5)0.0012 (5)−0.0007 (5)
C190.0347 (7)0.0310 (7)0.0268 (6)−0.0023 (5)0.0002 (5)0.0008 (5)
C200.0403 (8)0.0338 (7)0.0491 (9)0.0004 (6)0.0046 (6)−0.0003 (6)
C210.0551 (10)0.0290 (7)0.0616 (10)−0.0069 (7)0.0044 (8)−0.0001 (7)
C220.0418 (8)0.0389 (8)0.0416 (8)−0.0143 (6)−0.0025 (6)0.0077 (6)
C230.0332 (7)0.0435 (8)0.0455 (8)−0.0037 (6)0.0025 (6)0.0066 (6)
C240.0355 (7)0.0315 (7)0.0422 (8)−0.0007 (6)0.0029 (6)0.0014 (6)
C250.0406 (8)0.0385 (8)0.0357 (7)−0.0051 (6)0.0067 (6)−0.0106 (6)
C260.0393 (8)0.0463 (8)0.0343 (7)−0.0035 (6)0.0076 (6)−0.0082 (6)
C270.0377 (8)0.0635 (10)0.0422 (8)0.0031 (7)0.0059 (6)0.0009 (7)
C280.0728 (14)0.1043 (18)0.0640 (13)0.0279 (13)0.0127 (10)0.0292 (12)
C290.0511 (9)0.0500 (9)0.0313 (7)−0.0034 (7)0.0001 (6)0.0089 (6)
C300.0527 (9)0.0664 (11)0.0341 (8)−0.0017 (8)0.0054 (7)0.0011 (7)
C310.0510 (10)0.0684 (12)0.0541 (10)−0.0076 (8)0.0113 (8)−0.0129 (9)
C320.0810 (13)0.0589 (11)0.0475 (10)−0.0034 (10)−0.0018 (9)−0.0066 (8)
F1—C151.359 (2)C18—C191.4876 (18)
F2—C221.3566 (16)C19—C201.386 (2)
O1—C111.2160 (18)C19—C241.3904 (19)
O2—C181.2199 (16)C20—C211.382 (2)
O3—C21.3620 (17)C20—H200.9500
O3—C251.4294 (16)C21—C221.372 (2)
O4—C71.3622 (17)C21—H210.9500
O4—C291.4337 (17)C22—C231.373 (2)
C1—C21.3830 (19)C23—C241.388 (2)
C1—C91.4297 (19)C23—H230.9500
C1—C111.5070 (19)C24—H240.9500
C2—C31.409 (2)C25—C261.506 (2)
C3—C41.363 (2)C25—H25A0.9900
C3—H30.9500C25—H25B0.9900
C4—C101.413 (2)C26—C271.508 (2)
C4—H40.9500C26—H26A0.9900
C5—C61.358 (2)C26—H26B0.9900
C5—C101.413 (2)C27—C281.508 (3)
C5—H50.9500C27—H27A0.9900
C6—C71.414 (2)C27—H27B0.9900
C6—H60.9500C28—H28A0.9800
C7—C81.3839 (19)C28—H28B0.9800
C8—C91.4281 (18)C28—H28C0.9800
C8—C181.5076 (18)C29—C301.514 (2)
C9—C101.4312 (19)C29—H29A0.9900
C11—C121.495 (2)C29—H29B0.9900
C12—C171.390 (2)C30—C311.495 (3)
C12—C131.391 (2)C30—H30A0.9900
C13—C141.402 (3)C30—H30B0.9900
C13—H130.9500C31—C321.517 (2)
C14—C151.365 (4)C31—H31A0.9900
C14—H140.9500C31—H31B0.9900
C15—C161.359 (3)C32—H32A0.9800
C16—C171.388 (2)C32—H32B0.9800
C16—H160.9500C32—H32C0.9800
C17—H170.9500
C2—O3—C25120.83 (11)C19—C20—H20119.6
C7—O4—C29119.42 (11)C22—C21—C20118.14 (14)
C2—C1—C9120.04 (12)C22—C21—H21120.9
C2—C1—C11115.87 (12)C20—C21—H21120.9
C9—C1—C11123.58 (12)F2—C22—C21118.27 (14)
O3—C2—C1114.97 (12)F2—C22—C23118.52 (14)
O3—C2—C3123.29 (13)C21—C22—C23123.22 (14)
C1—C2—C3121.69 (13)C22—C23—C24117.88 (14)
C4—C3—C2118.98 (13)C22—C23—H23121.1
C4—C3—H3120.5C24—C23—H23121.1
C2—C3—H3120.5C23—C24—C19120.64 (13)
C3—C4—C10121.83 (13)C23—C24—H24119.7
C3—C4—H4119.1C19—C24—H24119.7
C10—C4—H4119.1O3—C25—C26106.19 (12)
C6—C5—C10122.08 (13)O3—C25—H25A110.5
C6—C5—H5119.0C26—C25—H25A110.5
C10—C5—H5119.0O3—C25—H25B110.5
C5—C6—C7119.06 (13)C26—C25—H25B110.5
C5—C6—H6120.5H25A—C25—H25B108.7
C7—C6—H6120.5C25—C26—C27114.69 (12)
O4—C7—C8115.38 (12)C25—C26—H26A108.6
O4—C7—C6123.22 (12)C27—C26—H26A108.6
C8—C7—C6121.31 (13)C25—C26—H26B108.6
C7—C8—C9120.23 (12)C27—C26—H26B108.6
C7—C8—C18116.83 (12)H26A—C26—H26B107.6
C9—C8—C18122.08 (11)C26—C27—C28112.29 (15)
C8—C9—C1124.26 (12)C26—C27—H27A109.1
C8—C9—C10117.89 (12)C28—C27—H27A109.1
C1—C9—C10117.84 (12)C26—C27—H27B109.1
C4—C10—C5121.04 (13)C28—C27—H27B109.1
