trans-Bis(benzyl-diphenyl-phosphane-κP)dichloridoplatinum(II).

In the mononuclear title compound, trans-[PtCl2(C19H17P)2], the slightly distorted square-planar coordination sphere of the Pt(II) atom is occupied by two benzyl-diphenyl-phosphane ligands and two chloride atoms in a mutually trans geometry. The effective cone angles for the two phosphane ligands are 160 and 169°. C-H⋯Cl inter-actions generate infinite long chains along [01-1]. Additional C-H⋯π and π-π stacking interactions [centroid-centroid distance = 4.2499 (15) Å and ring slippage = 2.386 Å] are observed.

Related literature

For reviews of related compounds, see: Spessard & Miessler (1996 ▶); Muller & Meijboom (2010 ▶). For background to cone angles, see: Tolman (1977 ▶); Otto (2001 ▶). For the cis isomer of the title compound, see: Davis & Meijboom (2011 ▶).

Experimental

Crystal data

[PtCl2(C19H17P)2]

M = 818.58

Triclinic,

a = 9.5585 (12) Å

b = 13.4135 (17) Å

c = 14.7553 (18) Å

α = 66.307 (2)°

β = 73.147 (3)°

γ = 88.034 (3)°

V = 1650.7 (4) Å3

Z = 2

Mo Kα radiation

μ = 4.54 mm−1

T = 100 K

0.24 × 0.1 × 0.08 mm

Data collection

Bruker APEX DUO 4K CCD diffractometer

Absorption correction: multi-scan (SADABS; Bruker, 2008 ▶) T min = 0.409, T max = 0.713

33198 measured reflections

8253 independent reflections

7779 reflections with I > 2σ(I)

R int = 0.031

Refinement

R[F 2 > 2σ(F 2)] = 0.018

wR(F 2) = 0.039

S = 1.03

8253 reflections

388 parameters

H-atom parameters constrained

Δρmax = 0.65 e Å−3

Δρmin = −0.54 e Å−3

Data collection: APEX2 (Bruker, 2011 ▶); cell refinement: SAINT (Bruker, 2008 ▶); data reduction: SAINT and XPREP (Bruker, 2008 ▶); program(s) used to solve structure: SIR97 (Altomare et al., 1999 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: DIAMOND (Brandenburg & Putz, 2005 ▶); software used to prepare material for publication: publCIF (Westrip, 2010 ▶) and WinGX (Farrugia, 2012) ▶.

Click here for additional data file.

Crystal structure: contains datablock(s) global, I. DOI: 10.1107/S160053681204696X/ng5305sup1.cif

Click here for additional data file.

Structure factors: contains datablock(s) I. DOI: 10.1107/S160053681204696X/ng5305Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[PtCl2(C19H17P)2]	Z = 2
Mr = 818.58	F(000) = 808
Triclinic, P1	Dx = 1.647 Mg m−3Dm = 1.647 Mg m−3Dm measured by not measured
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 9.5585 (12) Å	Cell parameters from 9225 reflections
b = 13.4135 (17) Å	θ = 2.6–28.4°
c = 14.7553 (18) Å	µ = 4.54 mm−1
α = 66.307 (2)°	T = 100 K
β = 73.147 (3)°	Needle, colourless
γ = 88.034 (3)°	0.24 × 0.1 × 0.08 mm
V = 1650.7 (4) Å3

Bruker APEX DUO 4K CCD diffractometer	8253 independent reflections
Radiation source: sealed tube	7779 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.031
Detector resolution: 8.4 pixels mm-1	θmax = 28.4°, θmin = 1.6°
φ and ω scans	h = −12→12
Absorption correction: multi-scan (SADABS; Bruker, 2008)	k = −17→17
Tmin = 0.409, Tmax = 0.713	l = −19→19
33198 measured reflections

