Literature DB >> 23450280

A triamido-uranium(V) inverse-sandwich 10π-toluene tetraanion arene complex.

Dipti Patel1, Floriana Tuna, Eric J L McInnes, Jonathan McMaster, William Lewis, Alexander J Blake, Stephen T Liddle.   

Abstract

Reduction of [U(Ts(Tol))(Cl)(μ-Cl)U(Ts(Tol))(THF)2] [2, Ts(Tol) = HC(SiMe2NAr')3; Ar' = 4-MeC6H4)] with KC8 in toluene afforded the new arene-bridged diuranium complex [{U(Ts(Tol))}2(μ-η(6):η(6)-C6H5Me)] (3); combined structural, spectroscopic, magnetic, and computational analyses unambiguously confirm that the uranium centres in 3 are in the +5 oxidation state and the toluene is a 10π-tetraanion.

Entities:  

Year:  2013        PMID： 23450280     DOI： 10.1039/c3dt50255d

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  4 in total

1.  Nitrogen activation and cleavage by a multimetallic uranium complex.

Authors:  Megan Keener; Farzaneh Fadaei-Tirani; Rosario Scopelliti; Ivica Zivkovic; Marinella Mazzanti
Journal:  Chem Sci       Date:  2022-06-22       Impact factor: 9.969

2.  An actinide Zintl cluster: a tris(triamidouranium)μ3-η2:η2:η2-heptaphosphanortricyclane and its diverse synthetic utility.

Authors:  Dipti Patel; Floriana Tuna; Eric J L McInnes; William Lewis; Alexander J Blake; Stephen T Liddle
Journal:  Angew Chem Int Ed Engl       Date:  2013-10-14       Impact factor: 15.336

3.  Isolation of +2 rare earth metal ions with three anionic carbocyclic rings: bimetallic bis(cyclopentadienyl) reduced arene complexes of La2+ and Ce2+ are four electron reductants.

Authors:  Christopher M Kotyk; Megan E Fieser; Chad T Palumbo; Joseph W Ziller; Lucy E Darago; Jeffrey R Long; Filipp Furche; William J Evans
Journal:  Chem Sci       Date:  2015-09-21       Impact factor: 9.825

4.  Catalytic insertion of E-H bonds (E = C, N, P, S) into heterocumulenes by amido-actinide complexes.

Authors:  Rami J Batrice; Moris S Eisen
Journal:  Chem Sci       Date:  2015-10-29       Impact factor: 9.825
  4 in total

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