C4—C10—C9119.56 (13)H27A—C27—H27B107.9
C5—C10—C9119.39 (13)C27—C28—H28A109.5
O1—C11—C12121.51 (13)C27—C28—H28B109.5
O1—C11—C1119.57 (13)H28A—C28—H28B109.5
C12—C11—C1118.86 (12)C27—C28—H28C109.5
C17—C12—C13119.27 (16)H28A—C28—H28C109.5
C17—C12—C11122.02 (14)H28B—C28—H28C109.5
C13—C12—C11118.71 (16)O4—C29—C30107.38 (13)
C12—C13—C14119.3 (2)O4—C29—H29A110.2
C12—C13—H13120.3C30—C29—H29A110.2
C14—C13—H13120.3O4—C29—H29B110.2
C15—C14—C13119.01 (19)C30—C29—H29B110.2
C15—C14—H14120.5H29A—C29—H29B108.5
C13—C14—H14120.5C31—C30—C29115.01 (14)
C16—C15—F1119.4 (2)C31—C30—H30A108.5
C16—C15—C14123.20 (18)C29—C30—H30A108.5
F1—C15—C14117.4 (2)C31—C30—H30B108.5
C15—C16—C17117.9 (2)C29—C30—H30B108.5
C15—C16—H16121.0H30A—C30—H30B107.5
C17—C16—H16121.0C30—C31—C32113.15 (16)
C16—C17—C12121.23 (17)C30—C31—H31A108.9
C16—C17—H17119.4C32—C31—H31A108.9
C12—C17—H17119.4C30—C31—H31B108.9
O2—C18—C19121.02 (12)C32—C31—H31B108.9
O2—C18—C8118.77 (12)H31A—C31—H31B107.8
C19—C18—C8120.20 (11)C31—C32—H32A109.5
C20—C19—C24119.35 (13)C31—C32—H32B109.5
C20—C19—C18118.26 (13)H32A—C32—H32B109.5
C24—C19—C18122.38 (12)C31—C32—H32C109.5
C21—C20—C19120.76 (14)H32A—C32—H32C109.5
C21—C20—H20119.6H32B—C32—H32C109.5
C25—O3—C2—C1−167.14 (12)O1—C11—C12—C17163.03 (14)
C25—O3—C2—C310.4 (2)C1—C11—C12—C17−19.90 (19)
C9—C1—C2—O3176.55 (12)O1—C11—C12—C13−17.7 (2)
C11—C1—C2—O34.41 (18)C1—C11—C12—C13159.41 (13)
C9—C1—C2—C3−1.0 (2)C17—C12—C13—C141.1 (2)
C11—C1—C2—C3−173.19 (13)C11—C12—C13—C14−178.22 (15)
O3—C2—C3—C4−175.24 (13)C12—C13—C14—C15−0.5 (3)
C1—C2—C3—C42.2 (2)C13—C14—C15—C16−1.0 (3)
C2—C3—C4—C10−1.2 (2)C13—C14—C15—F1179.03 (15)
C10—C5—C6—C7−0.8 (2)F1—C15—C16—C17−178.29 (15)
C29—O4—C7—C8−177.39 (12)C14—C15—C16—C171.7 (3)
C29—O4—C7—C6−0.9 (2)C15—C16—C17—C12−1.0 (2)
C5—C6—C7—O4−173.93 (13)C13—C12—C17—C16−0.4 (2)
C5—C6—C7—C82.4 (2)C11—C12—C17—C16178.95 (14)
O4—C7—C8—C9174.85 (11)C7—C8—C18—O2108.25 (14)
C6—C7—C8—C9−1.7 (2)C9—C8—C18—O2−61.18 (17)
O4—C7—C8—C185.22 (17)C7—C8—C18—C19−70.66 (16)
C6—C7—C8—C18−171.35 (12)C9—C8—C18—C19119.90 (13)
C7—C8—C9—C1−179.36 (12)O2—C18—C19—C20−11.03 (19)
C18—C8—C9—C1−10.28 (19)C8—C18—C19—C20167.86 (13)
C7—C8—C9—C10−0.46 (18)O2—C18—C19—C24167.79 (13)
C18—C8—C9—C10168.62 (12)C8—C18—C19—C24−13.32 (19)
C2—C1—C9—C8177.88 (12)C24—C19—C20—C210.7 (2)
C11—C1—C9—C8−10.6 (2)C18—C19—C20—C21179.59 (14)
C2—C1—C9—C10−1.01 (18)C19—C20—C21—C22−1.2 (2)
C11—C1—C9—C10170.50 (12)C20—C21—C22—F2−179.14 (14)
C3—C4—C10—C5−179.85 (13)C20—C21—C22—C230.8 (3)
C3—C4—C10—C9−0.9 (2)F2—C22—C23—C24179.99 (13)
C6—C5—C10—C4177.59 (14)C21—C22—C23—C240.1 (2)
C6—C5—C10—C9−1.4 (2)C22—C23—C24—C19−0.5 (2)
C8—C9—C10—C4−177.00 (12)C20—C19—C24—C230.2 (2)
C1—C9—C10—C41.96 (18)C18—C19—C24—C23−178.65 (13)
C8—C9—C10—C51.97 (18)C2—O3—C25—C26174.59 (12)
C1—C9—C10—C5−179.06 (12)O3—C25—C26—C2762.58 (16)
C2—C1—C11—O1112.36 (15)C25—C26—C27—C28−179.43 (16)
C9—C1—C11—O1−59.48 (18)C7—O4—C29—C30170.00 (12)
C2—C1—C11—C12−64.77 (16)O4—C29—C30—C3161.91 (19)
C9—C1—C11—C12123.39 (14)C29—C30—C31—C32175.40 (16)
D—H···AD—HH···AD···AD—H···A
C27—H27B···Cg10.992.793.7754 (19)175
C26—H26A···Cg2i0.992.543.4239 (16)145
C3—H3···F2ii0.952.503.4408 (17)169
Table 1