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.018	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.039	H-atom parameters constrained
S = 1.03	w = 1/[σ2(Fo2) + (0.0157P)2 + 0.6462P] where P = (Fo2 + 2Fc2)/3
8253 reflections	(Δ/σ)max = 0.002
388 parameters	Δρmax = 0.65 e Å−3
0 restraints	Δρmin = −0.54 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
Pt1	0.435237 (8)	0.254343 (6)	0.260155 (5)	0.00938 (2)
Cl1	0.32010 (6)	0.39062 (4)	0.16068 (4)	0.01605 (10)
Cl2	0.57602 (5)	0.12862 (4)	0.34467 (4)	0.01508 (9)
P1	0.49965 (6)	0.36874 (4)	0.32689 (4)	0.01070 (10)
P2	0.39698 (6)	0.14486 (4)	0.18021 (4)	0.01132 (10)
C1	0.5284 (2)	0.30979 (16)	0.45596 (14)	0.0133 (4)
H1A	0.5961	0.252	0.4572	0.016*
H1B	0.579	0.3679	0.4636	0.016*
C2	0.3947 (2)	0.26114 (16)	0.54973 (14)	0.0136 (4)
C3	0.3107 (2)	0.32666 (17)	0.59474 (16)	0.0173 (4)
H3	0.3307	0.4039	0.5611	0.021*
C4	0.1986 (2)	0.27982 (18)	0.68797 (16)	0.0196 (4)
H4	0.1428	0.325	0.7178	0.023*
C5	0.1682 (2)	0.16662 (18)	0.73760 (16)	0.0194 (4)
H5	0.093	0.1344	0.8021	0.023*
C6	0.2477 (2)	0.10114 (17)	0.69279 (16)	0.0191 (4)
H6	0.2257	0.024	0.7261	0.023*
C7	0.3599 (2)	0.14780 (16)	0.59903 (15)	0.0163 (4)
H7	0.413	0.1023	0.5684	0.02*
C8	0.3766 (2)	0.47250 (15)	0.33790 (14)	0.0129 (4)
C9	0.2264 (2)	0.44601 (16)	0.36676 (15)	0.0155 (4)
H9	0.1906	0.3779	0.3725	0.019*
C10	0.1284 (3)	0.51857 (18)	0.38729 (16)	0.0206 (5)
H10	0.0257	0.5004	0.4063	0.025*
C11	0.1805 (3)	0.61791 (18)	0.38000 (16)	0.0232 (5)
H11	0.1135	0.667	0.3955	0.028*
C12	0.3307 (3)	0.64529 (17)	0.34999 (17)	0.0233 (5)
H12	0.3664	0.7135	0.3443	0.028*
C13	0.4290 (3)	0.57345 (16)	0.32830 (16)	0.0178 (4)
H13	0.5317	0.5928	0.307	0.021*
C14	0.6772 (2)	0.44094 (15)	0.24140 (15)	0.0130 (4)
C15	0.6881 (2)	0.50991 (17)	0.13829 (16)	0.0186 (4)
H15	0.6028	0.5205	0.116	0.022*
C16	0.8220 (3)	0.56263 (18)	0.06883 (17)	0.0220 (5)
