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Literature DB >> 23427822

Lithium superionic sulfide cathode for all-solid lithium-sulfur batteries.

Zhan Lin¹, Zengcai Liu, Nancy J Dudney, Chengdu Liang.

Abstract

This work presents a facile synthesis approach for core-shell structured Li2S nanoparticles with Li2S as the core and Li3PS4 as the shell. This material functions as lithium superionic sulfide (LSS) cathode for long-lasting, energy-efficient lithium-sulfur (Li-S) batteries. The LSS has an ionic conductivity of 10(-7) S cm(-1) at 25 °C, which is 6 orders of magnitude higher than that of bulk Li2S (∼10(-13) S cm(-1)). The high lithium-ion conductivity of LSS imparts an excellent cycling performance to all-solid Li-S batteries, which also promises safe cycling of high-energy batteries with metallic lithium anodes.

Entities: Chemical

Year: 2013 PMID： 23427822 DOI： 10.1021/nn400391h

Source DB: PubMed Journal: ACS Nano ISSN： 1936-0851 Impact factor: 15.881

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Cited

8 in total

Review 1. From lithium to sodium: cell chemistry of room temperature sodium-air and sodium-sulfur batteries.

Authors: Philipp Adelhelm; Pascal Hartmann; Conrad L Bender; Martin Busche; Christine Eufinger; Juergen Janek
Journal: Beilstein J Nanotechnol Date: 2015-04-23 Impact factor: 3.649

2. Forced Disorder in the Solid Solution Li₃P-Li₂S: A New Class of Fully Reduced Solid Electrolytes for Lithium Metal Anodes.

Authors: Conrad Szczuka; Bora Karasulu; Matthias F Groh; Farheen N Sayed; Timothy J Sherman; Joshua D Bocarsly; Sundeep Vema; Svetlana Menkin; Steffen P Emge; Andrew J Morris; Clare P Grey
Journal: J Am Chem Soc Date: 2022-08-30 Impact factor: 16.383

3. Ionic Conductivity of Nanocrystalline and Amorphous Li₁₀GeP₂S₁₂: The Detrimental Impact of Local Disorder on Ion Transport.

Authors: Lukas Schweiger; Katharina Hogrefe; Bernhard Gadermaier; Jennifer L M Rupp; H Martin R Wilkening
Journal: J Am Chem Soc Date: 2022-05-24 Impact factor: 16.383

Lithium superionic sulfide cathode for all-solid lithium-sulfur batteries.

Review 1. From lithium to sodium: cell chemistry of room temperature sodium-air and sodium-sulfur batteries.

2. Forced Disorder in the Solid Solution Li₃P-Li₂S: A New Class of Fully Reduced Solid Electrolytes for Lithium Metal Anodes.

3. Ionic Conductivity of Nanocrystalline and Amorphous Li₁₀GeP₂S₁₂: The Detrimental Impact of Local Disorder on Ion Transport.

4. Design principles for solid-state lithium superionic conductors.

5. Ultrasmall Li2S nanoparticles anchored in graphene nanosheets for high-energy lithium-ion batteries.

6. Biomineralization of lithium nanoparticles by Li-resistant Pseudomonas rodhesiae isolated from the Atacama salt flat.

Review 7. Designing composite solid-state electrolytes for high performance lithium ion or lithium metal batteries.

8. Interfacial architecture for extra Li⁺ storage in all-solid-state lithium batteries.

Lithium superionic sulfide cathode for all-solid lithium-sulfur batteries.

Review 1. From lithium to sodium: cell chemistry of room temperature sodium-air and sodium-sulfur batteries.

2. Forced Disorder in the Solid Solution Li3P-Li2S: A New Class of Fully Reduced Solid Electrolytes for Lithium Metal Anodes.

3. Ionic Conductivity of Nanocrystalline and Amorphous Li10GeP2S12: The Detrimental Impact of Local Disorder on Ion Transport.

4. Design principles for solid-state lithium superionic conductors.

5. Ultrasmall Li2S nanoparticles anchored in graphene nanosheets for high-energy lithium-ion batteries.

6. Biomineralization of lithium nanoparticles by Li-resistant Pseudomonas rodhesiae isolated from the Atacama salt flat.

Review 7. Designing composite solid-state electrolytes for high performance lithium ion or lithium metal batteries.

8. Interfacial architecture for extra Li⁺ storage in all-solid-state lithium batteries.

2. Forced Disorder in the Solid Solution Li₃P-Li₂S: A New Class of Fully Reduced Solid Electrolytes for Lithium Metal Anodes.

3. Ionic Conductivity of Nanocrystalline and Amorphous Li₁₀GeP₂S₁₂: The Detrimental Impact of Local Disorder on Ion Transport.