Hydrogen-bond geometry (Å, °)

Cg1 and Cg2 are the centroids of the C12–C17 and C5–C10 rings, respectively.

D—H⋯A D—HH⋯A D⋯A D—H⋯A
C27—H27B⋯Cg10.992.793.7754 (19)175
C26—H26A⋯Cg2i 0.992.543.4239 (16)145
C3—H3⋯F2ii 0.952.503.4408 (17)169

Symmetry codes: (i) ; (ii) .

  3 in total

1.  A short history of SHELX.

Authors:  George M Sheldrick
Journal:  Acta Crystallogr A       Date:  2007-12-21       Impact factor: 2.290

2.  (2,7-Dimethoxy-naphthalene-1,8-di-yl)bis-(4-fluoro-benzo-yl)dimethanone.

Authors:  Shoji Watanabe; Atsushi Nagasawa; Akiko Okamoto; Keiichi Noguchi; Noriyuki Yonezawa
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2010-01-09

3.  [8-(4-But-oxy-benzo-yl)-2,7-dimeth-oxy-naphthalen-1-yl](4-but-oxy-phen-yl)methanone.

Authors:  Kosuke Sasagawa; Toyokazu Muto; Akiko Okamoto; Hideaki Oike; Noriyuki Yonezawa
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2011-11-19
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