H16	0.8277	0.6108	−0.0004	0.026*
C17	0.9486 (2)	0.54559 (18)	0.09962 (17)	0.0210 (5)
H17	1.0408	0.5812	0.0515	0.025*
C18	0.9389 (2)	0.47609 (18)	0.20123 (17)	0.0212 (5)
H18	1.025	0.4641	0.2225	0.025*
C19	0.8044 (2)	0.42395 (17)	0.27196 (16)	0.0182 (4)
H19	0.799	0.3766	0.3413	0.022*
C27	0.5508 (2)	0.17383 (16)	0.06288 (14)	0.0132 (4)
C32	0.6258 (2)	0.09293 (17)	0.03745 (16)	0.0179 (4)
H32	0.5979	0.018	0.0827	0.021*
C31	0.7414 (2)	0.12179 (17)	−0.05392 (16)	0.0192 (4)
H31	0.7925	0.0665	−0.0707	0.023*
C30	0.7826 (2)	0.23148 (17)	−0.12105 (15)	0.0180 (4)
H30	0.8613	0.251	−0.1836	0.022*
C29	0.7083 (2)	0.31196 (17)	−0.09620 (15)	0.0182 (4)
H29	0.7354	0.3867	−0.1422	0.022*
C28	0.5946 (2)	0.28397 (16)	−0.00462 (15)	0.0169 (4)
H28	0.5458	0.3398	0.0126	0.02*
C33	0.2343 (2)	0.16194 (15)	0.13646 (15)	0.0138 (4)
C38	0.2353 (3)	0.15109 (17)	0.04602 (17)	0.0205 (5)
H38	0.3239	0.1398	0.0028	0.025*
C37	0.1054 (3)	0.1569 (2)	0.01952 (19)	0.0282 (5)
H37	0.1057	0.1486	−0.0415	0.034*
C36	−0.0239 (3)	0.17476 (18)	0.08137 (17)	0.0239 (5)
H36	−0.1117	0.1786	0.0627	0.029*
C35	−0.0251 (2)	0.18690 (18)	0.17016 (17)	0.0225 (5)
H35	−0.1135	0.1996	0.2125	0.027*
C34	0.1039 (2)	0.18053 (18)	0.19755 (16)	0.0198 (4)
H34	0.1027	0.189	0.2587	0.024*
C20	0.3854 (2)	−0.00427 (15)	0.25407 (15)	0.0139 (4)
H20A	0.3845	−0.0401	0.2072	0.017*
H20B	0.4752	−0.0223	0.2758	0.017*
C21	0.2533 (2)	−0.05230 (15)	0.34940 (15)	0.0133 (4)
C26	0.2527 (2)	−0.05270 (17)	0.44434 (15)	0.0173 (4)
H26	0.3344	−0.0185	0.4488	0.021*
C25	0.1336 (3)	−0.10261 (19)	0.53223 (16)	0.0231 (5)
H25	0.1345	−0.1027	0.5965	0.028*
C24	0.0128 (2)	−0.15251 (18)	0.52703 (16)	0.0203 (4)
H24	−0.0683	−0.1871	0.5875	0.024*
C23	0.0117 (2)	−0.15134 (17)	0.43293 (16)	0.0184 (4)
H23	−0.0705	−0.1851	0.4287	0.022*
C22	0.1304 (2)	−0.10102 (16)	0.34484 (15)	0.0167 (4)
H22	0.1279	−0.0997	0.2805	0.02*

