| Literature DB >> 23444917 |
Sae Rom Park1, Cheoljae Kim, Dong-gil Kim, Neetipalli Thrimurtulu, Hyun-Suk Yeom, Jungho Jun, Seunghoon Shin, Young Ho Rhee.
Abstract
The first gold-catalyzed intermolecular coupling of alkynoates and allylic ethers invoking alkoxy addition and [3,3]-sigmatropic rearrangement as the key mechanism has been developed. Remarkably, the reaction showed complete chemoselectivity toward the pathway initiated by the alkoxy addition to alkynes. This unprecedented reactivity led to a new access to diversely substituted β-alkoxyacrylates in a highly efficient manner.Entities:
Year: 2013 PMID： 23444917 DOI： 10.1021/ol4001087
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005