| Literature DB >> 23462865 |
Agustí Lledó1, Aida Fuster, Marc Revés, Xavier Verdaguer, Antoni Riera.
Abstract
Medium sized trans-cycloalkenes are unusually reactive in the intermolecular Pauson-Khand reaction (PKR) with regard to typical monocyclic alkenes. This is due to the ring strain imparted by the E stereochemistry. The PKR of these alkenes offers a modular, regioselective and straightforward entry to trans fused [n.3.0] bicyclic scaffolds (n = 6-8).Entities:
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Year: 2013 PMID： 23462865 DOI： 10.1039/c3cc41005f
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222