	U11	U22	U33	U12	U13	U23
Pt1	0.00944 (4)	0.00964 (4)	0.00983 (4)	0.00115 (2)	−0.00353 (3)	−0.00432 (3)
Cl1	0.0197 (3)	0.0158 (2)	0.0176 (2)	0.00698 (19)	−0.0111 (2)	−0.00844 (18)
Cl2	0.0158 (2)	0.0131 (2)	0.0189 (2)	0.00403 (18)	−0.00962 (19)	−0.00633 (18)
P1	0.0105 (2)	0.0112 (2)	0.0106 (2)	0.00044 (18)	−0.00338 (19)	−0.00455 (18)
P2	0.0119 (3)	0.0115 (2)	0.0102 (2)	−0.00023 (19)	−0.00265 (19)	−0.00438 (18)
C1	0.0133 (10)	0.0147 (9)	0.0117 (9)	0.0004 (8)	−0.0048 (8)	−0.0046 (7)
C2	0.0139 (10)	0.0171 (9)	0.0105 (8)	0.0010 (8)	−0.0062 (8)	−0.0046 (7)
C3	0.0201 (11)	0.0181 (10)	0.0171 (10)	0.0013 (8)	−0.0070 (9)	−0.0095 (8)
C4	0.0183 (11)	0.0269 (11)	0.0200 (10)	0.0054 (9)	−0.0067 (9)	−0.0155 (9)
C5	0.0149 (11)	0.0285 (11)	0.0134 (9)	−0.0006 (9)	−0.0037 (8)	−0.0074 (8)
C6	0.0171 (11)	0.0179 (10)	0.0177 (10)	0.0005 (8)	−0.0052 (9)	−0.0027 (8)
C7	0.0122 (10)	0.0180 (10)	0.0171 (9)	0.0033 (8)	−0.0037 (8)	−0.0063 (8)
C8	0.0162 (10)	0.0139 (9)	0.0099 (8)	0.0034 (8)	−0.0046 (8)	−0.0060 (7)
C9	0.0171 (11)	0.0163 (9)	0.0119 (9)	0.0006 (8)	−0.0028 (8)	−0.0055 (7)
C10	0.0186 (11)	0.0271 (11)	0.0138 (9)	0.0069 (9)	−0.0030 (8)	−0.0079 (8)
C11	0.0315 (14)	0.0231 (11)	0.0164 (10)	0.0127 (10)	−0.0058 (9)	−0.0112 (9)
C12	0.0383 (15)	0.0157 (10)	0.0199 (10)	0.0062 (9)	−0.0118 (10)	−0.0094 (8)
C13	0.0223 (12)	0.0155 (10)	0.0183 (10)	0.0008 (8)	−0.0095 (9)	−0.0073 (8)
C14	0.0128 (10)	0.0128 (9)	0.0139 (9)	−0.0001 (7)	−0.0029 (8)	−0.0066 (7)
C15	0.0170 (11)	0.0198 (10)	0.0169 (10)	−0.0003 (8)	−0.0065 (8)	−0.0043 (8)
C16	0.0220 (12)	0.0215 (11)	0.0168 (10)	−0.0037 (9)	−0.0052 (9)	−0.0023 (8)
C17	0.0161 (11)	0.0218 (11)	0.0203 (10)	−0.0048 (9)	0.0008 (9)	−0.0078 (9)
C18	0.0142 (11)	0.0262 (11)	0.0229 (11)	0.0000 (9)	−0.0067 (9)	−0.0088 (9)
C19	0.0173 (11)	0.0193 (10)	0.0170 (10)	0.0009 (8)	−0.0068 (8)	−0.0053 (8)
C27	0.0108 (10)	0.0177 (9)	0.0109 (8)	−0.0008 (8)	−0.0016 (7)	−0.0068 (7)
C32	0.0206 (11)	0.0139 (9)	0.0174 (10)	−0.0004 (8)	−0.0040 (9)	−0.0056 (8)
C31	0.0199 (12)	0.0189 (10)	0.0197 (10)	0.0030 (9)	−0.0036 (9)	−0.0107 (8)
C30	0.0143 (11)	0.0249 (11)	0.0128 (9)	0.0003 (8)	−0.0013 (8)	−0.0073 (8)
C29	0.0181 (11)	0.0168 (10)	0.0148 (9)	−0.0005 (8)	−0.0027 (8)	−0.0031 (8)
C28	0.0185 (11)	0.0153 (9)	0.0160 (9)	0.0022 (8)	−0.0033 (8)	−0.0070 (8)
C33	0.0152 (10)	0.0108 (9)	0.0147 (9)	−0.0023 (7)	−0.0058 (8)	−0.0036 (7)
C38	0.0261 (12)	0.0218 (11)	0.0203 (10)	0.0071 (9)	−0.0104 (9)	−0.0132 (9)
C37	0.0375 (15)	0.0330 (13)	0.0278 (12)	0.0054 (11)	−0.0217 (11)	−0.0180 (10)
C36	0.0221 (12)	0.0231 (11)	0.0263 (11)	−0.0044 (9)	−0.0147 (10)	−0.0043 (9)
C35	0.0130 (11)	0.0274 (11)	0.0197 (10)	−0.0026 (9)	−0.0027 (9)	−0.0034 (9)
C34	0.0168 (11)	0.0274 (11)	0.0118 (9)	−0.0046 (9)	−0.0032 (8)	−0.0049 (8)
C20	0.0153 (10)	0.0125 (9)	0.0130 (9)	0.0015 (8)	−0.0033 (8)	−0.0051 (7)
C21	0.0151 (10)	0.0098 (8)	0.0132 (9)	0.0025 (7)	−0.0034 (8)	−0.0037 (7)
C26	0.0171 (11)	0.0190 (10)	0.0158 (9)	−0.0020 (8)	−0.0059 (8)	−0.0063 (8)
C25	0.0237 (12)	0.0324 (12)	0.0131 (9)	−0.0044 (10)	−0.0041 (9)	−0.0096 (9)
C24	0.0164 (11)	0.0257 (11)	0.0159 (10)	−0.0043 (9)	−0.0002 (8)	−0.0084 (8)
C23	0.0175 (11)	0.0189 (10)	0.0191 (10)	−0.0017 (8)	−0.0053 (9)	−0.0079 (8)
C22	0.0206 (11)	0.0165 (10)	0.0135 (9)	−0.0019 (8)	−0.0055 (8)	−0.0059 (8)

