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Literature DB >> 23443313

Unravelling the labyrinth of palladium-catalysed reactions involving isocyanides.

Abstract

Isocyanides possess a rich history in the world of synthetic chemistry. Recently the scope of this already versatile class of reagent has been expanded into its use in palladium-catalysed cascade sequences. The scope of this type of reaction is explored in depth and this tutorial review focuses on its various applications in chemical synthesis, and the wide range of systems that can be efficiently prepared using this strategy are documented.

Entities: Chemical

Year: 2013 PMID： 23443313 DOI： 10.1039/c3cs60022j

Source DB: PubMed Journal: Chem Soc Rev ISSN： 0306-0012 Impact factor: 54.564

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Cited

13 in total

1. Mechanistic Basis for Efficient, Site-Selective, Aerobic Catalytic Turnover in Pd-Catalyzed C-H Imidoylation of Heterocycle-Containing Molecules.

Authors: Stephen J Tereniak; Shannon S Stahl
Journal: J Am Chem Soc Date: 2017-10-06 Impact factor: 15.419

2. NHC-Ni(II)-catalyzed cyclopropene-isocyanide [5 + 1] benzannulation.

Authors: Jian-Qiang Huang; Meng Yu; Xuefeng Yong; Chun-Yu Ho
Journal: Nat Commun Date: 2022-07-16 Impact factor: 17.694

3. Access to 1-amino-3,4-dihydroisoquinolines via palladium-catalyzed C-H bond aminoimidoylation reaction from functionalized isocyanides.

Authors: Zhuang Xiong; Panyuan Cai; Yingshuang Mei; Jian Wang
Journal: RSC Adv Date: 2019-12-18 Impact factor: 4.036

4. Overcoming the limitations of directed C-H functionalizations of heterocycles.

Authors: Yue-Jin Liu; Hui Xu; Wei-Jun Kong; Ming Shang; Hui-Xiong Dai; Jin-Quan Yu
Journal: Nature Date: 2014-11-10 Impact factor: 49.962

5. Silver-Assisted [3 + 2] Annulation of Nitrones with Isocyanides: Synthesis of 2,3,4-Trisubstituted 1,2,4-Oxadiazolidin-5-ones.

Authors: Xuanyu Shen; Andrey Shatskiy; Yan Chen; Markus D Kärkäs; Xiang-Shan Wang; Jian-Quan Liu
Journal: J Org Chem Date: 2020-02-20 Impact factor: 4.354

Review 6. Synergy Effects in the Chemical Synthesis and Extensions of Multicomponent Reactions (MCRs)-The Low Energy Way to Ultra-Short Syntheses of Tailor-Made Molecules.

Authors: Heiner Eckert
Journal: Molecules Date: 2017-02-25 Impact factor: 4.411

Unravelling the labyrinth of palladium-catalysed reactions involving isocyanides.

1. Mechanistic Basis for Efficient, Site-Selective, Aerobic Catalytic Turnover in Pd-Catalyzed C-H Imidoylation of Heterocycle-Containing Molecules.

2. NHC-Ni(II)-catalyzed cyclopropene-isocyanide [5 + 1] benzannulation.

3. Access to 1-amino-3,4-dihydroisoquinolines via palladium-catalyzed C-H bond aminoimidoylation reaction from functionalized isocyanides.

4. Overcoming the limitations of directed C-H functionalizations of heterocycles.

5. Silver-Assisted [3 + 2] Annulation of Nitrones with Isocyanides: Synthesis of 2,3,4-Trisubstituted 1,2,4-Oxadiazolidin-5-ones.

Review 6. Synergy Effects in the Chemical Synthesis and Extensions of Multicomponent Reactions (MCRs)-The Low Energy Way to Ultra-Short Syntheses of Tailor-Made Molecules.

7. Metal-Mediated Addition of N-Nucleophiles to Isocyanides: Mechanistic Aspects.

8. Synthesis of Densely Functionalized Pyrimidouracils by Nickel(II)-Catalyzed Isocyanide Insertion.

9. Nickel-catalyzed allylic carbonylative coupling of alkyl zinc reagents with tert-butyl isocyanide.

Review 10. Recent Advances in Palladium-Catalyzed Isocyanide Insertions.