Pt1—P1	2.3096 (5)	C17—C18	1.388 (3)
Pt1—Cl2	2.3102 (5)	C17—H17	0.95
Pt1—Cl1	2.3128 (5)	C18—C19	1.388 (3)
Pt1—P2	2.3155 (5)	C18—H18	0.95
P1—C14	1.817 (2)	C19—H19	0.95
P1—C8	1.818 (2)	C27—C32	1.397 (3)
P1—C1	1.8456 (19)	C27—C28	1.403 (3)
P2—C33	1.824 (2)	C32—C31	1.391 (3)
P2—C27	1.825 (2)	C32—H32	0.95
P2—C20	1.8424 (19)	C31—C30	1.394 (3)
C1—C2	1.510 (3)	C31—H31	0.95
C1—H1A	0.99	C30—C29	1.385 (3)
C1—H1B	0.99	C30—H30	0.95
C2—C7	1.399 (3)	C29—C28	1.385 (3)
C2—C3	1.403 (3)	C29—H29	0.95
C3—C4	1.390 (3)	C28—H28	0.95
C3—H3	0.95	C33—C34	1.391 (3)
C4—C5	1.393 (3)	C33—C38	1.396 (3)
C4—H4	0.95	C38—C37	1.397 (3)
C5—C6	1.384 (3)	C38—H38	0.95
C5—H5	0.95	C37—C36	1.385 (4)
C6—C7	1.395 (3)	C37—H37	0.95
C6—H6	0.95	C36—C35	1.381 (3)
C7—H7	0.95	C36—H36	0.95
C8—C9	1.388 (3)	C35—C34	1.394 (3)
C8—C13	1.398 (3)	C35—H35	0.95
C9—C10	1.388 (3)	C34—H34	0.95
C9—H9	0.95	C20—C21	1.512 (3)
C10—C11	1.391 (3)	C20—H20A	0.99
C10—H10	0.95	C20—H20B	0.99
C11—C12	1.389 (3)	C21—C22	1.395 (3)
C11—H11	0.95	C21—C26	1.397 (3)
C12—C13	1.387 (3)	C26—C25	1.387 (3)
C12—H12	0.95	C26—H26	0.95
C13—H13	0.95	C25—C24	1.390 (3)
C14—C19	1.396 (3)	C25—H25	0.95
C14—C15	1.402 (3)	C24—C23	1.385 (3)
C15—C16	1.381 (3)	C24—H24	0.95
C15—H15	0.95	C23—C22	1.387 (3)
C16—C17	1.393 (3)	C23—H23	0.95
C16—H16	0.95	C22—H22	0.95
P1—Pt1—Cl2	87.718 (19)	C18—C17—C16	119.4 (2)
P1—Pt1—Cl1	91.019 (19)	C18—C17—H17	120.3
Cl2—Pt1—Cl1	173.220 (18)	C16—C17—H17	120.3
P1—Pt1—P2	173.566 (18)	C17—C18—C19	120.6 (2)
Cl2—Pt1—P2	90.665 (19)	C17—C18—H18	119.7
Cl1—Pt1—P2	89.858 (19)	C19—C18—H18	119.7
C14—P1—C8	106.61 (9)	C18—C19—C14	120.17 (19)
C14—P1—C1	103.09 (9)	C18—C19—H19	119.9
C8—P1—C1	101.91 (9)	C14—C19—H19	119.9
C14—P1—Pt1	107.53 (7)	C32—C27—C28	118.98 (18)
C8—P1—Pt1	116.64 (7)	C32—C27—P2	123.67 (15)
C1—P1—Pt1	119.65 (7)	C28—C27—P2	117.34 (15)
C33—P2—C27	104.68 (9)	C31—C32—C27	120.15 (19)
C33—P2—C20	102.65 (9)	C31—C32—H32	119.9
C27—P2—C20	104.59 (9)	C27—C32—H32	119.9
C33—P2—Pt1	117.37 (7)	C32—C31—C30	120.3 (2)
C27—P2—Pt1	108.96 (7)	C32—C31—H31	119.8
C20—P2—Pt1	117.20 (7)	C30—C31—H31	119.8
C2—C1—P1	117.65 (14)	C29—C30—C31	119.70 (19)
C2—C1—H1A	107.9	C29—C30—H30	120.1
P1—C1—H1A	107.9	C31—C30—H30	120.1
C2—C1—H1B	107.9	C28—C29—C30	120.32 (19)
P1—C1—H1B	107.9	C28—C29—H29	119.8
H1A—C1—H1B	107.2	C30—C29—H29	119.8
C7—C2—C3	118.48 (19)	C29—C28—C27	120.50 (19)
C7—C2—C1	120.09 (18)	C29—C28—H28	119.7
C3—C2—C1	121.19 (18)	C27—C28—H28	119.7
C4—C3—C2	120.78 (19)	C34—C33—C38	119.19 (19)
C4—C3—H3	119.6	C34—C33—P2	119.13 (15)
C2—C3—H3	119.6	C38—C33—P2	121.60 (17)
C3—C4—C5	120.0 (2)	C33—C38—C37	119.6 (2)
C3—C4—H4	120	C33—C38—H38	120.2
C5—C4—H4	120	C37—C38—H38	120.2
C6—C5—C4	119.9 (2)	C36—C37—C38	120.6 (2)
C6—C5—H5	120.1	C36—C37—H37	119.7
C4—C5—H5	120.1	C38—C37—H37	119.7
C5—C6—C7	120.4 (2)	C35—C36—C37	120.0 (2)
C5—C6—H6	119.8	C35—C36—H36	120
C7—C6—H6	119.8	C37—C36—H36	120
C6—C7—C2	120.5 (2)	C36—C35—C34	119.8 (2)
C6—C7—H7	119.8	C36—C35—H35	120.1
C2—C7—H7	119.8	C34—C35—H35	120.1
C9—C8—C13	119.65 (19)	C33—C34—C35	120.8 (2)
C9—C8—P1	118.67 (15)	C33—C34—H34	119.6
C13—C8—P1	121.35 (16)	C35—C34—H34	119.6
C8—C9—C10	120.4 (2)	C21—C20—P2	115.37 (14)
C8—C9—H9	119.8	C21—C20—H20A	108.4
C10—C9—H9	119.8	P2—C20—H20A	108.4
C9—C10—C11	119.9 (2)	C21—C20—H20B	108.4
C9—C10—H10	120	P2—C20—H20B	108.4
C11—C10—H10	120	H20A—C20—H20B	107.5
C12—C11—C10	119.9 (2)	C22—C21—C26	118.42 (18)
C12—C11—H11	120	C22—C21—C20	120.11 (17)
C10—C11—H11	120	C26—C21—C20	121.43 (18)
C13—C12—C11	120.3 (2)	C25—C26—C21	120.50 (19)
C13—C12—H12	119.9	C25—C26—H26	119.8
C11—C12—H12	119.9	C21—C26—H26	119.8
C12—C13—C8	119.9 (2)	C26—C25—C24	120.50 (19)
C12—C13—H13	120.1	C26—C25—H25	119.8
C8—C13—H13	120.1	C24—C25—H25	119.8
C19—C14—C15	118.98 (19)	C23—C24—C25	119.4 (2)
C19—C14—P1	122.68 (15)	C23—C24—H24	120.3
C15—C14—P1	118.15 (15)	C25—C24—H24	120.3
C16—C15—C14	120.5 (2)	C24—C23—C22	120.2 (2)
C16—C15—H15	119.8	C24—C23—H23	119.9
C14—C15—H15	119.8	C22—C23—H23	119.9
C15—C16—C17	120.38 (19)	C23—C22—C21	120.96 (18)
C15—C16—H16	119.8	C23—C22—H22	119.5
C17—C16—H16	119.8	C21—C22—H22	119.5
Cl2—Pt1—P1—C14	83.74 (7)	C14—C15—C16—C17	1.8 (3)
Cl1—Pt1—P1—C14	−89.59 (7)	C15—C16—C17—C18	−0.8 (3)
Cl2—Pt1—P1—C8	−156.67 (7)	C16—C17—C18—C19	−0.1 (3)
Cl1—Pt1—P1—C8	30.00 (7)	C17—C18—C19—C14	0.0 (3)
Cl2—Pt1—P1—C1	−33.21 (8)	C15—C14—C19—C18	0.9 (3)
Cl1—Pt1—P1—C1	153.46 (8)	P1—C14—C19—C18	175.77 (17)
Cl2—Pt1—P2—C33	156.19 (7)	C33—P2—C27—C32	−101.79 (18)
Cl1—Pt1—P2—C33	−30.57 (7)	C20—P2—C27—C32	5.8 (2)
Cl2—Pt1—P2—C27	−85.16 (7)	Pt1—P2—C27—C32	131.87 (16)
Cl1—Pt1—P2—C27	88.08 (7)	C33—P2—C27—C28	78.23 (17)
Cl2—Pt1—P2—C20	33.27 (8)	C20—P2—C27—C28	−174.18 (16)
Cl1—Pt1—P2—C20	−153.49 (8)	Pt1—P2—C27—C28	−48.10 (17)
C14—P1—C1—C2	168.80 (15)	C28—C27—C32—C31	−0.5 (3)
C8—P1—C1—C2	58.37 (17)	P2—C27—C32—C31	179.56 (16)
Pt1—P1—C1—C2	−71.98 (16)	C27—C32—C31—C30	−0.4 (3)
P1—C1—C2—C7	100.76 (19)	C32—C31—C30—C29	0.3 (3)
P1—C1—C2—C3	−85.0 (2)	C31—C30—C29—C28	0.7 (3)
C7—C2—C3—C4	2.1 (3)	C30—C29—C28—C27	−1.6 (3)
C1—C2—C3—C4	−172.26 (18)	C32—C27—C28—C29	1.5 (3)
C2—C3—C4—C5	−0.3 (3)	P2—C27—C28—C29	−178.56 (16)
C3—C4—C5—C6	−1.4 (3)	C27—P2—C33—C34	−159.45 (16)
C4—C5—C6—C7	1.1 (3)	C20—P2—C33—C34	91.54 (17)
C5—C6—C7—C2	0.8 (3)	Pt1—P2—C33—C34	−38.53 (18)
C3—C2—C7—C6	−2.4 (3)	C27—P2—C33—C38	23.99 (19)
C1—C2—C7—C6	172.07 (18)	C20—P2—C33—C38	−85.02 (18)
C14—P1—C8—C9	157.60 (15)	Pt1—P2—C33—C38	144.91 (15)
C1—P1—C8—C9	−94.68 (16)	C34—C33—C38—C37	−1.2 (3)
Pt1—P1—C8—C9	37.51 (17)	P2—C33—C38—C37	175.32 (17)
C14—P1—C8—C13	−28.96 (18)	C33—C38—C37—C36	0.8 (3)
C1—P1—C8—C13	78.77 (17)	C38—C37—C36—C35	0.0 (4)
Pt1—P1—C8—C13	−149.04 (14)	C37—C36—C35—C34	−0.4 (3)
C13—C8—C9—C10	−0.8 (3)	C38—C33—C34—C35	0.9 (3)
P1—C8—C9—C10	172.78 (15)	P2—C33—C34—C35	−175.79 (16)
C8—C9—C10—C11	−0.7 (3)	C36—C35—C34—C33	−0.1 (3)
C9—C10—C11—C12	1.4 (3)	C33—P2—C20—C21	−63.36 (16)
C10—C11—C12—C13	−0.7 (3)	C27—P2—C20—C21	−172.43 (14)
C11—C12—C13—C8	−0.8 (3)	Pt1—P2—C20—C21	66.82 (16)
C9—C8—C13—C12	1.5 (3)	P2—C20—C21—C22	98.4 (2)
P1—C8—C13—C12	−171.87 (15)	P2—C20—C21—C26	−83.9 (2)
C8—P1—C14—C19	121.64 (18)	C22—C21—C26—C25	1.4 (3)
C1—P1—C14—C19	14.8 (2)	C20—C21—C26—C25	−176.4 (2)
Pt1—P1—C14—C19	−112.56 (17)	C21—C26—C25—C24	−0.3 (3)
C8—P1—C14—C15	−63.45 (18)	C26—C25—C24—C23	−0.5 (3)
C1—P1—C14—C15	−170.34 (16)	C25—C24—C23—C22	0.2 (3)
Pt1—P1—C14—C15	62.34 (17)	C24—C23—C22—C21	1.0 (3)
C19—C14—C15—C16	−1.8 (3)	C26—C21—C22—C23	−1.7 (3)
P1—C14—C15—C16	−176.92 (17)	C20—C21—C22—C23	176.08 (19)

D—H···A	D—H	H···A	D···A	D—H···A
C7—H7···Cl2i	0.95	2.85	3.532 (2)	130
C26—H26···Cl2	0.95	2.72	3.555 (2)	147
C29—H29···Cl1ii	0.95	2.93	3.731 (2)	143
C16—H16···Cg1ii	0.95	2.73	3.443 (3)	132
C23—H23···Cg2iii	0.95	2.63	3.536 (2)	159
C29—H29···Cg3ii	0.95	2.99	3.525 (2)	117
C36—H36···Cg4iv	0.95	2.77	3.708 (3)	169

Table 1

Hydrogen-bond geometry (Å, °)

Cg1, Cg2, Cg3 and Cg4 are the centroids of the C33—C38, C2—C7, C8—C13 and C27—C32 rings, repectively.

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C7—H7⋯Cl2i	0.95	2.85	3.532 (2)	130
C26—H26⋯Cl2	0.95	2.72	3.555 (2)	147
C29—H29⋯Cl1ii	0.95	2.93	3.731 (2)	143
C16—H16⋯Cg1ii	0.95	2.73	3.443 (3)	132
C23—H23⋯Cg2iii	0.95	2.63	3.536 (2)	159
C29—H29⋯Cg3ii	0.95	2.99	3.525 (2)	117
C36—H36⋯Cg4iv	0.95	2.77	3.708 (3)	169

Symmetry codes: (i) ; (ii) ; (iii) ; (iv) .